Composite structural material formed product and packaging material using the same, method for producing the composite structural material, and coating liquid

Patent metadata

Field	Value
Publication number	US-9260622-B2
Application number	US-201113638715-A
Country	US
Kind code	B2
Filing date	Mar 30, 2011
Priority date	Mar 30, 2010
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

The composite structural material of the present invention includes a base (X) and a layer (Y) stacked on the base (X). The layer (Y) includes a reaction product (R) of a metal oxide (A) and a phosphorus compound (B). In the infrared absorption spectrum of the layer (Y) in the range of 800 to 1400 cm −1 , the wave number (n 1 ) at which the infrared absorption reaches maximum is in the range of 1080 to 1130 cm −1 .

First claim

The invention claimed is:

1. A composite structural material, comprising:
a base (X); and
a layer (Y) stacked on the base (X),
wherein the layer (Y) comprises a reaction product (R) obtained by a process comprising reacting a metal oxide (A) and a phosphorus compound (B),
the phosphorus compound (B) is at least one selected from the group consisting of phosphoric acid, polyphosphoric acid, phosphorous acid, phosphonic acid represented by a formula HP(═O)(OH) 2 , and a salt, a halide and a dehydrate thereof, and trimethyl phosphate, and
in an infrared absorption spectrum of the layer (Y) in the range of 800 to 1400 cm −1 , a wave number (n 1 ) at which the infrared absorption reaches maximum is in the range of 1080 to 1130 cm −1 .

2. The composite structural material of claim 1 , wherein
in an infrared absorption spectrum of the layer (Y) in the range of 800 to 1400 cm −1 , an infrared absorption peak attributed to a bond expressed by M-O—P in which a metal atom (M) constituting the metal oxide (A) and a phosphorus atom (P) derived from the compound (B) are bonded via an oxygen atom (O) is the highest among all infrared absorption peaks attributed to a bond constituting the metal oxide (A), a bond constituting the phosphorus compound (B), and a bond formed by a reaction of the metal oxide (A) and the phosphorus compound (B) individually and/or with each other, and
wherein a wave number (n 1 ) at which the infrared absorption peak reaches maximum is in the range of 1080 to 1130 cm −1 .

3. The composite structural material of claim 1 , wherein the phosphorus compound (B) comprises a plurality of sites, which react with the metal oxide (A).

4. The composite structural material of claim 1 , wherein an absorbance (A 1 ) at the wave number (n 1 ) and an absorbance (A 2 ) at a wave number (n 2 ) satisfy a relationship of (A 2 )/(A 1 )≦0.2 in the infrared absorption spectrum of the layer (Y), and
wherein the wave number (n 2 ) is a wave number at which an infrared absorption due to a stretching vibration of hydroxyl group reaches maximum in the infrared absorption spectrum of the layer (Y) in the range of 2500 to 4000 cm −1 .

5. The composite structural material of claim 1 , wherein a half width of the absorption peak at the wave number (n 1 ) is 200 cm −1 or less.

6. The composite structural material according to claim 1 ,
wherein the layer (Y) has a structure in which particles of the metal oxide (A) are bonded to each other via a phosphorus atom derived from the phosphorus compound (B), and
wherein a number of moles of metal atom that bonds the particles to each other and that is not derived from the metal oxide (A) is in the range of 0 to 1 times a number of moles of phosphorus atom bonding the particles to each other.

7. The composite structural material of claim 1 , wherein the metal oxide (A) is a hydrolyzed condensate of a compound (L) comprising the metal atom (M) to which a hydrolyzable characteristic group is bonded.

8. The composite structural material of claim 7 , wherein the compound (L) comprises a compound (L 1 ) of formula (I):
M 1 X 1 m R 1 (n-m)   (I)

wherein:
M 1 is Al, Ti, or Zr;
X 1 is F, Cl, Br, I, R 2 O—, R 3 C(═O)O—, (R 4 C(═O)) 2 CH—, or NO 3 ;
R 1 , R 2 , R 3 , and R 4 each are independently an alkyl group, an aralkyl group, an aryl group, or an alkenyl group;
in the case where a plurality of any of X 1 , R 1 , R 2 , R 3 , and R 4 are present in the formula (I), the plurality of X 1 , R 1 , R 2 , R 3 , and R 4 may be the same as or different from each other respectively;
n is equal to a valence of M 1 ; and
m is an integer of 1 to n.

9. The composite structural material of claim 1 , wherein the phosphorus compound (B) is at least one selected from the group consisting of phosphoric acid, polyphosphoric acid, phosphorous acid, phosphonic acid represented by a formula HP(═O)(OH) 2 , and a salt, a halide, and a dehydrate thereof.

10. The composite structural material of claim 1 , wherein, in the layer (Y), the number of moles (N M ) of the metal atom constituting the metal oxide (A) and the number of moles (N p ) of the phosphorus atom from the phosphorus compound (B) satisfy a relationship of:
0.8≦( N M )/( N p )≦4.5.

11. The composite structural material according to claim 1 , wherein the layer (Y) further comprises a polymer (C) comprising at least one functional group (f) selected from the group consisting of a hydroxyl group, a carboxyl group, a carboxylic anhydride group, and a salt of a carboxyl group.

12. The composite structural material of claim 11 , wherein the polymer (C) is at least one selected from the group consisting of polyvinyl alcohol, ethylene-vinyl alcohol copolymer, polysaccharides, polyacrylic acid, a salt of polyacrylic acid, polymethacrylic acid, and a salt of polymethacrylic acid.

13. The composite structural material of claim 1 , wherein the base (X) is a layer base.

14. The composite structural material of claim 13 , wherein the base (X) comprises at least one layer selected from the group consisting of a thermoplastic resin film layer, a paper layer, and an inorganic deposited layer.

15. The composite structural material of claim 1 , having a moisture transmission rate under conditions of 40° C. and 90/0% RH of not more than 5 g/(m 2 ·day).

16. The composite structural material of claim 1 , having an oxygen transmission rate under conditions of 20° C. and 85% RH of not more than 1 ml/(m 2 ·day·atm).

17. The composite structural material of claim 1 , wherein the moisture transmission rate under conditions of 40° C. and 90/0% RH after immersion in hot water of 120° C. for 30 minutes is not more than twice the moisture transmission rate under conditions of 40° C. and 90/0% RH before the immersion.

18. The composite structural material of claim 1 , wherein the oxygen transmission rate under conditions of 20° C. and 85% RH after immersion in hot water of 120° C. for 30 minutes is not more than twice the oxygen transmission rate under conditions of 20° C. and 85% RH before the immersion.

19. A packaging material comprising the composite structural material of claim 1 .

20. The packaging material of claim 19 , being a packaging material for retort foods.

21. A formed product formed with the packaging material of claim 19 .

22. The formed product of claim 21 , being a vertical form fill seal pouch, a vacuum packaging pouch, a pouch with a spout, a laminated tube container, an infusion bag, a lidding film, a paper container, or a vacuum insulator.

Assignees

• Yoshida Kentaro
• Sasaki Ryoichi
• Omoda Mamoru
• Hirose Wataru
• Shibata Manabu
• Oshita Tatsuya
• Kuraray Co

Inventors

• Yoshida Kentaro
• Sasaki Ryoichi
• Omoda Mamoru
• Hirose Wataru
• Shibata Manabu
• Oshita Tatsuya

Classifications

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• B32B5/26

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title

• B32B15/12

  of paper or cardboard · CPC title

• B32B2509/10

  Refrigerators or refrigerating equipment · CPC title

• B32B27/10

  of paper or cardboard · CPC title