Resin, and arf dry photoresist composition comprising same and application
US-2024302749-A1 · Sep 12, 2024 · US
US9249247B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9249247-B2 |
| Application number | US-201013503750-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 15, 2010 |
| Priority date | Nov 16, 2009 |
| Publication date | Feb 2, 2016 |
| Grant date | Feb 2, 2016 |
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The present invention relates to acrylic emulsion polymers having excellent hair styling properties as well as their use in hair care preparations in particular hair styling preparations.
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The invention claimed is: 1. A cosmetic composition comprising: (a) an acrylic emulsion polymer which is an emulsion polymerized reaction product of a monomer mixture of raw monomer materials consisting of methacrylic acid, n-butyl methacrylate, ethyl acrylate, ethyl methacrylate, and less than 5 wt. %, based on 100 wt. % of the monomer mixture, of impurities or additives which may be present in the raw monomer materials, and (b) a cosmetically acceptable carrier. 2. The cosmetic composition according to claim 1 , wherein the composition comprises 0.01-20 wt. %, based on total weight of the cosmetic composition, of the acrylic emulsion polymer. 3. The cosmetic composition according to claim 2 , wherein the composition comprises 0.05-10 wt. % of the acrylic emulsion polymer. 4. The cosmetic composition according to claim 1 , wherein the monomer mixture consists of 10-30 wt. % of methacrylic acid, 40-60 wt. % of n-butyl methacrylate, 5-15 wt. % of ethyl acrylate and 10-30 wt. % of ethyl methacrylate, and less than 5 wt. % of impurities or additives, based on 100 wt. % of the monomer mixture. 5. The cosmetic composition according to claim 1 , wherein the monomer mixture consists of 17-22 wt. % of methacrylic acid, 45-56 wt. % of n-butyl methacrylate, 9-15 wt. % of ethyl acrylate and 15-25 wt. % of ethyl methacrylate, and less than 5 wt. % of impurities or additives, based on 100 wt. % of the monomer mixture. 6. The cosmetic composition according to claim 1 , wherein the ethyl methacrylate (EMA) and ethyl acrylate (EA) in the monomer mixture are present in an amount to provide a coefficient of EMA to EA (w/w) in a range of 4 to 1. 7. The cosmetic composition according to claim 6 , wherein the coefficient of EMA to EA (w/w) is in the range of 2 to 1. 8. The cosmetic composition according to claim 6 , wherein the coefficient of EMA to EA (w/w) is in the range of about 2.0 to 1.3. 9. The cosmetic composition according to claim 1 , wherein the methacrylic acid in the monomer composition is present in an amount less than 25 wt. %. 10. A hair styling preparation which comprises the cosmetic composition according to claim 1 . 11. The hair styling preparation according to claim 10 , wherein the hair styling preparation is in the form of a styling cream, styling gel, liquid hair-setting preparation, hair foams or hairspray. 12. The hair styling preparation according to claim 10 , wherein the hair styling preparation is an aerosol hairspray. 13. The hair styling preparation according to claim 10 , which further comprises at least one additional hair fixative resin. 14. A hair styling polymer which comprises an acrylic emulsion polymer which is an emulsion polymerization reaction product of a monomer mixture consisting of methacrylic acid, n-butyl methacrylate, ethyl acrylate and ethyl methacrylate, and less than 5 wt. % of impurities or additives, based on 100 wt. % of the monomer mixture.
C3-(meth)acrylate, e.g. (iso)propyl (meth)acrylate · CPC title
Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title
Preparations for styling the hair, e.g. by temporary shaping or colouring · CPC title
Chemistry & Metallurgy · mapped topic
with acrylic or methacrylic acids · CPC title
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