Organic electrolyte solution and redox flow battery including the same

Patent metadata

Field	Value
Publication number	US-9257714-B2
Application number	US-201313754415-A
Country	US
Kind code	B2
Filing date	Jan 30, 2013
Priority date	Jan 31, 2012
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

An organic electrolyte solution including a solvent; an electrolyte including a metal-ligand coordination compound; and an additive including a hydrophobic group and a metal affinic group.

First claim

What is claimed is:

1. An organic electrolyte solution comprising:
a solvent;
an electrolyte comprising a metal-ligand coordination compound; and

a high-molecular weight additive comprising a metal affinic group, and
wherein the metal affinic group interacts with the metal of the metal-ligand coordination compound, and comprises at least one selected from an ester group, a carboxyl group, a phosphoric acid group, a sulfonic acid group, a hydroxyl group, and an amine group,
wherein a hydrogen atom of a backbone of the additive is substituted with a hydrophobic group,
wherein the backbone of the additive comprises at least one selected from a saturated or unsaturated hydrocarbon, a polyester, a polyurethane, a phosphoric ester polymer, and a phosphoric ester-sulfonic acid amine copolymer, and
wherein the hydrophobic group is at least one selected from a substituted or unsubstituted C6 to C7 aryl group, and a substituted or unsubstituted C1 to C3 alkyl group.

2. The organic electrolyte solution of claim 1 , wherein a metal of the metal-ligand coordination compound comprises at least one selected from nickel (Ni), cobalt (Co), iron (Fe), ruthenium (Ru), zinc (Zn), manganese (Mn), yttrium (Y), zirconium (Zr), titanium (Ti), chromium (Cr), magnesium (Mg), cerium (Ce), copper (Cu), lead (Pb), and vanadium (V).

3. The organic electrolyte solution of claim 1 , wherein a ligand of the metal-ligand coordination compound comprises at least one selected from dipyridyl, terpyridyl, ethylene diamine, propylene diamine, phenanthroline, and an N-heterocyclic carbene (NHC).

4. The organic electrolyte solution of claim 3 , wherein the N-heterocyclic carbene comprises at least one selected from 2,6-bis(methyl imidazole-2-ylidene)pyridine, 1,3-dimethylimidazole, 1,3-bis(2,5-diisopropyl)imidazole, 1,3-dimethylimidazole, 1,3-di-tert-butylimidazole, 1,3-dicyclohexylimidazole, and 1-ethyl3-methylimidazole.

5. The organic electrolyte solution of claim 1 , wherein the metal-ligand coordination compound is reversibly oxidizable or reducible in an oxidation-reduction reaction.

6. The organic electrolyte solution of claim 1 , wherein the additive is contained in the organic electrolyte solution in an amount of about 1 to about 15 volume percent, based on a total volume of the organic electrolyte solution.

7. The organic electrolyte solution of claim 1 ,
wherein the polymer has a molecular weight of about 10,000 to about 100,000 Daltons.

8. The organic electrolyte solution of claim 1 , wherein the additive comprises at least one selected from an alkylolammonium salt of a copolymer having acid groups, an alkylammonium salt of a phosphoric acid ester of a copolymer, a copolymer containing phosphoric acid groups; a copolymer containing carboxylic acid groups; and a polyester containing phosphoric acid groups.

9. The organic electrolyte solution of claim 1 , wherein the metal-ligand coordination compound comprises at least one selected from:

10. The organic electrolyte solution of claim 1 , wherein the metal-ligand coordination compound comprises at least one selected from BF 4 − , PF 6 − , CF 3 SO 3 − ClO 4r− , (CF 3 SO 2 ) 3 C − , and (CF 3 SO 2 ) 2 N − .

11. The organic electrolyte solution of claim 1 , wherein the solvent comprises at least one selected from an aqueous solvent, a non-aqueous solvent, and an ionic liquid.

12. The organic electrolyte solution of claim 11 , wherein the non-aqueous solvent is at least one selected from dimethyl acetamide, diethyl carbonate, dimethyl carbonate, acetonitrile, γ-butyrolactone (GBL), propylene carbonate (PC), ethylene carbonate (EC), N-methyl-2-pyrrolidone (NMP), fluoroethylene carbonate, ethyl methyl carbonate, 1,2-dimethoxyethane, 1,2-diethoxyethane, tetrahydrofuran, 2-methyltetrahydrofuran, dioxane, 1,3-dioxolane, diethylene glycol dimethyl ether, ethylene glycol dimethyl ether, and N,N-dimethylacetamide.

13. An electrode for a redox flow battery comprising the organic electrolyte solution of claim 1 .

14. A tank comprising the organic electrolyte solution of claim 1 .

15. A redox flow battery comprising:
a cathode cell comprising a cathode and a catholyte;
an anode cell comprising an anode and an anolyte; and
an ion exchange membrane disposed between the cathode cell and the anode cell,
wherein at least one of the catholyte and the anolyte comprises the organic electrolyte solution of claim 1 .

16. The redox flow battery of claim 15 , wherein the catholyte and the anolyte comprise a redox couple of Fe 2+ /Ni 0 or Ru 2+ /Ni 0 .

17. The redox flow battery of claim 15 , further comprising a catholyte tank and an anolyte tank in fluid communication with the cathode cell and the anode cell, respectively.

18. A method of manufacturing an organic electrolyte solution for a redox flow battery, the method comprising:
contacting a solvent, an electrolyte comprising a metal-ligand coordination compound; and a high-molecular weight additive comprising a metal affinic group to manufacture the organic electrolyte solution of claim 1 .

19. The method of claim 18 , wherein the additive comprises a polymer having a backbone selected from at least one selected from a saturated or unsaturated hydrocarbon, a polyester, a polyurethane, a phosphoric ester polymer, and a phosphoric ester-sulfonic acid amine copolymer, and
wherein the polymer has a molecular weight of about 10,000 to about 100,000 Daltons.

20. The method of claim 19 , wherein a hydrogen atom of a backbone of the additive is substituted with the hydrophobic group, wherein the hydrophobic group is at least one selected from a substituted or unsubstituted C 6 to C 7 aryl group, and a substituted or unsubstituted C 1 to C 3 alkyl group.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Park Joung-Won
• Oh Duk-Jin
• Lee Doo-Yeon
• Lee Myung-Jin

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M8/188

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• H01M8/20 Primary

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• H01M10/0564

  the electrolyte being constituted of organic materials only · CPC title

• Y02E60/528

  Cross-Sectional Technologies · mapped topic