Dehydrogenation catalyst and process

Patent metadata

Field	Value
Publication number	US-9242227-B2
Application number	US-201013515142-A
Country	US
Kind code	B2
Filing date	Dec 17, 2010
Priority date	Feb 5, 2010
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

A catalyst composition comprises (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) potassium or a potassium compound present in an amount of about 0.15 to about 0.6 wt % of potassium based upon the total weight of the catalyst composition, wherein the catalyst composition has an oxygen chemisorption of greater than 50%.

First claim

The invention claimed is:

1. A process for the dehydrogenation of cyclohexanone to produce phenol, the process comprising contacting a feed comprising cyclohexanone under dehydrogenation conditions with catalyst composition comprising (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) potassium or a potassium compound,
wherein the potassium is present in an amount of about 0.15 to about 0.6 wt % based upon the total weight of the catalyst composition,
wherein the catalyst composition is prepared by sequential impregnation with the potassium or potassium compound being applied to the support before the dehydrogenation component is applied to the support, and
wherein the catalyst composition has an oxygen chemisorption of greater than 50%.

2. The method of claim 1 , wherein the potassium is present in an amount of about 0.2 to about 0.5 wt %, based upon the total weight of the catalyst composition.

3. The method of claim 1 , wherein the support is selected from the group consisting of silica, a silicate, an aluminosilicate, zirconia, and carbon.

4. The method of claim 1 , wherein the dehydrogenation component comprises at least one of platinum and palladium.

5. The method of claim 1 , wherein the catalyst composition improves phenol selectivity relative to dehydrogenation catalysts containing greater than 0.6 wt % of potassium.

6. The method of claim 1 , wherein the dehydrogenation component is present in an amount of about 0.01 to about 2 wt %, based upon the total weight of the catalyst composition.

7. The method of claim 1 , wherein the dehydrogenation component is present in an amount of about 0.5 to about 1.5 wt % based upon the total weight of the catalyst composition.

8. A process for producing phenol from benzene, the process comprising:
(a) reacting benzene and hydrogen with a catalyst under hydroalkylation conditions to produce cyclohexylbenzene;
(b) oxidizing cyclohexylbenzene from (a) to produce cyclohexylbenzene hydroperoxide;
(c) converting cyclohexylbenzene hydroperoxide from (b) to produce an effluent stream comprising phenol and cyclohexanone; and
(d) contacting at least a portion of the effluent stream from (c) with a dehydrogenation catalyst comprising: (i) a support; (ii) a dehydrogenation component comprising at least one metal or compound thereof selected from Groups 6 to 10 of the Periodic Table of Elements; and (iii) potassium or a potassium compound, wherein the potassium is present in an amount of about 0.15 to about 0.6 wt % based upon the total weight of the catalyst composition, wherein the dehydrogenation catalyst is prepared by sequential impregnation with the potassium or potassium compound being applied to the support before the dehydrogenation component is applied to the support, and further wherein the contacting occurs under dehydrogenation conditions effective to convert at least part of the cyclohexanone in the effluent stream into phenol and hydrogen.

9. The process of claim 8 , wherein the catalyst provides a reduced selectivity to one or more of pentane, pentene and carbon monoxide relative to dehydrogenation catalysts containing greater than 0.6 wt % of potassium.

Assignees

• Dakka Jihad M
• Decaul Lorenzo C
• Helton Terry E
• Xu Teng
• Wallace Jenna L
• Exxonmobil Chem Patents Inc

Inventors

• Dakka Jihad M
• Decaul Lorenzo C
• Helton Terry E
• Xu Teng
• Wallace Jenna L

Classifications

• B01J37/12

  Oxidising · CPC title

• C07C2/74

  by addition with simultaneous hydrogenation · CPC title

• C07C409/14

  the carbon atom belonging to a ring other than a six-membered aromatic ring · CPC title

• C07C2101/14

  Chemistry & Metallurgy · mapped topic

• C07C37/08

  by decomposition of hydroperoxides, e.g. cumene hydroperoxide · CPC title