Metal powderdous catalyst for hydrogenation process

Patent metadata

Field	Value
Publication number	US-9238218-B2
Application number	US-201314380892-A
Country	US
Kind code	B2
Filing date	Feb 22, 2013
Priority date	Feb 24, 2012
Publication date	Jan 19, 2016
Grant date	Jan 19, 2016

Abstract

The present invention is related to a new metal powder catalytic system (catalyst) comprising a Fe-alloy as a carrier, its production and its use in hydrogenation processes.

First claim

The invention claimed is:

1. A powderous catalytic system comprising a carrier formed of a metal alloy comprising:
(i) 45 wt-%-75 wt-%, based on total weight of the metal alloy, of Fe,
(ii) 15 wt-%-30 wt-%, based on total weight of the metal alloy, of Ni,
(iii) 5 wt-%-20 wt-%, based on total weight of the metal alloy, of Co, and
(iv) 3 wt-%-8 wt-%, based on total weight of the metal alloy, of Mo, wherein
the metal alloy is coated by a metal oxide layer impregnated with Pd-nanoparticles.

2. The powderous catalytic system according to claim 1 , wherein the metal alloy is maraging steel.

3. The powderous catalytic system according to claim 1 , wherein the metal alloy comprises further metals.

4. The powderous catalytic system according to claim 1 , wherein the metal alloy comprises carbon.

5. The powderous catalytic system according to claim 1 , wherein the metal alloy is stainless steel comprising:
(i) 60 wt-%-70 wt-%, based on the total weight of the metal alloy, of Fe,
(ii) 15 wt-%-25 wt-%, based on the total weight of the metal alloy, of Ni,
(iii) 5 wt-%-15 wt-%, based on the total weight of the metal alloy, of Co, and
(iv) 3.5 wt-%-7 wt-%, based on the total weight of the metal alloy, of Mo.

6. The powderous catalytic system according to claim 1 , wherein the metal oxide layer is basic or amphoteric.

7. The powderous catalytic system according to claim 1 , wherein the metal oxide layer comprises Zn, Cr, Mn, Cu and/or Al.

8. The powderous catalytic system according to claim 1 , wherein the oxide layer comprises ZnO and optionally at least one further metal oxide chosen from the group consisting of Cr, Mn, Mg, Cu and Al.

9. The powderous catalytic system according to claim 1 , wherein the metal oxide layer comprises ZnO and Al 2 O 3 .

10. The powderous catalytic system according to claim 1 , wherein the metal oxide layer is non-acidic, and wherein the powderous catalytic system comprises between 0.1 wt-% and 50 wt-%, based on total weight of the powderous catalytic system, of the non-acidic metal oxide layer.

11. The powderous catalytic system according to claim 1 , wherein the metal oxide is mixture of ZnO and Al 2 O 3 in a ratio of Zn:Al 2 O 3 of 2:1 to 1:2.

12. The powderous catalytic system according to claim 1 , wherein the Pd-nanoparticles have an average particle size of between 0.5 and 20 nm.

13. The powderous catalytic system according to claim 1 , wherein the powderous catalytic system comprises between 0.001 wt-% and 5 wt-%, based on total weight of the powderous catalytic system, of the Pd-nanoparticles.

14. The powderous catalytic system according to claim 11 , wherein the ratio of Zn:Al 2 O 3 is 1:1.

15. A method for selective catalytic hydrogenation of an organic starting material comprising subjecting the organic starting material to catalytic hydrogenation conditions in the presence of the powderous catalytic system according to claim 1 .

16. The method according to claim 15 , wherein the organic starting material is a compound of formula (I):

wherein
R 1 is an optionally substituted linear or branched C 5 -C 35 alkyl moiety or an optionally substituted linear or branched C 5 -C 35 alkenyl moiety, and
R 2 is an optionally substituted linear or branched C 1 -C 4 alkyl moiety.

Assignees

• Dsm Ip Assets Bv

Inventors

• Bonrath Werner
• Buss Axel

Classifications

• B01J37/0207

  Pretreatment of the support · CPC title

• C07C29/17

  by hydrogenation of carbon-to-carbon double or triple bonds · CPC title

• C07C67/283

  by hydrogenation of unsaturated carbon-to-carbon bonds · CPC title

• B01J37/0226

  Oxidation of the substrate, e.g. anodisation · CPC title

• B01J23/8993 Primary

  with chromium, molybdenum or tungsten · CPC title