Elastomer composition for a tire object having a self-sealing property

Patent metadata

Field	Value
Publication number	US-9243133-B2
Application number	US-201113576151-A
Country	US
Kind code	B2
Filing date	Jan 21, 2011
Priority date	Jan 28, 2010
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

Elastomer composition having a self-sealing property which can be used in particular as puncture-resistant layer in an inflatable article, based on at least (phr meaning parts by weight per 100 parts of solid elastomer): a blend of at least two solid elastomers, a polybutadiene or butadiene copolymer elastomer, referred to as “elastomer A”, and a natural rubber or synthetic polyisoprene elastomer, referred to as “elastomer B”, the elastomer A:elastomer B ratio by weight being within a range from 10:90 to 90:10; between 30 and 90 phr of a hydrocarbon resin; from 0 to less than 30 phr of filler. Inflatable article, such as a tire, provided with a puncture-resistant layer comprising a composition according to the invention; the puncture-resistant layer is advantageously used in combination with an airtight layer, for example based on butyl rubber or TPS elastomer, in order to form, in the inflatable article, an airtight and puncture-resistant laminate.

First claim

The invention claimed is:

1. An elastomer composition having a self-sealing property which can be used as puncture-resistant layer in an inflatable article comprising (phr meaning parts by weight per 100 parts of solid elastomer):
a blend of at least two solid elastomers, a polybutadiene or butadiene copolymer elastomer, referred to as “elastomer A”, and a natural rubber or synthetic polyisoprene elastomer, referred to as “elastomer B”, the elastomer A:elastomer B ratio by weight being within a range from 10:90 to 90:10;
between 30 and 90 phr of a hydrocarbon resin; and
less than 5 phr of filler.

2. The composition according to claim 1 , wherein the elastomer A is a polybutadiene.

3. The composition according to claim 2 , wherein the elastomer A is a polybutadiene having a content (mol %) of cis-1,4- bonds of greater than 90%.

4. The composition according to claim 1 , wherein the elastomer B is natural rubber or a synthetic cis-1,4 polyisoprene.

5. The composition according to claim 1 , wherein the elastomer A:elastomer B ratio by weight is within a range from 20:80 to 80:20.

6. The composition according to claim 1 , wherein the blend of elastomers A and B constitutes the only solid elastomer of the composition.

7. The composition according to claim 1 , wherein the total content of the elastomer A and the elastomer B is greater than 50 phr.

8. The composition according to claim 1 , wherein the number-average molar mass Mn of each of the elastomer A and the elastomer B is between 100 000 and 5 000 000 g/mol.

9. The composition according to claim 1 , wherein the content of the hydrocarbon resin is within a range from 45 to 75 phr.

10. The composition according to claim 1 , wherein the hydrocarbon resin exhibits a glass transition temperature (Tg) of greater than 0° C.

11. The composition according to claim 10 , wherein the hydrocarbon resin exhibits a Tg of between +25° C. and +100° C.

12. The composition according to claim 1 , wherein the number-average molar mass Mn of the hydrocarbon resin is between 400 and 2000 g/mol.

13. The composition according to claim 1 , wherein the hydrocarbon resin is selected from the group consisting of cyclopentadiene (CPD) homopolymer or copolymer resins, dicyclopentadiene (DCPD) homopolymer or copolymer resins, terpene homopolymer or copolymer resins, terpene phenol homopolymer or copolymer resins, C 5 fraction homopolymer or copolymer resins, C 9 fraction homopolymer or copolymer resins, a-methylstirene homopolymer or copolymer resins, and the mixtures of these resins.

14. The composition according to claim 1 , the filler being carbon black.

15. The composition according to claim 1 , wherein the filler is between 0.5 and 2 phr of carbon black.

16. The composition according to claim 1 , additionally comprising a liquid plasticizer for which the glass transition temperature (Tg) is less than −20° C.

17. The composition according to claim 16 , wherein the content of the liquid plasticizer is less than 60 phr.

18. The composition according to claim 17 , wherein the content of the liquid plasticizer is within a range from 5 to 40 phr.

19. The composition according to claim 16 , wherein the liquid plasticizer is selected from the group consisting of liquid elastomers, polyolefin oils, naphthenic oils, paraffinic oils, DAE oils, MES oils, TDAE oils, mineral oils, vegetable oils, ether plasticizers, ester plasticizers, phosphate plasticizers, sulphonate plasticizers and the mixtures of these compounds.

20. The composition according to claim 19 , wherein the liquid plasticizer is selected from the group consisting of liquid elastomers, polyolefin oils, vegetable oils and the mixtures of these compounds.

21. The composition according to claim 16 , wherein the number-average molar mass Mn of the liquid plasticizer is between 400 and 90 000 g/mol.

22. The composition according to claim 1 , additionally comprising a crosslinking agent.

23. The composition according to claim 22 , wherein the crosslinking agent comprises sulphur or a sulphur donor.

24. The composition according to claim 23 , wherein the crosslinking agent comprises sulphur and a guanidine derivative.

25. The composition according to claim 24 , wherein the crosslinking agent comprises between 0.1 and 1.5 phr of sulphur and between 0 and 1.5 phr of guanidine derivative.

26. The composition according to claim 23 , wherein the sulphur donor is a thiuram polysulphide.

27. The composition according to claim 26 , wherein the content of thiuram polysulphide is between 0.1 and 15 phr.

28. An inflatable article comprising a puncture-resistant layer, said layer comprising the composition according to claim 1 .

29. The article according to claim 28 , wherein said layer has a thickness of greater than 0.3 mm.

30. The article according to claim 29 , wherein said layer has a thickness of between 0.5 mm and 10 mm.

31. The article according to claim 28 , wherein said layer is deposited on the internal wall of the inflatable article.

32. The article according to claim 28 , wherein the inflatable article is an article made of rubber.

33. The article according to claim 32 , wherein the inflatable article is a tire.

34. The article according to claim 28 , wherein said layer is used in combination with an airtight layer, thus forming a self-sealing and airtight laminate.

35. The article according to claim 34 , wherein the airtight layer is based on butyl rubber or a thermoplastic stirene elastomer.

Assignees

• Voge Bozena
• Pelissier Vincent
• Merino Lopez Jose
• Michelin & Cie
• Michelin Rech Tech

Inventors

• Voge Bozena
• Pelissier Vincent
• Merino Lopez Jose

Classifications

• B60C19/122

  disposed inside of the inner liner · CPC title

• C08L9/00 Primary

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• B29B7/7461

  Combinations of dissimilar mixers · CPC title

• B29C73/163

  Sealing compositions or agents, e.g. combined with propellant agents · CPC title