Method of modifying nano-porous gas-reforming catalyst with high-temperature stability

Patent metadata

Field	Value
Publication number	US-9259727-B2
Application number	US-201213657996-A
Country	US
Kind code	B2
Filing date	Oct 23, 2012
Priority date	Oct 23, 2012
Publication date	Feb 16, 2016
Grant date	Feb 16, 2016

Abstract

A gas-reforming catalyst is modified to obtain stability in high temperature. The catalyst uses α-Al 2 O 3 as a carrier and is nano-porous. Hence, reaction surface is greatly broadened; and platinum contained inside does not become bigger after times of use. The catalyst does not deposit carbon and has long life. The stability of the catalyst can be still remained even at a temperature higher than 800° C.

First claim

What is claimed is:

1. A method of forming a nano-porous gas-reforming catalyst with high-temperature stability, comprising steps of:
(a) adding γ-aluminum oxide (γ-Al 2 O 3 ) with a carbon material selected from a group consisting of active carbon and a carbon nanomaterial; then, mixing the γ-Al 2 O 3 and said carbon material through ball milling and tableting the ball milled mixture to obtain a cylinder of γ-Al 2 O 3 having nano-pores;
(b) calcining said cylinder of γ-Al 2 O 3 having nano-pores in a furnace flown with air for 6˜9 hours (hrs) at a temperature-rising velocity of 5° C. per minute (° C./min) until a temperature of 1080˜1320 Celsius degrees (° C.); then, lowering down said temperature to a room temperature at a temperature-falling velocity of 5° C./min to obtain a cylinder of α-Al 2 O 3 having nano-pores;
(c) dissolving cerium nitrate (Ce(NO 3 ) 3 .6H 2 O) into deionized water to obtain a solution of cerium nitrate;
(d) impregnating said cylinder of α-Al 2 O 3 having nano-pores in said solution of cerium nitrate;
(e) draining left-over water from said solution of cerium nitrate by using a vacuum evaporator to obtain a catalyst impregnated cylinder of α-Al 2 O 3 having nano-pores;
(f) drying said catalyst impregnated cylinder of α-Al 2 O 3 having nano-pores in an oven, wherein said catalyst is a CeO 2 /α-Al 2 O 3 catalyst and CeO 2 is carried on the cylinder of α-Al 2 O 3 and embedded in said nano-pores;
(g) calcining said dried CeO 2 /α-Al 2 O 3 catalyst in a furnace flown with air for 3˜5 hrs with a temperature-rising velocity of 5° C./min until a temperature of 440˜660° C.;
(h) dissolving chloroplatinic acid into deionized water to obtain a solution of platinum;
(i) impregnating said calcined CeO 2 /α-Al 2 O 3 catalyst in said solution of platinum so as to form a platinum impregnated Pt/CeO 2 /α-Al 2 O 3 catalyst;
(j) draining left-over water from said solution of platinum by using a vacuum evaporator and drying said drained Pt/CeO 2 /α-Al 2 O 3 catalyst in an oven; and
(k) calcining said dried Pt/CeO 2 /α-Al 2 O 3 catalyst in a furnace flown with air for ˜5 hrs with a temperature-rising velocity of 5° C./min until a temperature of 520˜780° C.; then, lowering down said temperature to a room temperature at a temperature-falling velocity of 5° C./min to obtain a calcined Pt/CeO 2 /α-Al 2 O 3 catalyst having nano-pores, wherein Pt and CeO 2 are located on α-Al 2 O 3 embedded in said nano-pores; and wherein said Pt/CeO 2 /α-Al 2 O 3 catalyst has a durability longer than 2000 hrs, a gas conversion rate higher than 95 percent (%) and stability at a temperature higher than 1000° C.

2. The method according to claim 1 , wherein said carbon nanomaterial is a carbon nanotube (CNT).

3. The method according to claim 1 , wherein, in step (b), said α-Al 2 O 3 catalyst is a cylinder having a granular size of 2.04˜3.06 millimeters (mm) and a height of 2.48˜3.72 mm and has nano-pores having diameters of 60˜40 nanometers (nm).

4. The method according to claim 1 , wherein, in step (b), 3 liters per minute (LPM) of air is flown in to process calcination for 8 hrs with a temperature-rising velocity of 5° C./min until 1200° C.

5. The method according to claim 1 , wherein, in step (d), said impregnating is processed for 12 hrs.

6. The method according to claim 1 , wherein, in step (g), 3LPM of air is flown in to process calcination for 4 hrs with a temperature-rising velocity of 5° C./min until 550° C.

7. The method according to claim 1 , wherein, in step (i), said impregnating is processed for 12 hrs.

8. The method according to claim 1 , wherein, in step (k), 3LPM of air is flown in to process calcination for 4 hrs with a temperature-rising velocity of 5° C./min until 650° C.

Assignees

• Atomic Energy Council
• Inst Nuclear Energy Res Atomic Energy Council Executive Yuan Roc

Inventors

• Hsu Ning-Yih
• Jeng King-Tsai
• Chiou Shean-Du
• Lin Su-Hsine
• Tzeng Hwa-Yuan
• Huang Wan-Min
• Chang Yuan-Ming
• Lee Ruey-Yi

Classifications

• B01J35/55

  Cylinders or rings · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01J35/026

  Operations & Transport · mapped topic