Methods, systems and membranes for separation of organic compounds from liquid samples

Patent metadata

Field	Value
Publication number	US-9242876-B2
Application number	US-201113087706-A
Country	US
Kind code	B2
Filing date	Apr 15, 2011
Priority date	Apr 15, 2011
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

Various aspects of the present invention pertain to porous membranes that comprise: (1) a plurality of pores with pore sizes of more than about 0.1 μm in diameter; and (2) a plurality of hydrophilic molecules. Additional aspects of the present invention pertain to methods of separating organic compounds from a liquid sample by: (1) providing the porous membrane; and (2) flowing the liquid sample through the porous membrane in order to retain organic compounds on the porous membrane. Further aspects of the present invention pertain to systems for separating organic compounds from a liquid sample. Such systems comprises: (1) the porous membrane; and (2) a flowing unit that enables the liquid sample to flow through the porous membrane. Additional aspects of the present invention pertain to methods of making the above-described porous membranes by: (1) coating a surface of a porous membrane containing 0.1 μm pores with a ceramic material; and (2) associating the coated surface of the porous membrane with hydrophilic molecules.

First claim

What is claimed is:

1. A method for separation of organic compounds from a liquid sample, wherein the method comprises:
a. providing a ceramic porous membrane comprising:
i. a plurality of pores with pore sizes of more than about 0.1 μm in diameter, and
ii. a plurality of hydrophilic molecules, wherein the hydrophilic molecules comprise zwitterionic molecules linked to the ceramic porous membrane through carboxylic acid groups on the zwitterionic molecules; and

b. flowing the liquid sample through the ceramic porous membrane, wherein the flowing retains organic compounds on the ceramic porous membrane.

2. The method of claim 1 , wherein the organic compounds comprise hydrocarbons.

3. The method of claim 1 , wherein the liquid sample comprises saltwater.

4. The method of claim 1 , wherein the pores in the ceramic porous membrane have pore sizes of about 0.14 μm in diameter.

5. The method of claim 1 , wherein the hydrophilic molecules in the ceramic porous membrane are selected from the group consisting of carboxylic acids, acidic molecules, basic molecules, phenyl amines, phenyl amidines, amino pyridines, and combinations thereof.

6. The method of claim 1 , wherein the hydrophilic molecules in the ceramic porous membrane comprise carboxylic acids selected from the group consisting of cysteic acid, 3,5-diiodotyrosine, trans-fumaric acid, malonic acid, octanoic acid, stearic acid, 3,5-dihydroxybenzoic acid, parahydroxy benzoic acid, and combinations thereof.

7. The method of claim 1 , wherein the method reduces the carbon content of the liquid sample to below about 7 ppm.

8. The method of claim 1 , wherein the flowing step comprises a filtration step.

9. The method of claim 1 , wherein the ceramic porous membrane comprises at least one of alumina, titania, and zirconia.

10. The method of claim 1 , wherein the zwitterionic molecules comprise functionalized carboxylic acids.

11. The method of claim 1 , wherein the zwitterionic molecules comprise cysteic acid.

12. A method for separation of organic compounds from a liquid sample,
wherein the method comprises flowing the liquid sample through a ceramic porous membrane,
wherein the ceramic porous membrane comprises:
a plurality of pores with pore sizes of more than about 0.1 μm in diameter, and
a plurality of hydrophilic molecules, wherein the hydrophilic molecules comprise zwitterionic molecules linked to the ceramic porous membrane through carboxylic acid groups on the zwitterionic molecules, and

wherein the flowing retains organic compounds on the ceramic porous membrane.

13. The method of claim 12 , wherein the organic compounds comprise hydrocarbons.

14. The method of claim 12 , wherein the liquid sample comprises saltwater.

15. The method of claim 12 , wherein the hydrophilic molecules in the ceramic porous membrane comprise carboxylic acids selected from the group consisting of cysteic acid, 3,5-diiodotyrosine, trans-fumaric acid, malonic acid, octanoic acid, stearic acid, 3,5-dihydroxybenzoic acid, parahydroxy benzoic acid, and combinations thereof.

16. The method of claim 12 , wherein the flowing step comprises a filtration step.

17. The method of claim 12 , wherein the ceramic porous membrane comprises at least one of alumina, titania, and zirconia.

18. The method of claim 12 , wherein the zwitterionic molecules comprise functionalized carboxylic acids.

19. The method of claim 12 , wherein the zwitterionic molecules comprise cysteic acid.

20. A system for separation of organic compounds from a liquid sample, wherein the system comprises:
a. a ceramic porous membrane comprising:
i. a plurality of pores with pore sizes of more than about 0.1 μm in diameter, and
ii. a plurality of hydrophilic molecules, wherein the hydrophilic molecules comprise zwitterionic molecules linked to the ceramic porous membrane through carboxylic acid groups on the zwitterionic molecules; and

b. a flowing unit, wherein the flowing unit enables the liquid sample to flow through the ceramic porous membrane.

21. The system of claim 20 , wherein the ceramic porous membrane comprises at least one of alumina, titania, and zirconia.

22. The system of claim 20 , wherein the pores in the ceramic porous membrane have pore sizes of about 0.14 μm in diameter.

23. The system of claim 20 , wherein the hydrophilic molecules in the ceramic porous membrane are selected from the group consisting of carboxylic acids, acidic molecules, basic molecules, phenyl amines, phenyl amidines, amino pyridines, and combinations thereof.

24. The system of claim 20 , wherein the hydrophilic molecules in the ceramic porous membrane comprise carboxylic acids selected from the group consisting of cysteic acid, 3,5-diiodotyrosine, trans-fumaric acid, malonic acid, octanoic acid, stearic acid, 3,5-dihydroxybenzoic acid, parahydroxy benzoic acid, and combinations thereof.

25. The system of claim 20 , wherein the flowing unit comprises a filtration unit.

26. The system of claim 20 , wherein the flowing unit houses the ceramic porous membrane.

27. The system of claim 11 , wherein the zwitterionic molecules comprise functionalized carboxylic acids.

28. The system of claim 11 , wherein the zwitterionic molecules comprise cysteic acid.

Assignees

• Barron Andrew R
• Maguire-Boyle Samuel J
• Univ Rice William M

Inventors

• Barron Andrew R
• Maguire-Boyle Samuel J

Classifications

• C02F2101/32

  Hydrocarbons, e.g. oil · CPC title

• B01D67/0088

  Physical treatment with compounds, e.g. swelling, coating or impregnation · CPC title

• B01D69/02

  characterised by their properties · CPC title

• B01D2323/02

  Hydrophilization · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title