Recyclable polyarylene sulfide and preparation method thereof

Patent metadata

Field	Value
Publication number	US-9249263-B2
Application number	US-201113582874-A
Country	US
Kind code	B2
Filing date	Feb 28, 2011
Priority date	Mar 9, 2010
Publication date	Feb 2, 2016
Grant date	Feb 2, 2016

Abstract

Embodiments of the present invention relate to recyclable polyarylene sulfide that may exhibit and maintain excellent mechanical properties, particularly does not exhibit decrease in melt viscosity when it is molten, and thus, exhibit little deterioration of mechanical properties, and a method for preparing the same. The polyarylene sulfide has initial melt viscosity measured at 300° C. of 300 to 6000 poise, and melt viscosity after heat treated and molten at 300° C., equal to or greater than the initial melt viscosity.

First claim

What is claimed is:

1. Polyarylene sulfide having initial melt viscosity measured at 300° C. of 500 to 4,000 poise, and melt viscosity after heat treated and molten at 300° C., equal to or greater than the initial melt viscosity, and melting point (Tm) of 270 to 285° C.,
wherein melt viscosity change rate as defined by the following Equation 1 is 0 to 20%:
Melt viscosity change rate(%)=100(MV f /MV i −1)  [Equation 1]

in the Equation 1, MV i denotes the initial melt viscosity of polyarylene sulfide, and MV f is the melt viscosity of polyarylene sulfide after heat treating the polyarylene sulfide at 300° C. and melting it;
wherein the polyarylene sulfide is produced by a method comprising polymerizing a diiodide aromatic compound and an initial amount of a sulfur compound;
adding an additional amount of sulfur compound at a point after the addition of the initial amount of a sulfur compound, wherein the polyarylene sulfide has iodine content of 0.8 wt % or less.

2. The polyarylene sulfide according to claim 1 , wherein the MV f is melt viscosity measured under shear rate of 1 rad/s in a plate-plate rheometer, 10 minutes after heat treating the polyarylene sulfide under inert gas atmosphere at 300° C. for 3 minutes to melt it.

3. The polyarylene sulfide according to claim 1 , wherein the polyarylene sulfide has number average molecular weight of 3,000 to 1,000,000.

4. The polyarylene sulfide according to claim 3 , wherein the polyarylene sulfide has number average molecular weight of 3,000 to 50,000.

5. The polyarylene sulfide according to claim 1 , wherein the polyarylene sulfide has a dispersion degree of 2.0 to 4.0 as defined by the ratio of weight average molecular weight to number average molecular weight.

6. A method for preparing the polyarylene sulfide of claim 1 , comprising polymerization reaction of reactants including diiodide aromatic compounds, sulfur compounds, and based on 100 parts by weight of the diiodide aromatic compounds, 0.05 to 10 parts by weight of a polymerization terminator.

7. The method according to claim 6 , wherein the diiodide aromatic compounds are included in the reactants in the content of 0.9 moles or more based on the sulfur compounds.

8. The method according to claim 6 , wherein the polymerization terminator is at least one selected from the group consisting of diphenyl sulfide, diphenyl ether, diphenyl, benzophenone, monoiodoaryl compounds, benzothiazole, benzothiazolesulfenamide, thiuram, dithiocarbamate and diphenyl disulfide.

9. The method according to claim 6 , wherein the diiodide aromatic compound is at least one selected from the group consisting of diiodobenzene, diiodonaphthalene, diiodobiphenyl, diiodobisphenol, and diiodobenzophenone.

10. The method according to claim 6 , wherein the polymerization reaction is conducted for 1 to 30 hours while increasing temperature and decreasing pressure under the initial reaction conditions of temperature of 180 to 250° C. and pressure of 50 to 450 torr to the final temperature of 270 to 350° C. and the final pressure of 0.001 to 20 torr.

11. The method according to claim 6 , further comprising melt mixing the reactants including the diiodide aromatic compounds, the sulfur compounds, and the polymerization terminator, before the polymerization reaction.

12. The method according to claim 6 , wherein the polymerization reaction is progressed in the presence of a nitrobenzene-based catalyst.

13. A molded product including the polyarylene sulfide according to claim 1 .

14. The molded product according to claim 13 , wherein the molded product is in the form of a film, a sheet or fiber.

Assignees

• Kim Sung-Gi
• Cha Il-Hoon
• Sk Chemicals Co Ltd

Inventors

• Kim Sung-Gi
• Cha Il-Hoon

Classifications

• C08G75/02 Primary

  Polythioethers · CPC title

• C08J2381/04

  Polysulfides · CPC title

• C08G75/14

  Polysulfides · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08G75/16 Primary

  by polycondensation of organic compounds with inorganic polysulfides · CPC title