Method for producing conjugated diolefin and apparatus for production

Patent metadata

Field	Value
Publication number	US-9255041-B2
Application number	US-201214118166-A
Country	US
Kind code	B2
Filing date	May 9, 2012
Priority date	May 19, 2011
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

A method for producing a conjugated diolefin that can suppress reaction byproducts with high boiling point from remaining in steps following a quenching step by a quenching tower, and producing a conjugated diolefin (e.g., 1,3-butadiene) that can be used as a raw material for synthetic rubber, resin and the like, even when using an industrial grade mixed hydrocarbon that may not necessarily have a high purity as a raw material to produce the conjugated diolefin (e.g., butadiene). The method includes a step of producing a product gas by reaction containing a conjugated diolefin by feeding a hydrocarbon containing a monoolefin having 4 or more carbon atoms and oxygen to a reactor accommodated with a catalyst containing a metal oxide and a carrier, and a step of sending the product gas by reaction to a quenching tower and washing with a quenching agent (e.g., an organic amine aqueous solution).

First claim

What is claimed is:

1. A method for producing a conjugated diolefin, comprising:
a step of feeding a hydrocarbon containing a monoolefin having 4 or more carbon atoms and oxygen to a reactor accommodated with a catalyst which comprises a metal oxide and a carrier to produce a product gas by reaction containing a conjugated diolefin; and
a step of sending the product gas by reaction to a quenching tower and washing the gas with a quenching agent, wherein an organic amine aqueous solution is used as the quenching agent.

2. The method for producing the conjugated diolefin according to claim 1 , wherein an aromatic organic solvent is used in combination as the quenching agent.

3. The method for producing the conjugated diolefin according to claim 1 or 2 , wherein a withdrawn liquid from the quenching tower contains at least one compound selected from the group consisting of 4-methyl-4-formyl-1-cyclohexene, methacrolein, methacrylic acid, benzoic acid, acetic acid, acrylic acid, and an organic amine salt thereof.

4. The method for producing the conjugated diolefin according to claim 1 or 2 , wherein the quenching tower has a plurality of vertical sections, an aromatic organic solvent is used as the quenching agent at a lowest section among the plurality of sections, and an organic amine aqueous solution is used as the quenching agent at a section above the lowest section.

5. The method for producing the conjugated diolefin according to claim 1 or 2 , wherein the organic amine contains at least one compound selected from the group consisting of monoethanolamine, diethanolamine, and triethanolamine.

6. The method for producing the conjugated diolefin according to claim 2 , wherein the aromatic organic solvent contains at least one compound selected from the group consisting of o-xylene, m-xylene, p-xylene, and a mixed xylene.

7. The method for producing the conjugated diolefin according to claim 1 or 2 , wherein the metal oxide is represented by the following experimental formula (1):
Mo 12 Bi p Fe q A a B b C c D d E e O x   (1)

wherein A represents at least one element selected from the group consisting of nickel and cobalt; B represents at least one element selected from the group consisting of alkali metal elements; C represents at least one element selected from the group consisting of magnesium, calcium, strontium, barium, zinc, and manganese; D represents at least one element selected from the group consisting of rare earth elements; E represents at least one element selected from the group consisting of chromium, indium, and gallium; O represents oxygen; p, q, a, b, c, d, e, and x denote an atomic ratio of bismuth, iron, A, B, C, D, E, and O, respectively, to 12 molybdenum atoms, where 0.1≦p≦5, 0.5≦q≦8, 0≦a≦10, 0.02≦b≦2, 0≦c≦5, 0≦d≦5, and 0≦e≦5; and x denotes the number of oxygen atoms required to satisfy valence requirements of other elements that are present.

8. The method for producing the conjugated diolefin according to claim 1 or 2 , wherein the reactor is a fluidized bed reactor.

Assignees

• Yano Hiroyuki
• Watanabe Haruhiko
• Asahi Kasei Chemicals Corp

Inventors

• Yano Hiroyuki
• Watanabe Haruhiko

Classifications

• C07C2523/02

  of the alkali- or alkaline earth metals or beryllium · CPC title

• C07C2521/06

  Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof · CPC title

• B01J2523/22

  Magnesium · CPC title

• B01J23/883

  and nickel · CPC title

• C08F36/06

  Butadiene · CPC title