Structure and method of fabricating a CZTS photovoltaic device by electrodeposition
US-9041141-B2 · May 26, 2015 · US
US9257584B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9257584-B2 |
| Application number | US-201414210497-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 14, 2014 |
| Priority date | Mar 14, 2014 |
| Publication date | Feb 9, 2016 |
| Grant date | Feb 9, 2016 |
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A solar cell device and a method of fabricating the device is described. The solar cell is fabricated by providing a substructure comprising an absorber over a back contact having a P 1 line therein and scribing a P 2 line in the absorber by mechanical scribing and laser scribing after the mechanical scribing. The scribing can be performed with an integrated scriber, including a scribing tip and a light source mounted adjacent the scribing tip and operable concurrently with the scribing tip.
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What is claimed is: 1. A method of fabricating a solar cell comprising: providing a substructure comprising an absorber over a back contact having a P 1 line therein; and scribing a P 2 line through said absorber by: mechanical scribing; and laser scribing after said mechanical scribing. 2. The method as in claim 1 , wherein said providing step comprises: providing a substrate; depositing said back contact over said substrate; scribing said P 1 line through said back contact; and depositing said absorber over said back contact and within said P 1 line. 3. The method as in claim 1 , wherein said scribing step comprises: moving a scribing tip along an area of said substructure to cut a trench, wherein a light source follows said scribing tip; and focusing a beam from said light source on residue within said trench. 4. The method as in claim 3 , wherein a width covered by said beam comprises at least 50% of a width covered by said scribing tip. 5. The method as in claim 3 , wherein a width covered by said beam comprises about 50% to 95% of a width covered by said scribing tip. 6. The method as in claim 1 , wherein said substructure further comprises an interface layer between said back contact and said absorber; and said scribing step further scribes said P 2 line through said interface layer. 7. The method as in claim 6 , wherein said scribing step comprises: moving a scribing tip along an area of said substructure to cut a trench, wherein a light source follows said scribing tip; and focusing a beam from said light source on a portion of said interface layer within said trench. 8. The method as in claim 1 , wherein said scribing step is performed with an integrated scriber comprising: a scribing tip; and a light source mounted adjacent said scribing tip and operable concurrently with said scribing tip. 9. The method as in claim 1 , wherein said scribing step further comprises collecting particles from said P 2 line. 10. The method as in claim 9 , wherein said scribing step comprises: moving a scribing tip along an area of said substructure to cut a trench, wherein a light source follows said scribing tip and a particle collector follows said light source; focusing a beam from said light source on residue within said trench; and removing particles from said trench with said particle collector. 11. A method of fabricating a solar cell comprising: providing a substructure comprising an absorber over a back contact having a P 1 line therein; scribing a P 2 line through said absorber by: mechanical scribing to cut a trench in the substructure and laser scribing within the trench after said mechanical scribing; and depositing a front contact over the absorber and within the trench, wherein the front contact directly connects with the back contact in the P 2 line. 12. The method as in claim 11 , wherein said scribing step further comprises removing absorber residue from within the trench. 13. The method as in claim 11 , wherein said scribing step further comprises removing an interface layer from within the trench. 14. The method as in claim 11 , wherein said substructure further comprises an interface layer between the back contact and absorber and said P 2 line is scribed though the interface layer. 15. The method as in claim 14 , wherein said interface layer comprises Mo(SeS) x . 16. A method of fabricating a solar cell comprising: providing a substructure comprising an absorber over a back contact having a P 1 line therein; and scribing a P 2 line through said absorber by: mechanical scribing with a scribing tip; and laser scribing with a light source after said mechanical scribing, wherein said scribing tip and light source are mounted on a movable base. 17. The method as in claim 16 , wherein said scribing tip and light source are applied to the substructure concurrently. 18. The method as in claim 16 , wherein a beam is applied from said light source having a wavelength ranging from about 1100 nm to about 1250 nm. 19. The method as in claim 16 , wherein a beam is applied from said light source having a power ranging from about 0.1 W to about 5 W. 20. The method as in claim 16 , wherein said movable base further comprises a particle collector mounted adjacent said light source; and the scribing step further comprises removing absorber residue with the particle collector.
Patterning processes to connect the photovoltaic cells, e.g. laser cutting of conductive or active layers · CPC title
comprising Group I-III-VI materials, e.g. CdS/CuInSe2 [CIS] heterojunction photovoltaic cells · CPC title
Manufacture or treatment of devices covered by this subclass (patterning processes to connect thin photovoltaic cells in integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/33; manufacture or treatment of encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/80; manufacture or treatment of integrated devices, or assemblies of multiple devices, comprising at least one element in which radiation controls the flow of current H10F39/00) · CPC title
Structures for the connecting of adjacent photovoltaic cells, e.g. interconnections or insulating spacers · CPC title
Structures for connecting between photovoltaic cells, e.g. interconnections or insulating spacers (between thin-film photovoltaic cells on a single substrate H10F19/35) · CPC title
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