Electrode binder composition for nonaqueous electrolyte battery, electrode for nonaqueous electrolyte battery, and nonaqueous electrolyte battery

Patent metadata

Field	Value
Publication number	US-9257703-B2
Application number	US-201113976338-A
Country	US
Kind code	B2
Filing date	Dec 27, 2011
Priority date	Dec 28, 2010
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

Provided is a binder composition for electrodes that has high stability in the form of a liquid composition dissolved or dispersed in a solvent and can improve cycle property of a non-aqueous electrolyte battery. The binder composition used is a binder composition including a polymer A containing 80% by weight or more and 99.9% by weight or less of a repeating unit derived from a monomer including a nitrile group and 0.1% by weight or more and 20% by weight or less of a repeating unit derived from an ethylenically unsaturated compound, wherein a weight-average molecular weight of the polymer A is 500,000 to 2,000,000, and a molecular weight distribution (Mw/Mn) of the polymer A is 13 or smaller.

First claim

The invention claimed is:

1. A binder composition for an electrode of a non-aqueous electrolyte battery, the binder composition comprising a polymer A containing 80% by weight or more and 99.9% by weight or less of a repeating unit derived from a monomer including a nitrile group and 0.1% by weight or more and 20% by weight or less of a repeating unit derived from an ethylenically unsaturated compound, wherein
a weight-average molecular weight of the polymer A is 500,000 to 2,000,000,
a molecular weight distribution (Mw/Mn) of the polymer A is 13 or smaller,
the binder composition further comprises a polymer B containing 10% by weight or more and 40% by weight or less of a repeating unit derived from acrylonitrile or methacrylonitrile, and
the polymer B has an iodine number of 50 g/100 g or lower.

2. The binder composition for an electrode of a non-aqueous electrolyte battery according to claim 1 , wherein a weight ratio of the polymer A to the polymer B (the polymer A/the polymer B) is 3/7 or higher and 7/3 or lower.

3. An electrode for a non-aqueous electrolyte battery, comprising a current collector and an electrode material layer provided on at least one side of the current collector, wherein
the electrode material layer contains an electrode active material and the binder composition for an electrode according to claim 1 , and
a solid content of the binder composition for the electrode with respect to 100 parts by weight of the electrode active material is 0.3 parts by weight or more and 5 parts by weight or less.

4. A non-aqueous electrolyte battery comprising the electrode for a non-aqueous electrolyte battery according to claim 3 .

5. The non-aqueous electrolyte battery according to claim 4 , wherein the non-aqueous electrolyte battery is a lithium ion secondary battery.

6. An electrode for a non-aqueous electrolyte battery, comprising a current collector and an electrode material layer provided on at least one side of the current collector, wherein
the electrode material layer contains an electrode active material and the binder composition for an electrode according to claim 2 , and
a solid content of the binder composition for the electrode with respect to 100 parts by weight of the electrode active material is 0.3 parts by weight or more and 5 parts by weight or less.

7. A non-aqueous electrolyte battery comprising the electrode for a non-aqueous electrolyte battery according to claim 6 .

8. The non-aqueous electrolyte battery according to claim 7 , wherein the non-aqueous electrolyte battery is a lithium ion secondary battery.

9. The binder composition for an electrode of a non-aqueous electrolyte battery according to claim 1 , wherein the binder composition is for a positive electrode.

Assignees

• Sekine Toshiyuki
• Zeon Corp

Inventors

• Sekine Toshiyuki

Classifications

• C08F220/42

  Nitriles · CPC title

• C08F236/12

  with nitriles · CPC title

• C08L33/064

  containing anhydride, COOH or COOM groups, with M being metal or onium-cation · CPC title

• C08K3/04

  Carbon · CPC title

• C08L9/02

  Copolymers with acrylonitrile · CPC title