Method of treating a high-temperature well with a fluid containing a viscosifier and a stabilizer package

Patent metadata

Field	Value
Publication number	US-9260648-B2
Application number	US-201313895218-A
Country	US
Kind code	B2
Filing date	May 15, 2013
Priority date	May 15, 2013
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

A treatment fluid for treating a portion of a high-temperature subterranean formation comprises: a base fluid, wherein the base fluid comprises water; a viscosifier, wherein the viscosifier is a polymer, and wherein the viscosifier is thermally stable up to a temperature of 325° F.; and a stabilizer package, wherein the stabilizer package: (A) comprises a first stabilizer and a second stabilizer, wherein the first stabilizer is an oxygen scavenger and the second stabilizer is a pH adjustor; and (B) is capable of increasing the thermal stability of the viscosifier to a temperature greater than 350° F., wherein the portion of the subterranean formation has a bottomhole temperature greater than 350° F. A method of treating a high-temperature subterranean formation comprises introducing the treatment fluid into the portion of the subterranean formation.

First claim

What is claimed is:

1. A method of treating a portion of a subterranean formation comprising:
introducing a treatment fluid into the portion of the subterranean formation, wherein the portion of the subterranean formation has a bottomhole temperature greater than 350° F., wherein the treatment fluid is stable at a temperature greater than 400° F., and wherein the treatment fluid comprises:
(A) a base fluid, wherein the base fluid comprises water;
(B) a viscosifier, wherein the viscosifier is a terpolymer, wherein the terpolymer comprises the monomer residues 2-acrylamido-2-methylpropane sulfonic acid, acrylamide, and acrylic acid, wherein the terpolymer has a molecular weight in the range of 500,000 to 2,000,000, and wherein the viscosifier is thermally stable up to a temperature of 325° F.; and
(C) a stabilizer package, wherein the stabilizer package:
(i) comprises a first stabilizer and a second stabilizer, wherein the first stabilizer is an oxygen scavenger and the second stabilizer is a pH adjustor; and
(ii) increases the thermal stability of the viscosifier to a temperature greater than 400° F.

2. The method according to claim 1 , wherein the water is selected from the group consisting of freshwater, brackish water, saltwater, and any combination thereof.

3. The method according to claim 1 , wherein the concentration of the monomer residues is selected such that the terpolymer is thermally stable up to a temperature of 325° F.

4. The method according to claim 1 , wherein the monomer residues are present in the following concentrations: 2-acrylamido-2-methylpropane sulfonic acid from about 15% to about 80%; acrylamide from about 20% to about 85%; and acrylic acid from about 0% to about 10% by weight of the terpolymer.

5. The method according to claim 1 , wherein the first stabilizer is selected from the group consisting of sodium thiosulfate, an alkali metal thiosulfate, sodium dithionite, disodium phosphate, sodium sulfite, zinc sulfite, hydroquinone, hydrazine, diethylhydroxylamine, carbohydrazide, and combinations thereof.

6. The method according to claim 1 , wherein the first stabilizer is sodium thiosulfate.

7. The method according to claim 1 , wherein the first stabilizer is selected and is in a sufficient concentration such that the polymer is thermally stable at a temperature greater than 400° F.

8. The method according to claim 1 , wherein the first stabilizer is in a concentration in the range of about 0.5% to about 5% by weight of the treatment fluid.

9. The method according to claim 1 , wherein the second stabilizer is selected and is in a sufficient concentration such that the treatment fluid has a pH in the range of about 8.5 to 11.

10. The method according to claim 1 , wherein the pH adjustor is a compound that is capable of providing a pH of at least 9 to the treatment fluid.

11. The method according to claim 1 , wherein the pH adjustor is a base, a buffer, or an alkaline buffer.

12. The method according to claim 1 , wherein the second stabilizer is selected from the group consisting of sodium bicarbonate, N-cyclohexyl-2-aminoethanesulfonic acid, borate, sodium carbonate, potassium carbonate, magnesium oxide, and combinations thereof.

13. The method according to claim 1 , wherein the second stabilizer is sodium bicarbonate.

14. The method according to claim 1 , wherein the second stabilizer is selected and is in a sufficient concentration such that the polymer is thermally stable at a temperature greater than 400° F.

15. The method according to claim 1 , wherein the second stabilizer is in a concentration in the range of about 0.1% to about 5% by weight of the treatment fluid.

16. The method according to claim 1 , wherein the stabilizer package increases the thermal stability temperature of the viscosifier by a temperature in the range of 25° F. to about 300° F.

17. The method according to claim 1 , wherein the first stabilizer and the second stabilizer are selected and are in a sufficient concentration such that the treatment fluid is stable at the bottomhole temperature and pressure of the subterranean formation for a desired amount of time.

18. The method according to claim 1 , wherein the subterranean formation is penetrated by a well, wherein at least a portion of the well has a bottomhole temperature greater than 350° F.

Assignees

• Halliburton Energy Services Inc

Inventors

• Suryawanshi Prerana U
• Danait Achala V
• Kalgaonkar Rajendra A

Classifications

• C09K8/74

  combined with additives added for specific purposes · CPC title

• C09K8/882

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09K8/42

  Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells (compositions for plastering C09K8/50) · CPC title

• C09K8/40

  Spacer compositions, e.g. compositions used to separate well-drilling from cementing masses · CPC title

• C09K8/665

  containing inorganic compounds (proppants C09K8/80) · CPC title