Methods for preparing 2,5-furandicarboxylic acid

US9260403B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-9260403-B2
Application numberUS-201414229388-A
CountryUS
Kind codeB2
Filing dateMar 28, 2014
Priority dateSep 29, 2011
Publication dateFeb 16, 2016
Grant dateFeb 16, 2016

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Abstract

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Provided are methods of producing 2,5-furandicarboxylic acid (FDCA) from renewable sources such as seaweed, alginate, oligoalginate, pectin, oligopectin, polygalacturonate, galacturonate, and/or oligogalacturonate. The sugars in the renewable sources can be converted into one or more intermediates such as 4-deoxy-L-erythro-5-hexoseulose uronate (DEHU), 4-deoxy-L-threo-5-hexosulose uronate (DTHU), 5-hydroxymethyl furfural (HMF), 2,5-dihydroxymethyl furan (DHMF), and 5-formyl-2-furancarboxylic acid (FFA), which can be converted into FDCA by dehydration and cyclization to produce 5-formyl-2-furancarboxylic acid (FFA), followed by oxidation to produce FDCA. DEHU or DTHU may also be converted into FDCA by oxidation to produce 2,3-dihydroxy-5-oxohexanedioic acid (DOHA), which then undergoes dehydration and cyclization to produce FDCA.

First claim

Opening claim text (preview).

What is claimed is: 1. A method of producing 2,5-furandicarboxylic acid (FDCA), comprising: a) providing a compound of Formula (I), b) dehydrating and cyclizing the compound of formula I into 5-formyl-2-furancarboxylic acid (FFA); and c) oxidizing the FFA to produce FDCA. 2. The method of claim 1 , wherein the compound of Formula (I) is 4-deoxy-…

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  • C07D307/68Primary

    Chemistry & Metallurgy · mapped topic

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What does patent US9260403B2 cover?
Provided are methods of producing 2,5-furandicarboxylic acid (FDCA) from renewable sources such as seaweed, alginate, oligoalginate, pectin, oligopectin, polygalacturonate, galacturonate, and/or oligogalacturonate. The sugars in the renewable sources can be converted into one or more intermediates such as 4-deoxy-L-erythro-5-hexoseulose uronate (DEHU), 4-deoxy-L-threo-5-hexosulose uronate (DTHU…
Who is the assignee on this patent?
Yoshikuni Yasuo, Cooper Susan R, Wargacki Adam J, and 6 more
What technology area does this patent fall under?
Primary CPC classification C07D307/68. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Feb 16 2016 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).