Graphene-based multi-junctions flexible solar cell

Patent metadata

Field	Value
Publication number	US-9249016-B2
Application number	US-201213419001-A
Country	US
Kind code	B2
Filing date	Mar 13, 2012
Priority date	Mar 29, 2011
Publication date	Feb 2, 2016
Grant date	Feb 2, 2016

Abstract

This disclosure relates to structures for the conversion of light into energy. More specifically, the disclosure describes devices for conversion of light to electricity using photovoltaic cells comprising graphene.

First claim

What is claimed is:

1. A multijunction solar cell comprising:
a plurality of sub-cells, at least two sub-cells of the plurality of sub-cells having a different band gap energy, wherein at least one of the plurality of sub-cells comprises a first monoatomic graphene layer stacked with a second monoatomic graphene layer,
and wherein the at least one of the plurality of sub-cells also comprises an n-type dopant distributed with the entire first monoatomic graphene layer and a p-type dopant distributed with the entire second monoatomic graphene layer.

2. The multijunction solar cell of claim 1 , wherein the plurality of sub-cells comprise more than two sub-cells.

3. The multijunction solar cell of claim 2 , wherein the plurality of sub-cells comprises three or more sub-cells.

4. The multijunction solar cell of claim 1 , wherein the different band gap energy decreases in subsequent sub-cells more distal from incident electromagnetic radiation.

5. The multijunction solar cell of claim 1 , wherein the solar cell comprises a plurality of sub-cells each having a band-gap difference of about 0.25 eV or more compared to an immediately adjacent sub-cell.

6. The multijunction solar cell of claim 1 , wherein the solar cell comprises a plurality of sets of sub-cells, each set comprising a plurality of sub-cells and each sub-cell within a set comprising similar band gaps and each different set comprising different band gaps.

7. The multijunction solar cell of claim 1 , further comprising a transparent or translucent conductive substrate separating and in contact with each sub-cell.

8. The multijunction solar cell of claim 7 , further comprising an anti-reflective coating and metal contact at the surface closest to the light source and a metal contact at the surface furthest from the light source, the contacts separated by the plurality of sub-cells.

9. The multijunction solar cell of claim 1 , wherein the n-type dopant is nitrogen or phosphorous.

10. The multijunction solar cell of claim 1 , wherein the p-type dopant is boron or aluminum.

11. A multijunction solar cell of claim 1 ,
wherein the at least one of the plurality of sub-cells is a first sub-cell, the solar cell comprising:
a top metal contact and an antireflective coating;
the first sub-cell comprising:
a first transparent or translucent conductive layer in contact with the top metal contact;
the first monoatomic graphene layer;
the second monoatomic graphene layer, wherein both the first and second graphene layers have the same band gap;

a second sub-cell beneath the first sub-cell, the second sub-cell comprising:
a second transparent or translucent conductive layer;
a third monoatomic graphene layer;
a fourth monoatomic graphene layer stacked with the third monoatomic graphene layer,
wherein both the third and fourth monoatomic graphene layers have the same band gap and wherein the band gap of the third and fourth monoatomic graphene layers is the same or smaller than the band gap of the first sub-cell; and
a bottom metal contact.

12. The multijunction solar cell of claim 11 , wherein one or more additional sub-cells separate the first and second sub-cells.

13. The multijunction solar cell of claim 1 , wherein the at least one of the plurality of sub-cells comprises a third monoatomic graphene layer stacked with the first and second monoatomic graphene layers.

14. A multijunction solar cell, comprising:
a first sub-cell comprising:
a first monoatomic graphene layer;
a second monoatomic graphene layer in contact with the first monoatomic graphene layer;
a first n-type dopant distributed with the entire first monoatomic graphene layer; and
a first p-type dopant distributed with the entire second monoatomic graphene layer, wherein both the first and the second monoatomic graphene layers have the same first band gap;

a first transparent or translucent layer in contact with either the first monoatomic graphene layer or the second monoatomic graphene layer; and
a second sub-cell beneath the first transparent or translucent layer, the second sub-cell comprising:
a third monoatomic graphene layer;
a fourth monoatomic graphene layer in contact with the third monoatomic graphene layer,
a second n-type dopant distributed with the entire third monoatomic graphene layer; and
a second p-type dopant distributed with the entire fourth monoatomic graphene layer, wherein both the third and the fourth monoatomic graphene layers have the same second band gap, the second band gap being smaller than the first band gap.

15. The multijunction solar cell of claim 14 , comprising:
a second transparent or translucent layer in contact with either the third monoatomic graphene layer or the fourth monoatomic graphene layer; and
a third sub-cell beneath the second transparent or translucent layer, the third sub-cell comprising:
a fifth monoatomic graphene layer;
a sixth monoatomic graphene layer in contact with the fifth monoatomic graphene layer,
a third n-type dopant distributed with the entire fifth monoatomic graphene layer; and
a third p-type dopant distributed with the entire sixth monoatomic graphene layer, wherein both the fifth and the sixth monoatomic graphene layers have the same third band gap, the third band gap being smaller than the second band gap.

16. The multijunction solar cell of claim 14 , wherein the first and the second monoatomic graphene layers are the only monoatomic graphene layers in the first sub-cell.

Assignees

• Aria Adrianus I
• Gharib Morteza
• California Inst Of Techn

Inventors

• Aria Adrianus I
• Gharib Morteza

Classifications

• H10F71/1395

  for thin-film devices · CPC title

• H10F19/40

  comprising photovoltaic cells in a mechanically stacked configuration · CPC title

• H10F10/142

  comprising multiple PN homojunctions, e.g. tandem cells · CPC title

• H10F71/121 Primary

  The active layers comprising only Group IV materials · CPC title

• H10F71/00 Primary

  Manufacture or treatment of devices covered by this subclass (patterning processes to connect thin photovoltaic cells in integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/33; manufacture or treatment of encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells H10F19/80; manufacture or treatment of integrated devices, or assemblies of multiple devices, comprising at least one element in which radiation controls the flow of current H10F39/00) · CPC title