Method to produce catalytically active nanocomposite coatings

Patent metadata

Field	Value
Publication number	US-9255238-B2
Application number	US-201113250760-A
Country	US
Kind code	B2
Filing date	Sep 30, 2011
Priority date	Sep 30, 2011
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

A nanocomposite coating and method of making and using the coating. The nanocomposite coating is disposed on a base material, such as a metal or ceramic; and the nanocomposite consists essentially of a matrix of an alloy selected from the group of Cu, Ni, Pd, Pt and Re which are catalytically active for cracking of carbon bonds in oils and greases and a grain structure selected from the group of borides, carbides and nitrides.

First claim

The invention claimed is:

1. A nanocomposite coating base layer consisting essentially of a matrix of an alloy selected from the group of a Cu alloy, a Ni alloy, a Pd alloy, a Pt alloy and a Re alloy and mixtures thereof and grains;
wherein the nanocomposite base layer is about 1% to 10% by weight for the matrix and the grains from about 90% to 99% by weight;
wherein the grains consist essentially of either a) transition metal carbides, nitrides, carbo-nitrides and borides or b) refractory metal carbides, nitrides, carbo-nitrides and borides.

2. A nanocomposite coating comprising:
the nanocomposite base layer consisting essentially of a matrix of an alloy selected from the group of a Cu alloy, a Ni alloy, a Pd alloy, a Pt alloy and a Re alloy and mixtures thereof and grains selected from the group of a boride, a carbide, a carbo-nitride and a nitride;
wherein the nanocomposite base layer is about 1% to 10% by weight for the matrix and the grains from about 90% to 99% by weight; and
a carbon containing layer disposed on the nanocomposite coating, the carbon containing layer formed by disposing an oil on the nanocomposite coating and moving another metal layer against the nanocomposite base layer, thereby catalytically cracking molecules of the disposed oil to form the carbon containing layer.

3. The nanocomposite coating base layer as defined in claim 2 wherein the grains are selected from the group consisting of transition metal carbides, nitrides, carbo-nitrides and borides.

4. The nanocomposite coating base layer as defined in claim 2 wherein the grains are selected from the group consisting of refractory metal carbides, nitrides, carbo-nitrides and borides.

Assignees

• Erdemir Ali
• Eryilmaz Osman Levent
• Urgen Mustafa
• Kazmanli Kursat
• Uchicago Argonne Llc

Inventors

• Erdemir Ali
• Eryilmaz Osman Levent
• Urgen Mustafa
• Kazmanli Kursat

Classifications

• B01J37/347

  Ionic or cathodic spraying; Electric discharge · CPC title

• B01J27/22

  Carbides · CPC title

• C10M2201/061

  Carbides; Hydrides; Nitrides · CPC title

• C10N2010/02

  Groups 1 or 11 · CPC title

• C10N2010/06

  Groups 3 or 13 · CPC title