Method of making a transparent metal oxide electrode

Patent metadata

Field	Value
Publication number	US-9251935-B2
Application number	US-201314399849-A
Country	US
Kind code	B2
Filing date	May 8, 2013
Priority date	May 8, 2012
Publication date	Feb 2, 2016
Grant date	Feb 2, 2016

Abstract

The present invention relates to a method for enhancing the conductivity of an undoped transparent metal oxide to obtain a transparent conductive oxide (TCO) electrode. More in particular it relates to such a method comprising the steps of providing a transparent metal oxide, applying a UV transparent barrier layer on the transparent metal oxide, and irradiating the transparent metal oxide with UV radiation after applying the barrier layer.

First claim

The invention claimed is:

1. Method of manufacturing a device having a transparent metal oxide electrode, the method comprising the steps of
providing a transparent metal oxide,
applying a substantially UV transparent barrier layer on the transparent metal oxide,

irradiating the transparent metal oxide with UV radiation,
wherein the barrier layer is applied before irradiating the transparent metal oxide, such that the UV radiation is provided to the transparent metal oxide through the UV transparent barrier layer before completing manufacture of the device.

2. Method according to claim 1 comprising the step of depositing the transparent metal oxide on a carrier layer.

3. Method according to claim 2 wherein the transparent metal oxide is deposited on a carrier layer before applying the barrier layer on the transparent metal oxide.

4. Method according to claim 1 , wherein the transparent metal oxide comprises zinc oxide.

5. Method according to claim 1 wherein the transparent metal oxide has a square resistance of at least 100 Ohm/sq before the irradiation and wherein the step of irradiating the transparent metal oxide with UV radiation is performed irradiating the metal oxide by means UV irradiation from a UV source for a duration that, under the conditions of the irradiation, decreases the square resistance of the transparent metal oxide to below 100 Ohm/sq.

6. Method according to claim 1 , wherein the transparent metal oxide is irradiated with UV radiation during ten minutes or less.

7. Method according to claim 4 , wherein the transparent metal oxide is heated during providing the UV radiation up to a temperature higher than room temperature.

8. Method according to claim 1 , wherein the UV transparent barrier layer comprises aluminium oxide.

9. Method according to claim 4 , wherein zinc oxide is deposited by Plasma Enhanced Chemical Vapour Deposition on the carrier layer.

10. Method according to claim 7 wherein the barrier layer is deposited by spatial Atomic Layer Deposition on the transparent metal oxide.

11. Method according to claim 1 , wherein the device is photovoltaic cell of the CIGS type, the transparent metal oxide electrode being a zinc oxide electrode, the method further comprising the step of providing a buffer layer between the barrier layer and the transparent metal oxide.

12. Method according to claim 4 , wherein step of irradiating the transparent metal oxide with UV radiation is performed by irradiating the transparent metal oxide from a UV source for a duration so that the carrier density of the zinc oxide is increased to 1×10 20 cm −3 or higher after the irradiation.

13. Method according to claim 4 , wherein the step of irradiating the transparent metal oxide with UV radiation is performed by irradiating the transparent metal oxide from a UV source for a duration that increases the carrier density the carrier mobility of the zinc oxide to 40 cm 2 /Vs or higher after the irradiation.

14. Method according to claim 1 , comprising providing a top electrical contact on a part of the transparent metal oxide, extending through the barrier layer to provide external electrical contact.

15. Method according to claim 1 , comprising providing a top electrical contact on a part of the transparent metal oxide, the barrier layer covering the top electrical contact.

16. Method according to claim 5 wherein the step of irradiating the transparent metal oxide with UV radiation is performed irradiating the metal oxide by means UV irradiation from a UV source for a duration that, under the conditions of the irradiation, decreases the square resistance of the transparent metal oxide to below 20 Ohm/sq.

17. Method according to claim 1 , wherein the device is a photovoltaic cell.

18. Method of making a transparent metal oxide electrode, the method comprising the steps of
providing a transparent metal oxide,
applying a substantially UV transparent barrier layer comprising aluminum oxide on the transparent metal oxide,
irradiating the transparent metal oxide with UV radiation,

wherein the barrier layer is applied before irradiating the transparent metal oxide, such that the UV radiation is provided to the transparent metal oxide through the UV transparent barrier layer.

19. Method of making a photovoltaic cell of the CIGS type comprising a zinc oxide electrode the method comprising making the zinc oxide electrode by
providing a transparent zinc oxide layer,
providing a buffer layer on the zinc oxide layer
applying a substantially UV transparent barrier layer oxide on the transparent zinc oxide,
irradiating the transparent zinc oxide with UV radiation,

wherein the barrier layer is applied before irradiating the transparent zinc oxide, such that the UV radiation is provided to the transparent zinc oxide through the UV transparent barrier layer and the buffer layer.

Assignees

• TNO

Inventors

• Illiberi Andrea
• Grob Frank Theodoor Johannes
• Poodt Paulus Willibrordus George
• Winands Gerardus Johan Jozef
• Bolt Pieter Jan

Classifications

• H10F77/1694

  the films including Group I-III-VI materials, e.g. CIS or CIGS · CPC title

• H10F71/00

  Manufacture or treatment of devices covered by this subclass (patterning processes to connect thin photovoltaic cells in integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/33; manufacture or treatment of encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/80; manufacture or treatment of integrated devices, or assemblies of multiple devices, comprising at least one element in which radiation controls the flow of current H10F39/00) · CPC title

• H01B13/003 Primary

  using irradiation · CPC title

• C09C1/00 Primary

  Treatment of specific inorganic materials other than fibrous fillers (tenebrescent materials C09K9/00; luminescent materials C09K11/00); Preparation of carbon black · CPC title

• H01B1/08

  oxides · CPC title