Two-component coating compositions

Patent metadata

Field	Value
Publication number	US-9238764-B2
Application number	US-201213433711-A
Country	US
Kind code	B2
Filing date	Mar 29, 2012
Priority date	Mar 31, 2011
Publication date	Jan 19, 2016
Grant date	Jan 19, 2016

Abstract

The present invention describes two-component coating compositions which for curing require no polyisocyanates or melamine-formaldehyde resins as crosslinkers.

First claim

The invention claimed is:

1. A two-component coating composition comprising
at least one copolymer (A) which carries at least one cyclic carbonate group,
an amine component (B) comprising at least two amines which are diamines, polyamines, or a mixture thereof, where each of the amines has at least two amine groups selected from the group consisting of primary and secondary amine groups,
at least one solvent (C) in which the components (A) and (B) are soluble,
optionally at least one pigment (D), and
optionally at least one additive (E),
wherein the amine component has a fraction of tertiary amine groups, based on the total amount of primary, secondary, and tertiary amine groups, of less than 20%;
the molar ratio of primary and secondary amino groups in (B) to cyclic carbonate groups in (A) is from 1.2:1 to 1:5; and
the copolymer (A) is obtainable by radical polymerization of a monomer mixture comprising
(a1) at least one (meth)acrylate containing at least one cyclic carbonate group,
(a2) at least one additional (cyclo)alkyl (meth)acrylate,
(a3) at least one vinylaromatic monomer,
(a4) optionally at least one hydroxyalkyl (meth)acrylate, and
(a5) optionally at least one acid-group-containing monomer.

2. The coating composition according to claim 1 , wherein the monomer (a1) is selected from the group consisting of (2-oxo-1,3-dioxolan-4-yl)methyl acrylate and (2-oxo-1,3-dioxolan-4-yl)methyl methacrylate.

3. The coating composition according to claim 1 , wherein the monomer (a2) is selected from the group consisting of methyl acrylate, methyl methacrylate, ethyl acrylate, n-butyl acrylate, tert-butyl acrylate, and 2-ethylhexyl acrylate.

4. The coating composition according to claim 1 , wherein the monomer (a3) is selected from the group consisting of styrene and alpha-methylstyrene.

5. The coating composition according to claim 1 , wherein the copolymer (A) has a glass transition temperature (Tg) of 10 to 100° C.

6. The coating composition according to claim 1 , wherein one of the diamine or polyamine is selected from the group consisting of linear or branched C 2 -C 8 (cyclo)alkylenediamines (B1) and polyetheramines (B2).

7. The coating composition according to claim 1 , wherein one of the diamine or polyamine is selected from the group consisting of ethylenediamine, 1,3-diamino-2,2-dimethylpropane, hexamethylenediamine, diaminodicyclohexylmethane, cyclohexylenediamine, isophoronediamine, and bis(aminomethyl)cyclohexane.

8. The coating composition according to claim 1 , wherein one of the diamine or polyamine is an amination product of singly to vigintuply ethoxylated, propoxylated or mixedly ethoxylated and propoxylated neopentylglycol, trimethylolpropane, trimethylolethane or pentaerythritol.

9. A process for preparing a coating composition according to claim 1 , which comprises mixing components (A) and (B) with one another.

10. A method for coating a substrate, which comprises coating the substrate with a coating composition according to claim 1 , wherein components (A) and (B) are mixed with one another shortly before application to the substrate, and subjecting the coated substrate subsequently to thermal treatment at ambient temperature up to 150° C.

11. The method according to claim 10 , wherein the substrate is selected from the group consisting of wood, wood veneer, paper, paperboard, cardboard, textile, film, leather, nonwoven, plastics surfaces, glass, ceramic, mineral building materials, and metals, each of which may optionally have been precoated.

12. A two-component coating composition consisting of
30% to 80% by weight of at least one copolymer (A) which carries at least one cyclic carbonate group,
5% to 20% by weight of an amine component (B) comprising at least two amines which are diamines, polyamines, or a mixture thereof, where each of the amines has at least two amine groups selected from the group consisting of primary and secondary amine groups,
0% to 60% by weight of at least one solvent (C) in which the components (A) and (B) are soluble,
0% to 30% by weight of at least one pigment (D), and
0% to 10% by weight of at least one additive (E),
with the proviso that the sum of these components is always 100% by weight;
wherein the amine component has a fraction of tertiary amine groups, based on the total amount of primary, secondary, and tertiary amine groups, of less than 20%;
the molar ratio of primary and secondary amino groups in (B) to cyclic carbonate groups in (A) is from 1.2:1 to 1:5;
the copolymer (A) is obtainable by radical polymerization of a monomer mixture comprising at least one (meth)acrylate containing at least one cyclic carbonate group; and
either copolymer (A) or the amine component is separated from the remaining components of the composition.

13. The coating composition according to claim 1 , wherein the amine component comprises tris(2-aminoethyl)amine and isophoronediamine.

14. The coating composition according to claim 1 , wherein the amine component comprises diethylenetriamine and isophoronediamine.

15. The coating composition according to claim 1 , wherein the amine component comprises tris(2-aminoethyl)amine, 2,2-dimethylpropylenediamine and isophoronediamine.

16. The coating composition according to claim 1 , wherein the amine component comprises diethylenetriamine, 2,2-dimethylpropylenediamine and isophoronediamine.

17. The coating composition according to claim 1 , wherein the monomer (a2) comprises 2-ethylhexyl acrylate.

Assignees

• Brym Markus
• Rösch Christine
• Haaf Christina
• Steinbrecher Angelika Maria
• Schäfer Harald
• Elizalde Oihana
• Basf Se

Inventors

• Brym Markus
• Rösch Christine
• Haaf Christina
• Steinbrecher Angelika Maria
• Schäfer Harald
• Elizalde Oihana

Classifications

• C09J133/06 Primary

  of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical · CPC title

• C09D175/12

  from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group · CPC title

• C08F220/283

  and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate · CPC title

• C08F24/00

  Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a heterocyclic ring containing oxygen (cyclic esters of polyfunctional acids C08F18/00; cyclic anhydrides of unsaturated acids C08F20/00, C08F22/00) · CPC title

• C09J133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title