Positive electrode active material and preparation method thereof, positive electrode plate, secondary battery, battery module, battery pack, and electric apparatus
US-2024429384-A1 · Dec 26, 2024 · US
US9240595B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9240595-B2 |
| Application number | US-201314349157-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 26, 2013 |
| Priority date | Aug 24, 2012 |
| Publication date | Jan 19, 2016 |
| Grant date | Jan 19, 2016 |
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Provided is a new 5 V class spinel exhibiting an operating potential of 4.5 V or higher (5 V class) with respect to the Li metal reference potential, having an excellent discharge capacity retention ratio at high temperatures, for example 45° C. Suggested is a spinel type lithium-manganese-nickel-containing composite oxide containing a crystalline phase in which a portion of Mn sites in LiMn 2 O 4-δ are substituted with Li; another metal element M1, wherein M1 represents a metal element including at least one of Ni, Co and Fe and another metal element M2, wherein M2 represents a metal element including at least one of Mg, Ti, Al, Ba, Cr and Nb, and the spinel type lithium-manganese-nickel-containing composite oxide comprising a composite oxide phase containing Ni, Mn and B.
Opening claim text (preview).
The invention claimed is: 1. A spinel type lithium-manganese-nickel-containing composite oxide having an operating potential of 4.5 V or higher with respect to a Li metal reference potential, wherein the spinel type lithium-manganese-nickel-containing composite oxide comprises a composite oxide phase comprising a crystalline phase of Ni 5 MnO 4 (BO 3 ) 2 . 2. A spinel type lithium-manganese-nickel-containing composite oxide having an operating potential of 4.5 V or higher with respect to the Li metal reference potential, wherein the spinel type lithium-manganese-nickel-containing composite oxide comprises a crystalline phase in which a portion of Mn sites in LiMn 2 O 4-δ are substituted with Li; another metal element M1, wherein M1 represents a metal element including at least one of Ni, Co and Fe and another metal element M2, wherein M2 represents a metal element including at least one of Mg, Ti, Al, Ba, Cr and Nb, wherein the spinel type lithium-manganese-nickel-containing composite oxide comprises a composite oxide phase comprising a crystalline phase of Ni 5 MnO 4 (BO 3 ) 2 .
Surface area · CPC title
containing manganese · CPC title
of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title
Micrometer sized, i.e. from 1-100 micrometer · CPC title
by d-values or two theta-values, e.g. as X-ray diagram · CPC title
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