Method for producing aromatic hydrocarbons

Patent metadata

Field	Value
Publication number	US-9243192-B2
Application number	US-201013138064-A
Country	US
Kind code	B2
Filing date	Mar 26, 2010
Priority date	Mar 27, 2009
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

A method for producing aromatic hydrocarbons by bringing a feedstock derived from a fraction containing a light cycle oil produced in a fluid catalytic cracking into contact with a catalyst containing a crystalline aluminosilicate, wherein the proportion of the naphthene content within the feedstock is adjusted so as to be greater than the proportion of the naphthene content in the fraction containing the light cycle oil, and the contact between the feedstock and the catalyst is performed under a pressure within a range from 0.1 MPaG to 1.0 MPaG.

First claim

The invention claimed is:

1. A method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number, comprising contacting a feedstock derived from a fraction comprising a light cycle oil produced in a fluid catalytic cracking unit with a catalyst comprising a crystalline aluminosilicate in the absence of molecular hydrogen, wherein
the feedstock has a 10 volume % distillation temperature of at least 140° C., and a 90 volume % distillation temperature of not more than 360° C.,
a proportion of a saturated, multi-branched naphthene content in the feedstock is adjusted by mixing the fraction comprising the light cycle oil with a hydrotreated oil or by partially hydrogenating the fraction comprising the light cycle oil so that a proportion of the saturated, multi-branched naphthene content in the feedstock is greater than a proportion of a saturated, multi-branched naphthene content in the fraction comprising the light cycle oil, and
the contacting the feedstock with the catalyst is performed under a pressure within a range from 0.1 MPaG to 1.0 MPaG, and a contact time between the feedstock and the catalyst during the contacting the feedstock with the catalyst is within a range from 5 seconds to 300 seconds, and
wherein the proportion of the saturated, multi-branched naphthene content in the feedstock is at least 27% by mass.

2. The method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number according to claim 1 , wherein the proportion of the saturated, multi-branched naphthene content in the feedstock is adjusted by mixing the fraction comprising the light cycle oil with a partially hydrogenated product of the fraction comprising the light cycle oil.

3. The method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number according to claim 1 , wherein the saturated, multi-branched naphthene comprises mainly naphthene components of 8 or more carbon number.

4. The method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number according to claim 1 , wherein the catalyst further comprises at least one metal selected from the group consisting of gallium and zinc.

5. The method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number according to claim 1 , wherein a mass ratio of the naphthene content to a polycyclic aromatic hydrocarbon content in the feedstock is within a range from 0.1 to 5.0.

Assignees

• Yanagawa Shinichiro
• Aoki Yuko
• Hayasaka Kazuaki
• Jx Nippon Oil & Energy Corp

Inventors

• Yanagawa Shinichiro
• Aoki Yuko
• Hayasaka Kazuaki

Classifications

• C10G45/54

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10G49/007

  in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment · CPC title

• C10G35/095 Primary

  containing crystalline alumino-silicates, e.g. molecular sieves {(C10G35/065 takes precedence)} · CPC title

• C10G45/68

  Aromatisation of hydrocarbon oil fractions · CPC title

• C10G2400/30

  Aromatics · CPC title