Substrate for an organic electronic device and an organic electronic device comprising the same

Patent metadata

Field	Value
Publication number	US-9257675-B2
Application number	US-201113819308-A
Country	US
Kind code	B2
Filing date	Sep 6, 2011
Priority date	Sep 6, 2010
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

A substrate including a base substrate; a scattering layer which is formed on the base substrate, includes a binder and scattering particles for scattering light, and has an uneven structure formed on a surface thereof opposite the base substrate; and a planarizing layer which is formed on the scattering layer and has a flat surface formed thereon, is provided. Here, the refractive index Na of the scattering particles and the refractive index Nb of the planarizing layer satisfy the expression |Na−Nb|≧0.3, an organic electronic device including the substrate, and a method of manufacturing the same are provided. Light-extraction efficiency can be improved and the manufacturing process can be simplified without degrading device performance.

First claim

What is claimed is:

1. A substrate for an organic electronic device comprising:
a base substrate;
a scattering layer which is formed on the base substrate, includes a binder and scattering particles for scattering light, and has an uneven structure formed on a surface thereof opposite the base substrate; and
a planarizing layer which is formed on the scattering layer to planarize an uneven surface of the scattering layer,
wherein a refractive index Na of the scattering particles and a refractive index Nb of the planarizing layer satisfy the expression |Na−Nb|≧0.3, and the refractive index Na of the scattering particles is in a range of 2.0 to 3.5 and the refractive index Nb of the planarizing layer is in a range of 1.7 to 2.5.

2. The substrate for an organic electronic device of claim 1 , wherein the scattering particles are formed on the base substrate in a single-layer structure or a stacked structure including at most 5 layers.

3. The substrate for an organic electronic device of claim 1 , wherein the scattering particles have an average diameter of 0.01 μm to 20 μm.

4. The substrate for an organic electronic device of claim 1 , wherein the binder in the scattering layer is an inorganic binder or an organic/inorganic complex binder.

5. The substrate for an organic electronic device of claim 4 , wherein the binder in the scattering layer is at least one selected from the group consisting of silicon oxide, silicon nitride, silicon oxynitride, alumina, and an inorganic or organic/inorganic complex based on a siloxane bond.

6. The substrate for an organic electronic device of claim 1 , wherein the planarizing layer comprises an inorganic binder or an organic/inorganic complex binder.

7. The substrate for an organic electronic device of claim 6 , wherein the inorganic binder or the organic/inorganic complex binder is at least one selected from the group consisting of silicon oxide, silicon nitride, silicon oxynitride, alumina, and an inorganic or organic/inorganic complex based on a siloxane bond.

8. The substrate for an organic electronic device of claim 6 , wherein the planarizing layer further comprises a high-refractive index filler which is at least one selected from the group consisting of alumina, aluminum nitride, zirconium oxide, titanium oxide, cerium oxide, hafnium oxide, niobium pentoxide, tantalum pentoxide, indium oxide, tin oxide, indium tin oxide, zinc oxide, silicon, zinc sulfide, calcium carbonate, barium sulfate and silicon nitride.

9. An organic electronic device having a sequentially stacked structure comprising:
the substrate for an organic electronic device of claim 1 ;
a first electrode;
an organic layer which comprises a light emitting layer and an electron transfer layer doped with an alkali halide, MgF 2 or CaF 2 , wherein the doped electron transfer layer has a thickness of 40 to 100 nm; and
a second electrode.

10. The organic electronic device of claim 9 , wherein the electron transfer layer includes an electron transfer material and an alkali halide, MgF 2 , or CaF 2 with which the electron transfer material is doped, and
the electron transfer material includes a compound containing at least one functional group selected from the group consisting of an imidazole group, an oxazole group, a thiazole group, a quinoline and a phenanthroline group.

11. The organic electronic device of claim 9 , wherein the alkali halide is at least one selected from the group consisting of NaF, CsF, LiF, and KF.

12. The organic electronic device of claim 9 , wherein the alkali halide, MgF 2 , or CaF 2 has a concentration gradient, depending on the thickness of the electron transfer layer.

13. The organic electronic device of claim 9 , wherein introduction and transfer of electrons are simultaneously performed at the electron transfer layer.

14. The organic electronic device of claim 9 , further comprising a metal wiring formed between the first electrode and the organic layer.

15. A method of manufacturing the organic electronic device of claim 9 , comprising:
forming a first electrode;
forming an organic layer including a light emitting layer on the first electrode; and
forming a second electrode on the organic layer,
wherein the forming of the organic layer includes forming an electron transfer layer doped with an alkali halide, MgF 2 , or CaF 2 to a thickness of 40 to 100 nm.

16. The method of claim 15 , wherein the forming of the organic layer includes forming at least one of a hole injection layer, a hole transfer layer, and an electron injection layer on the first electrode in addition to the electron transfer layer.

17. The organic electronic device of claim 9 , wherein the doped electron transfer layer has a thickness of 55 to 85 nm.

18. A method of manufacturing the substrate for an organic electronic device of claim 1 , comprising:
forming the scattering layer on the base substrate using a coating solution including the binder and the scattering particles; and

forming the planarizing layer on the formed scattering layer to have a planarized surface.

Assignees

• Jang Seong Su
• Lee Yeon Keun
• Moon Kyoung Sik
• Son Se Hwan
• Lg Chemical Ltd

Inventors

• Jang Seong Su
• Lee Yeon Keun
• Moon Kyoung Sik
• Son Se Hwan

Classifications

• G02B5/0242

  by means of dispersed particles · CPC title

• H10K2101/00

  Properties of the organic materials covered by group H10K85/00 · CPC title

• H10K50/858

  comprising refractive means, e.g. lenses · CPC title

• H10K71/00

  Manufacture or treatment specially adapted for the organic devices covered by this subclass · CPC title

• H10K50/165

  comprising dopants · CPC title