Ester compound
US-2024025838-A1 · Jan 25, 2024 · US
US9260403B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9260403-B2 |
| Application number | US-201414229388-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 28, 2014 |
| Priority date | Sep 29, 2011 |
| Publication date | Feb 16, 2016 |
| Grant date | Feb 16, 2016 |
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Provided are methods of producing 2,5-furandicarboxylic acid (FDCA) from renewable sources such as seaweed, alginate, oligoalginate, pectin, oligopectin, polygalacturonate, galacturonate, and/or oligogalacturonate. The sugars in the renewable sources can be converted into one or more intermediates such as 4-deoxy-L-erythro-5-hexoseulose uronate (DEHU), 4-deoxy-L-threo-5-hexosulose uronate (DTHU), 5-hydroxymethyl furfural (HMF), 2,5-dihydroxymethyl furan (DHMF), and 5-formyl-2-furancarboxylic acid (FFA), which can be converted into FDCA by dehydration and cyclization to produce 5-formyl-2-furancarboxylic acid (FFA), followed by oxidation to produce FDCA. DEHU or DTHU may also be converted into FDCA by oxidation to produce 2,3-dihydroxy-5-oxohexanedioic acid (DOHA), which then undergoes dehydration and cyclization to produce FDCA.
Opening claim text (preview).
What is claimed is: 1. A method of producing 2,5-furandicarboxylic acid (FDCA), comprising: a) providing a compound of Formula (I), b) dehydrating and cyclizing the compound of formula I into 5-formyl-2-furancarboxylic acid (FFA); and c) oxidizing the FFA to produce FDCA. 2. The method of claim 1 , wherein the compound of Formula (I) is 4-deoxy-…
Chemistry & Metallurgy · mapped topic
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