Process and apparatus for treating a gas stream

Patent metadata

Field	Value
Publication number	US-9238212-B2
Application number	US-201414316149-A
Country	US
Kind code	B2
Filing date	Jun 26, 2014
Priority date	Jan 12, 2011
Publication date	Jan 19, 2016
Grant date	Jan 19, 2016

Abstract

A process of treating hydrogen gas liberated from the acid or alkaline dissolution of a metal is provided. The process comprises a step of passing the liberated hydrogen gas through a reactor containing an oxidizing agent for oxidation of the hydrogen gas into water, followed by a step of regenerating the oxidizing agent. Also provided is an apparatus for carrying out the process, the apparatus comprising a reactor containing the oxidizing agent, wherein the reactor is at least partially immersed in an alumina bath.

First claim

What is claimed is:

1. A heating apparatus comprising an alumina bath supplied with one or more external heating elements, wherein the alumina bath defines a cavity into which a reactor may be placed, the reactor comprising an oxidising agent for the oxidation of hydrogen gas into water.

2. The heating apparatus of claim 1 , wherein the oxidising agent comprises copper oxide.

3. The apparatus of claim 2 , wherein the oxidising agent is diluted with an inert diluent.

4. The heating apparatus of claim 3 , wherein the oxidising agent is diluted 50% by weight with the inert diluent.

5. The heating apparatus of claim 2 , wherein hydrogen gas is passed into the CuO reactor in which the hydrogen gas is oxidised into water while the CuO is converted into Cu.

6. The heating apparatus of claim 5 , wherein a stream of air-containing nitrogen gas (N2/air) is fed into the CuO reactor to oxidise Cu in order to regenerate CuO.

7. The heating apparatus of claim 2 , wherein the oxidising agent is selected from R3-11G and R3-17 catalysts.

8. The heating apparatus of claim 1 , wherein the reactor is at least partially immersed in the alumina bath.

9. The heating apparatus of claim 8 , wherein the reactor is completely immersed in the alumina bath.

10. The heating apparatus of claim 1 , wherein the one or more external heating elements is selected from a collar, a jacket, and a heating coil.

11. The heating apparatus of claim 1 , wherein the external heating elements are electrically heated.

12. The hearing apparatus of claim 1 , wherein the alumina bath is a heat exchanger.

13. The heating apparatus of claim 1 , wherein the alumina bath heats up the reactor to an initial reaction temperature with no deleterious effects to the oxidising agent material.

14. The heating apparatus of claim 13 , wherein the initial reaction temperature is 200° C.

15. The heating apparatus of claim 1 , wherein the alumina bath comprises outer walls taking the form of a substantially cylindrical or cuboidal container.

16. The heating apparatus of claim 15 , wherein the outer walls of the alumina bath comprise stainless steel or aluminum.

17. The heating apparatus of claim 1 , wherein the reactor comprises less than 12 kg of the oxidising agent.

18. An apparatus for treating hydrogen gas liberated from the acid or alkaline dissolution of a metal, the apparatus comprising a reactor comprising an oxidising agent for the oxidation of hydrogen gas into water, wherein the reactor is heated with one or more heating elements positioned in contact with the reactor, wherein the liberated hydrogen gas is passed through the reactor followed by regeneration of the oxidising agent, and wherein the oxidising agent comprises a metal oxide in bulk form or a metal oxide finely dispersed on the surface of an inert support.

19. The apparatus of claim 18 , wherein the one or more heating elements are selected from one or more heated clamps or bands.

20. The apparatus of claim 19 , wherein the bands may be in the form of a single helical band which runs along at least part of a length of the reactor.

21. The apparatus of claim 18 , wherein the heating elements are electrically heated.

22. The apparatus of claim 18 , wherein the one or more heating elements heat up the reactor to an initial reaction temperature with no deleterious effects to the oxidising agent material.

23. The apparatus of claim 22 , wherein the initial reaction temperature is 200° C.

24. The apparatus of claim 18 , wherein the oxidising agent comprises copper oxide.

25. The apparatus of claim 24 , wherein the oxidising agent is selected from R3-11G and R3-17 catalysts.

26. The apparatus of claim 18 , wherein the oxidising agent is diluted with an inert diluent.

27. The apparatus of claim 26 , wherein the inert diluent comprises stainless steel pellets.

28. The apparatus of claim 26 , wherein the oxidising agent is diluted 50% by weight with the inert diluent.

29. The apparatus of claim 18 , wherein the reactor further comprises a first conduit.

30. The apparatus of claim 29 , wherein the liberated hydrogen gas enters the reactor through the first conduit.

31. The apparatus of claim 29 , wherein a mixture of nitrogen and air is introduced to the reactor through the first conduit for the regeneration of the oxidising agent.

32. The apparatus of claim 18 , wherein the reactor further comprises a venting conduit.

33. The apparatus of claim 32 , wherein gaseous water exits the reactor through the venting conduit.

34. The apparatus of claim 32 , wherein waste nitrogen gas exist the reactor through the venting conduit after the regeneration of the oxidising agent.

35. The apparatus of claim 18 , wherein the reactor comprises less than 12 kg of the oxidising agent.

36. An apparatus for treating hydrogen gas liberated from the acid or alkaline dissolution of a metal, the apparatus comprising a reactor comprising an oxidising agent diluted with an inert diluent for the oxidation of hydrogen gas into water, wherein the reactor is at least partially immersed in an alumina bath supplied with one or more external heating elements, and wherein the liberated hydrogen gas is passed through the reactor followed by regeneration of the oxidizing agent.

37. The apparatus of claim 36 , wherein the one or more heating elements are selected from a collar, a jacket, and a heating coil.

38. The apparatus of claim 36 , wherein the heating elements are electrically heated.

39. The apparatus of claim 36 , wherein the alumina bath heats up the reactor to an initial reaction temperature with no deleterious effects to the oxidising agent material.

40. The apparatus of claim 30 , wherein the initial reaction temperature is 200° C.

41. The apparatus of claim 36 , wherein the oxidising agent comprises copper oxide.

42. The apparatus of claim 41 , wherein the oxidising agent is selected from R3-11G and R3-17 catalysts.

43. The apparatus of claim 36 , wherein the oxidising agent is diluted with an inert diluent.

44. The apparatus of claim 43 , wherein the inert diluent comprises stainless steel pellets.

45. The apparatus of claim 43 , wherein the oxidising agent is diluted 50% by weight with the inert diluent.

46. The apparatus of claim 36 , wherein the reactor further comprises a first conduit.

47. The apparatus of claim 46 , wherein the liberated hydrogen gas enters the reactor through the first conduit.

48. The apparatus of claim 46 , wherein a mixture of nitrogen and air is introduced to the reactor through the first conduit for the regeneration of the oxidising agent.

49. The apparatus of claim 36 , wherein the reactor further comprises a venting conduit.

50. The apparatus of claim 49 , wherein gaseous water exits the reactor through the venting conduit.

51. The apparatus of claim 49 , wherein waste nitrogen gas exist the reactor through the venting conduit after the regeneration of the oxidising agent.

52. The ap

Assignees

• Mallinckrodt Llc

Inventors

• Barbosa Luis

Classifications

• C01B5/00

  Water · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• G21G2001/0036

  Molybdenum · CPC title

• G21C9/06

  Means for preventing accumulation of explosives gases, e.g. recombiners · CPC title

• G21C19/46

  Aqueous processes {, e.g. by using organic extraction means, including the regeneration of these means} · CPC title