High purity heterophasic propylene copolymers

Patent metadata

Field	Value
Publication number	US-9255166-B2
Application number	US-73658608-A
Country	US
Kind code	B2
Filing date	Dec 18, 2008
Priority date	Apr 24, 2008
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

High purity heterophasic polypropylene copolymers comprising (A) 73 to 98 wt % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of ≧45 g/10 min and (B) 2 to 27 wt % of an elastomeric copolymer, comprising propylene in an amount of at least 50 wt % of component (B) and at least ethylene and/or one other C 4 to C 10 alpha olefin in an amount of up to 50 wt % of component (B), the heterophasic polypropylene copolymers being obtainable by a multistage polymerization process in the presence of a catalyst system comprising (i) a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol and a phthalic ester and (ii) optionally an organometallic cocatalyst and (iii) an external donor represented by formula (I) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) wherein R 1 and R 2 can be the same or different a represent a hydrocarbon group having 1 to 12 carbon atoms, their production and use.

First claim

We claim:

1. Process for producing high purity heterophasic polypropylene copolymers comprising
(A) 73 to 98 wt. % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of 45 to 500 g/10 min; wherein for the propylene copolymer matrix, the comonomer is ethylene and/or one other C 4 to C 10 alpha-olefin and the comonomer content is 7.0 to 10.0 wt. % of component (A); and
(B) 2 to 27 wt. % of elastomeric copolymers, comprising propylene in an amount of at least 50 wt. % of component (B) and ethylene and/or one other C 4 to C 10 alpha olefin in an amount of 20 to less than 50 wt. % of component (B),
wherein said high purity heterophasic polypropylene copolymers have the following properties: the amount of volatile organic compounds (VOC) is 336 to 408 μgTE/g; the tensile modulus is 1475 to 1835 MPa; and, the flexural modulus is 1384 to 1743 MPa;
said process comprises the steps of:
providing a catalyst system

producing a polypropylene polymer matrix (A) using said catalyst system, wherein said catalyst system comprises a Ziegler-Natta procatalyst (I) which contains a trans-esterification product of lower alcohol having at least C 5 alkyl and phthalic ester, an external donor (III) represented by formula (I) Si(OCH 2 CH 3 ) 3 (NR 1 R 2 ) wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms, and an organometallic cocatalyst (ii) in a first slurry reactor and in a second slurry reactor, both slurry reactors using the same polymerization conditions,
transferring the slurry reactor product into a 1 st GPR
producing an elastomeric copolymer (B) of propylene and ethylene and/or one other C 4 to C 10 alpha olefin in the polymer matrix in the presence of the catalyst system in said 1 st GPR
transferring the 1 st GPR product into a 2 nd GPR and producing a second elastomeric copolymer (B) of propylene and ethylene and/or one other C 4 to C 10 alpha olefin in the polymer matrix in the presence of the catalyst system in said 2 nd GPR, said 1 st and 2 nd copolymers of propylene and ethylene and/or one other C 4 to C 10 alpha olefin may have the same or different composition ratios and
recovering the polymer product for further processing.

2. Process according to claim 1 , wherein the propylene matrix (A) of the heterophasic polypropylene copolymers is a propylene homopolymer.

3. Process according to claim 1 , wherein the elastomeric copolymer (B) is unimodal.

4. Process according to claim 1 , wherein the elastomeric copolymer (B) comprises propylene and ethylene as the only polymerizable units.

5. High purity hetorophasic polypropylene copolymers having an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of above 35 g/10 min, said copolymers comprise
(A) 73 to 98 wt. % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load)of 45 to 500 g/10 min; wherein for the propylene copolymer matrix, the comonomer is ethylene and/or one other C 4 to C 10 alpha-olefin and the comonomer content is 7.0 to 10.0 wt. % of component (A); and
(B) 2 to 27 wt. % of an elastomeric copolymer, comprising propylene in an amount of at least 50 wt. % of component (B) and ethylene and/or one other C 4 to C 10 alpha olefin in an amount of 20 to less than 50 wt. % of component (B),
wherein said high purity heterophasic polypropylene copolymers have the following properties: the amount of volatile organic compounds (VOC) is 336 to 408 μgTE/g; the tensile modulus is 1475 to 1835 MPa: and, the flexural modulus is 1384 to 1743 MPa;
the heterophasic polypropylene copolymers being obtained by a multistage polymerzation procees in the presence of a catalyst system comprising
(i)a Ziegler-Natta procatalyst which contains a trans-esterification product of a lower alcohol having at least C 5 alkyl and a phthalic ester and
(ii) an organometallic cocatalyst and
(iii)an external donor represented by formula (I)
Si(OCH 2 CH 3 ) 3 (NR 1 R 2 )
wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms.

6. High purity heterophasic polypropylene copolymers according to claim 5 , wherein the propylene matrix (A) of said heterophasic polypropylene copolymers is a propylene homopolymer.

7. The high purity heterophasic polypropylene copolymers according to claim 5 used in the manufacture of moulded articles and injection molded articles.

8. A process for producing high purity heterophasic polypropylene copolymers comprising
(A) 73 to 98 wt. % of a propylene homopolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of 45 to 500 g/10 min and
(B) 2 to 27 wt. % of elastomeric copolymers, comprising propylene in an amount of at least 50 wt. % of component (B) and at least ethylene and/or one other C4 to C10 alpha olefin in an amount of 20 to less than 50 wt. % of component (B) in a multistage polymerization process, wherein said high purity heterophasic polypropylene copolymers have the following properties: the amount of volatile organic compounds (VOC) is 336 to 408 μgTE/g; the tensile modulus is 1475 to 1835 MPa; and, the flexural modulus is 1384 to 1743 MPa;
said process for producing comprising process steps of:
providing a catalyst system
producing a polypropylene polymer matrix (A) using said catalyst system, said catalyst system comprising a Ziegler-Natta procatalyst (i) which contains a trans-esterification product of lower alcohol having at least C 5 alkyl and a phthalic ester, (ii)an organometallic cocatalyst and an external donor (iii) represented by formula (I) Si(OCH 2 CH 3 ) 3(NR 1 R 2 ) wherein R 1 and R 2 can be the same or different and represent a hydrocarbon group having 1 to 12 carbon atoms, and an organometallic cocatalyst (ii) in a first slurry reactor and in a second slurry reactor, both slurry reactors using the same polymerization conditions,
transferring the slurry reactor product into a 1 st GPR
producing an elastomeric copolymer (B) of propylene and a ethylene and/or one other C 4 to C 10 alpha olefin in the polymer matrix in the presence of the catalyst system in said 1 st GPR
transferring the 1 st GPR product into a 2 nd GPR and producing a second elastomeric copolymer (B) of propylene and one comonomer which is ethylene or one other C 4 to C 10 alpha olefin in the polymer matrix in the presence of the catalyst system in said 2 nd GPR, said 1 st and 2 nd copolymers of propylene and ethylene and/or one other C 4 to C 10 alpha olefin may have the same or different composition ratios and
recovering the polymer product for further processing.

9. An article produced from heterophasic polypropylene copolymers, said heterophasic polypropylene copolymers having MFR 2 in accordance with ISO 1133 (230° C., 216 kg load) of above 35 g/10 min, said copolymer comprising
(A) 73 to 98 wt % of a propylene homo- or copolymer matrix with an MFR 2 in accordance with ISO 1133 (230° C., 2.16 kg load) of 45 to 500 g/10 min; wherein for the propylene copolymer matrix, the comonomer is ethylene and/or one other C 4 to C 10 alpha-olefin and the comonomer content is 7.0 to 10.0 wt % of component (A); and
(B) 2 to 27 wt % of an elastormeric copolymer, comprising propylene in an amount of at least 50 wt % of component (B) and ethylene and/or one other C 4 to C 10 alpha olefin in an amount of 20 to less than 50 wt % of component (B),
wherein said high purity heterophasic polypropylene copolymers have the following properties: the amount of volatile organic compounds (VOC) is 336 to 408 μgTE/g; the tensile modulus is 1475 to 1835 MPa; and, the flexural modulus is 1384 to 1743 M

Assignees

• Grein Christelle
• Bernreitner Klaus
• Vestberg Torvald
• Borealis Ag

Inventors

• Grein Christelle
• Bernreitner Klaus
• Vestberg Torvald

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L23/12

  Polypropene · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F210/06 Primary

  Propene · CPC title