Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

Patent metadata

Field	Value
Publication number	US-9238201-B2
Application number	US-201314068375-A
Country	US
Kind code	B2
Filing date	Oct 31, 2013
Priority date	Jul 8, 2011
Publication date	Jan 19, 2016
Grant date	Jan 19, 2016

Abstract

A method and apparatus for producing heat used in a synthesis gas production process is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the steam reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

First claim

The invention claimed is:

1. An oxygen transport membrane module for producing heat used in a synthesis gas production process, the module comprising:
a plurality of tubular oxygen transport membrane elements each having a permeate side located on an outer surfaces of the tubular oxygen transport membrane element and a retentate side located on an inner surfaces of the tubular oxygen transport membrane element, the tubular oxygen transport membrane elements configured to separate oxygen from an oxygen containing stream contacting the retentate side of the plurality of tubular oxygen transport membrane elements and produce the oxygen on the permeate side of the tubular oxygen transport membrane elements and to combust the permeated oxygen with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating radiant heat, a steam containing reaction product stream and a retentate stream;
at least one catalytic reactor disposed proximate the plurality of tubular oxygen transport membrane elements and configured to receive the steam containing reaction product stream, a hydrocarbon containing reactant steam and the radiant heat and to react the steam containing reaction product stream with the hydrocarbon containing reactant stream in the presence of the radiant heat to produce a synthesis gas stream;
wherein the view factor between the at least one catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the at least one catalytic reactor is greater than or equal to 0.5.

2. The module of claim 1 wherein the at least one catalytic reactor further comprises at least one reactor tube containing a catalyst to promote the steam reforming reaction, each reactor tube having an inlet at one end of each reactor tube to receive the steam containing reaction product stream and the hydrocarbon containing reactant stream and an outlet at the other end of each reactor tube to discharge the synthesis gas stream.

3. The module of claim 2 wherein the plurality of tubular oxygen transport membrane elements are positioned so as to surround the reactor tubes.

4. The module of claim 1 further comprising:
at least one inlet manifold connected to one or more of the plurality of the tubular oxygen transport membrane elements, the inlet manifold configured to introduce the hydrogen containing synthesis gas stream to the permeate side of the tubular oxygen transport membrane elements and the oxygen containing stream to the retentate side of the tubular oxygen transport membrane elements;
at least one outlet manifold connected to one or more of the plurality of the tubular oxygen transport membrane elements, the outlet manifolds configured to receive the steam containing reaction product stream; and
wherein the at least one outlet manifold is connected to the inlet of the at least one catalytic reactor to deliver the steam containing reaction product stream to the catalytic reactor.

5. The module of claim 4 wherein the at least one outlet manifold is further fluidically coupled with the hydrocarbon containing stream to mix with the steam containing reaction product stream, and deliver the combined stream to the catalytic reactor thereby to form a combined stream to undergo the steam reforming reaction.

6. The module of claim 4 wherein the retentate stream is heated from the combustion of the permeated oxygen with the hydrogen containing synthesis gas stream and heat from the heated retentate stream is indirectly transferred to the at least one catalytic reactor.

7. The module of claim 4 wherein the retentate stream is heated from the combustion of the permeated oxygen with the hydrogen containing synthesis gas stream and heat from the heated retentate stream is used to preheat the oxygen containing stream.

Assignees

• Kelly Sean M
• Kromer Brian R
• Litwin Michael M
• Rosen Lee J
• Christie Gervase Maxwell
• Wilson Jamie R
• Kosowski Lawrence W
• Robinson Charles
• Praxair Technology Inc

Inventors

• Kelly Sean M
• Kromer Brian R
• Litwin Michael M
• Rosen Lee J
• Christie Gervase Maxwell
• Wilson Jamie R
• Kosowski Lawrence W
• Robinson Charles

Classifications

• B01J2208/00309

  with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction · CPC title

• B01J2219/00157

  by means of a burner · CPC title

• B01J19/2475

  Membrane reactors · CPC title

• B01J2219/00117

  with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction · CPC title

• C01B2203/062

  Hydrocarbon production, e.g. Fischer-Tropsch process · CPC title