Carbon dioxide conversion to hydrocarbon fuel via syngas production cell harnessed from solar radiation

Patent metadata

Field	Value
Publication number	US-9238598-B2
Application number	US-201414147067-A
Country	US
Kind code	B2
Filing date	Jan 3, 2014
Priority date	Jan 4, 2013
Publication date	Jan 19, 2016
Grant date	Jan 19, 2016

Abstract

A process for converting carbon dioxide to hydrocarbon fuels using solar energy harnessed with a solar thermal power system to create thermal energy and electricity, using the thermal energy to heat a fuel feed stream, the heated fuel feed stream comprising carbon dioxide and water, the carbon dioxide captured from a flue gas stream, converting the carbon dioxide and water in a syngas production cell, the syngas production cell comprising a solid oxide electrolyte, to create carbon monoxide and hydrogen, and converting the carbon monoxide and hydrogen to hydrocarbon fuels in a catalytic reactor. In at least one embodiment, the syngas production cell is a solid oxide fuel cell. In at least one embodiment, the syngas production cell is a solid oxide electrolyzer cell.

First claim

What is claimed is:

1. A process for converting carbon dioxide to hydrocarbon fuels using solar energy, the process comprising the steps of:
receiving direct sunlight with a plurality of heliostats and reflecting the direct sunlight from the heliostats as reflected sunlight onto a tower receiver, wherein the reflected sunlight heats a heat transfer fluid in the tower receiver;
converting a water stream to a generated steam stream in a steam generator, wherein the heat transfer fluid provides heat to the steam generator;
feeding the generated steam stream to a steam turbine, wherein the steam turbine converts thermal energy in the generated steam stream to mechanical energy to drive an electric generator to generate electricity;
heating a fuel feed stream by transferring thermal energy from the heat transfer fluid to create a heated fuel feed stream, such that the heated fuel feed stream reaches a temperature of between 650° C. and 800° C.;
feeding the heated fuel feed stream to a syngas production cell, wherein the heated fuel feed stream comprises carbon dioxide and water, wherein the carbon dioxide is captured from a fuel gas stream, wherein the syngas production cell comprises a solid oxide electrolyzer cell, wherein the solid oxide electrolyzer cell comprises a porous cathode, the solid oxide electrolyte, and a porous anode;
converting the carbon dioxide and water in the heated fuel feed stream to carbon monoxide and hydrogen in the syngas production cell to produce a syngas stream, wherein the syngas production cell comprises a solid oxide electrolyte;
feeding the syngas stream to a catalytic reactor, wherein the catalytic reactor operates in the presence of a catalyst; and
converting the syngas stream to a hydrocarbon fuel stream in the catalytic reactor.

2. The process as claimed in claim 1 , wherein the step of converting the carbon dioxide and water in the heated fuel feed stream to carbon monoxide and hydrogen in the syngas production cell further comprises the steps of:
supplying the electricity to the porous cathode of the solid oxide electrolyzer cell;
contacting the porous cathode with the heated fuel feed stream;
reducing the carbon dioxide to create carbon monoxide and oxygen ions, wherein the oxygen ions pass through the porous cathode to the solid oxide electrolyte;
reducing the water to create hydrogen and oxygen ions, wherein the oxygen ions pass through the porous cathode to the solid oxide electrolyte;
diffusing the oxygen ions through the solid oxide electrolyte to the porous anode; and
releasing electrons from the oxygen ions at the porous anode, such that oxygen molecules are formed to create an oxygen stream.

3. The process as claimed in claim 1 , further comprising the step of:
feeding the hydrocarbon fuel to a power plant for consumption.

4. A process for converting carbon dioxide to hydrocarbon fuels using solar energy, the process comprising the steps of:
receiving direct sunlight with a plurality of heliostats and reflecting the direct sunlight from the heliostats as reflected sunlight onto a tower receiver, wherein the reflected sunlight heats a heat transfer fluid in the tower receiver;
converting a water stream to a generated steam stream in a steam generator, wherein the heat transfer fluid provides heat to the steam generator;
feeding the generated steam stream to a steam turbine, wherein the steam turbine converts thermal energy in the generated steam stream to mechanical energy to drive an electric generator to generate electricity;
heating a fuel feed stream by transferring thermal energy from the heat transfer fluid to create a heated fuel feed stream, such that the heated fuel feed stream reaches a temperature of between 650° C. and 800° C.;
feeding the heated fuel feed stream to a syngas production cell, wherein the heated fuel feed stream comprises carbon dioxide and water, wherein the carbon dioxide is captured from a fuel gas stream, wherein the syngas production cell comprises a solid oxide electrolyzer cell, wherein the solid oxide fuel cell comprises a porous anode, the solid oxide electrolyte, and a porous cathode;
converting the carbon dioxide and water in the heated fuel feed stream to carbon monoxide and hydrogen in the syngas production cell to produce a syngas stream, wherein the syngas production cell comprises a solid oxide electrolyte;
feeding the syngas stream to a catalytic reactor, wherein the catalytic reactor operates in the presence of a catalyst; and
converting the syngas stream to a hydrocarbon fuel stream in the catalytic reactor.

5. The process as claimed in claim 4 , wherein the step of converting the carbon dioxide and water in the heated fuel feed stream to carbon monoxide and hydrogen in the syngas production cell further comprises the steps of:
adding a gaseous hydrocarbon to the heated fuel feed stream;
feeding the heated fuel feed stream to the porous anode of the solid oxide fuel cell;
reforming the water and the gaseous hydrocarbon in the heated fuel feed stream to create carbon monoxide and hydrogen;
reforming the carbon dioxide and the gaseous hydrocarbon in the heated fuel feed stream to create carbon monoxide and hydrogen;
reducing oxygen from an oxygen supply on the porous cathode of the solid oxide fuel cell to generate oxygen ions;
diffusing the oxygen ions through the solid oxide electrolyte to the porous anode;
oxidizing the hydrogen at the porous anode with the oxygen ions to create water and electrons;
oxidizing the methane at the porous anode with the oxygen ions to create carbon monoxide, hydrogen, and electrons; and
supplying the electrons to an electrical substation, wherein the electrical substation is configured to combine the electrons from the syngas production cell with the electricity generated by the electric generator.

6. The process as claimed in claim 5 , wherein the gaseous hydrocarbon comprises methane.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hammad Ahmad D
• Yusuf Zaki
• Souentie Stamatios
• Al-Rasheedi Nayif A
• Fadhel Bandar A
• Al-Zahrani Atef Saeed

Classifications

• C01B3/38

  using catalysts · CPC title

• C10L2290/42

  Fischer-Tropsch steps · CPC title

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title

• C01B2203/061

  Methanol production · CPC title

• C25B1/04

  by electrolysis of water · CPC title