Metal organic framework-derived carbon aerogel, preparation method thereof and application in lithium ion batteries
US-12183924-B2 · Dec 31, 2024 · US
US9257717B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9257717-B2 |
| Application number | US-201214233149-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 3, 2012 |
| Priority date | Jul 22, 2011 |
| Publication date | Feb 9, 2016 |
| Grant date | Feb 9, 2016 |
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In a wound electrode group, a positive electrode includes positive electrode active material layers formed on both surfaces of a band-like positive electrode current collector, and a negative electrode includes negative electrode active material layers on both surfaces of a band-like negative electrode current collector. Charge capacity of the negative electrode falls within a range of 83-99% of theoretical capacity of the negative electrode in a full charge state of a nonaqueous electrolyte secondary battery. An active material mass M1 per unit area of a negative electrode active material layer formed on an outer circumference of the negative electrode current collector, and an active material mass M2 per unit area of a negative electrode active material layer formed on an inner circumference satisfy a relational expression of M1/M2<(R1+t/2)/(R1−t/2), where the electrode group has an innermost diameter of R1, and the negative electrode has a thickness of t.
Opening claim text (preview).
The invention claimed is: 1. A nonaqueous electrolyte secondary battery comprising: an electrode group formed by winding a positive electrode and a negative electrode with a porous insulating layer interposed therebetween, wherein the positive electrode includes positive electrode active material layers on both surfaces of a band-like positive electrode current collector, the negative electrode includes negative electrode active material layers on both surfaces of a band-like negative electrode current collector, charge capacity of the negative electrode falls within a range of 83-99% of theoretical capacity of the negative electrode in a full charge state of the nonaqueous electrolyte secondary battery, and an active material mass M1 per unit area of one of the negative electrode active material layers, which is formed on an outer circumference of the negative electrode current collector, and an active material mass M2 per unit area of the other of the negative electrode active material layers, which is formed on an inner circumference of the negative electrode current collector, satisfy a relational expression of M 1/ M 2<( R 1+ t/ 2)/( R 1− t/ 2), where the electrode group has an innermost diameter of R1, and the negative electrode has a thickness of t. 2. The nonaqueous electrolyte secondary battery of claim 1 , wherein the active material mass M1 per unit area of the one of the negative electrode active material layers, which is formed on the outer circumference of the negative electrode current collector, and the active material mass M2 per unit area of the other of the negative electrode active material layers, which is formed on the inner circumference of the negative electrode current collector, satisfy a relational expression of ( R 2+ t/ 2)/( R 2− t/ 2)< M 1/ M 2, where the electrode group has an outermost diameter of R2. 3. The nonaqueous electrolyte secondary battery of claim 1 , wherein the nonaqueous electrolyte secondary battery is a lithium-ion secondary battery, a negative electrode active material is carbon, and the charge capacity of the negative electrode falls within a range from 310 mAh/g to 372 mAh/g in the full charge state of the nonaqueous electrolyte secondary battery. 4. The nonaqueous electrolyte secondary battery of claim 1 , wherein the negative electrode active material layers formed on the both surfaces of the band-like negative electrode current collector have the same active material density, and a thickness T1 of the one of the negative electrode active material layers, which is formed on the outer circumference of the negative electrode current collector, and a thickness T2 of the other of the negative electrode active material layers, which is formed on the inner circumference of the negative electrode current collector, satisfy a relation of T 1/ T 2<( R 1+ t/ 2)/( R 1− t/ 2). 5. The nonaqueous electrolyte secondary battery of claim 1 , wherein an active material mass per unit area of one of the positive electrode active material layers, which is formed on an inner circumference of the positive electrode current collector, is smaller than the active material mass per unit area of the other of the positive electrode active material layers, which is formed on the outer circumference of the positive electrode current collector. 6. The nonaqueous electrolyte secondary battery of claim 2 , wherein the relation between the masses M1 and M2 satisfies a relational expression of M 1/ M 2=[( R 1+ R 2)/2+ t/ 2]/[( R 1+ R 2)/2− t/ 2].
Cross-Sectional Technologies · mapped topic
of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators · CPC title
Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title
Li-accumulators · CPC title
characterised by shape or form · CPC title
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