Thermochromic resin composite, method for adjusting clouding point of thermochromic resin composite, and dimmer

Patent metadata

Field	Value
Publication number	US-9256010-B2
Application number	US-201113806035-A
Country	US
Kind code	B2
Filing date	Jun 21, 2011
Priority date	Jun 25, 2010
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

Disclosed are a thermochromic resin composite and a dimmer allowing easy adjustment of a clouding point. The thermochromic resin composite is predominantly composed of an aqueous medium, an amphiphilic linear polymer changeable between a transparent state and an opaque state in the aqueous medium depending on temperature, and an amphiphilic endless polymer changeable between a transparent state and an opaque state in the aqueous medium depending on temperature, and the amphiphilic linear polymer and the amphiphilic endless polymer in the aqueous medium have one clouding point, the clouding point changing in accordance with a mixing ratio of the amphiphilic linear polymer to the amphiphilic endless polymer.

First claim

The invention claimed is:

1. A thermochromic resin composite predominantly comprising: an aqueous medium; an amphiphilic linear polymer changeable between a transparent state and an opaque state in the aqueous medium depending on temperature; and an amphiphilic endless polymer changeable between a transparent state and an opaque state in the aqueous medium depending on temperature, wherein the amphiphilic linear polymer and the amphiphilic endless polymer in the aqueous medium have one clouding point, the clouding point changing in accordance with a mixing ratio of the amphiphilic linear polymer to the amphiphilic endless polymer.

2. The thermochromic resin composite according to claim 1 , wherein a hydrophobic unit or/and a hydrophilic unit is the same between the amphiphilic linear polymer and the amphiphilic endless polymer.

3. The thermochromic resin composite according to claim 1 , wherein the amphiphilic linear polymer is a single-chain polymer, and the amphiphilic endless polymer is a single-ring polymer.

4. The thermochromic resin composite according to claim 1 , wherein the amphiphilic linear polymer is comprised of a linear hydrophilic unit and linear hydrophobic units bonded to both ends of the hydrophilic unit.

5. The thermochromic resin composite according to claim 1 , wherein the amphiphilic linear polymer is a precursor of the amphiphilic endless polymer.

6. The thermochromic resin composite according to claim 1 , wherein the amphiphilic linear polymer is comprised of a hydrophilic chain comprised of a repeating unit of polyethylene oxide represented by a general formula (1) and a hydrophobic chain comprised of a repeating unit represented by a general formula (2):

where n indicates an integer of 10 to 500,

where R 1 indicates a hydrogen atom, a halogen atom or a lower alkyl group, Z 1 indicates a hydrogen atom, a lower alkyl group, a perfluoroalkyl group, an alkyloxy group, a phenyl group substituted by a halogen atom, a lower alkyl group substituted by a halogen atom, an alkyloxy group substituted by a halogen atom, a cyano group, or a group represented by —COOY 1 , m indicates an integer of 1 to 500, and Y 1 indicates a hydrogen atom or a hydrocarbon group.

7. The thermochromic resin composite according to claim 1 , wherein the amphiphilic endless polymer is a ring polymer compound comprised of each repeating unit represented by a general formula (3) or a general formula (4):

where R 2 indicates a hydrogen atom, a halogen atom or a lower alkyl group, Z 2 indicates a hydrogen atom, a lower alkyl group, a perfluoroalkyl group, an alkyloxy group, a phenyl group substituted by a halogen atom, a lower alkyl group substituted by a halogen atom, an alkyloxy group substituted by a halogen atom, a cyano group, or a group represented by —COOY 2 , Y 2 indicates a hydrogen atom or a hydrocarbon group, p indicates an integer of 1 to 500, q indicates a integer of 10 to 500, and R 3 and R 4 each indicate a straight-chain, branched, or ring low molecular chain,

where R 5 and R 6 each indicate a hydrogen atom, a halogen atom or a lower alkyl group, Z 3 and Z 4 each indicate a hydrogen atom, a lower alkyl group, a perfluoroalkyl group, an alkyloxy group, a phenyl group substituted by a halogen atom, a lower alkyl group substituted by a halogen atom, an alkyloxy group substituted by a halogen atom, a cyano group, or a group represented by —COOY 3 , Y 3 indicates a hydrogen atom or a hydrocarbon group, r and s each indicate an integer of 1 to 500, t indicates an integer of 10 to 500, and R 7 , R 8 and R 9 each indicate a straight-chain, branched, or ring low molecular chain.

8. A dimmer including an optical element having a light transmittance decreasing at high temperature and increasing at low temperature, the dimmer comprising the thermochromic resin composite according to claim 1 as the optical element.

9. A method for adjusting a clouding point of a thermochromic resin composite, comprising:
preparing an amphiphilic linear polymer having a clouding point A at which a transparent state and an opaque state change reversibly in an aqueous medium depending on temperature, and an amphiphilic endless polymer having a clouding point B at which a transparent state and an opaque state change reversibly in the aqueous medium depending on temperature; and
adjusting a mixing ratio of the amphiphilic linear polymer to the amphiphilic endless polymer mixed in the aqueous medium so as to have a desired clouding point C at which a transparent state and an opaque state change reversibly, the clouding point C being different from the clouding point A and the clouding point B and within a temperature range of the clouding point A and the clouding point B.

Assignees

• Honda Satoshi
• Yamamoto Takuya
• Tezuka Yasuyuki
• Tokyo Inst Tech

Inventors

• Honda Satoshi
• Yamamoto Takuya
• Tezuka Yasuyuki

Classifications

• G02F1/0147

  based on thermo-optic effects (G02F1/132 takes precedence) · CPC title

• C08G83/008

  Supramolecular polymers · CPC title

• C09K2211/14

  Macromolecular compounds · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• C08F293/005

  using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent · CPC title