Catalyst composition

Patent metadata

Field	Value
Publication number	US-9243539-B2
Application number	US-201313912248-A
Country	US
Kind code	B2
Filing date	Jun 7, 2013
Priority date	Jun 19, 2012
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

A catalyst composition comprises a mixed metal catalyst which comprises unalloyed palladium and palladium-gold alloy disposed on a support, wherein the palladium-gold alloy is enriched in gold and at least one promoter in which said promoter comprises at least one reducible metal oxide.

First claim

The invention claimed is:

1. A catalytic convertor comprising a substrate comprising a substrate monolith coated with a catalyst composition comprising a mixed metal catalyst supported on a support, wherein the mixed metal catalyst comprises unalloyed palladium and palladium-gold alloy disposed on the support, and at least one promoter, wherein the palladium-gold alloy is enriched in gold, the at least one promoter comprises at least one reducible metal oxide, wherein the at least one reducible metal oxide is at least one oxide of manganese, iron, tin, copper, cobalt, titanium and cerium, and wherein the support is particulate ceria or a mixed oxide or composite oxide of particulate ceria with alumina.

2. A catalytic convertor according to claim 1 , wherein the atomic ratio of Pd:Au in the mixed metal catalyst is from 100:1 to 1:100.

3. A catalytic convertor according to claim 1 , wherein the weight ratio of Pd:Au in the mixed metal catalyst is >1:1.

4. A catalytic convertor according to claim 1 , wherein the amount of palladium and gold in the mixed metal catalyst is from 0.5-10 wt %.

5. A catalytic convertor according to claim 1 , wherein the at least one reducible metal oxide is at least one oxide of iron and cerium.

6. A catalytic convertor according to claim 5 , wherein the at least one reducible metal oxide is ceria.

7. A catalytic convertor according to claim 1 , wherein the promoter and support is ceria.

8. A catalytic convertor according to claim 1 , wherein the promoter and support is a mixed oxide or composite oxide of particulate ceria with alumina.

9. A catalytic convertor according to claim 1 , further comprising platinum located on a separate and distinct metal oxide support to the mixed metal catalyst.

10. A catalytic convertor according to claim 9 , wherein the separate and distinct metal oxide support also contains palladium.

11. A catalytic convertor according to claim 9 , wherein the mixed metal catalyst is on the at least one reducible metal oxide acting as both the at least one promoter and the support; the platinum is on the separate and distinct metal oxide support to the mixed metal catalyst; and both the mixed metal catalyst and the platinum are disposed in the same washcoat layer.

12. A catalytic convertor according to claim 9 , wherein the platinum on the separate and distinct metal oxide support is disposed in a layer under an overlayer comprising the supported mixed metal catalyst with the at least one promoter.

13. A catalytic convertor according to claim 1 , wherein the substrate monolith is a honeycomb flow-through monolith or a filter.

14. A catalytic convertor according to claim 1 , wherein the at least one reducible oxide is combined with a stabilizer or combined in a composite or mixed oxide with a refractory oxide.

15. A catalytic convertor according to claim 14 , wherein the at least one reducible oxide is a mixed oxide selected from manganese oxide with zirconium and ceria with zirconium.

16. A lean burn internal combustion engine exhaust gas emission treatment system comprising a catalytic convertor according to claim 1 .

17. An apparatus comprising a lean burn internal combustion engine and a lean burn internal combustion engine gas emission treatment system according to claim 16 .

18. A vehicle comprising an apparatus according to claim 17 .

Assignees

• Johnson Matthey Plc

Inventors

• Phillips Paul Richard
• Raj Agnes Suganya
• Rajaram Raj Rao

Classifications

• B01J37/035 Primary

  Precipitation on carriers · CPC title

• B01D2258/012

  Diesel engines and lean burn gasoline engines · CPC title

• B01D2255/2073

  Manganese · CPC title

• B01D2255/106

  Gold · CPC title

• B01D2255/2065

  Cerium · CPC title