Transparent conductive ink and transparent conductive pattern forming method

Patent metadata

Field	Value
Publication number	US-9236162-B2
Application number	US-201314396853-A
Country	US
Kind code	B2
Filing date	Apr 26, 2013
Priority date	Apr 26, 2012
Publication date	Jan 12, 2016
Grant date	Jan 12, 2016

Abstract

Provided is a transparent conductive ink which contains metal nanowires and/or metal nanotubes as a conductive component and can form a coating film which has good conductivity and a high light transmittance property, and also provided is a transparent conductive pattern forming method wherein this transparent conductive ink is used for forming a transparent conductive pattern by simple production steps, to thereby suppress the production cost and environmental load. At least one of metal nanowires and metal nanotubes are dispersed in a dispersion medium containing a shape-holding material which contains an organic compound having a molecular weight in the range of 150 to 500 and which has a viscosity of 1.0×10 3 to 2.0×10 6 mPa·s at 25° C., to prepare a transparent conductive ink. A transparent conductive pattern is formed by printing a pattern having an arbitrary shape on a substrate using this transparent conductive ink, subjecting the pattern to a heating treatment to dry the pattern, and subjecting the pattern which has been dried to pulsed light irradiation.

First claim

The invention claimed is:

1. A transparent conductive ink for pattern printing comprising at least either one of metal nanowires and metal nanotubes, and a dispersion medium which contains a shape-holding material and a viscosity adjustment solvent,
the shape-holding material containing an organic compound and having a viscosity at 25° C. of 1.0×10 3 to 2.0×10 6 mPa·s,
the organic compound having an alkyl group comprising a bridged carbon cyclic structure, and a hydroxyl group, and having a molecular weight in the range of 150 to 500,
the viscosity adjustment solvent being at least one of alcohol, ether, and an aliphatic hydrocarbon solvent,
the content of the metal nanowires or the metal nanotubes relative to the total mass of the transparent conductive ink being 0.01 to 10% by mass,
the content of the shape-holding material relative to the total mass of the dispersion medium being 10 to 90% by mass, and
the metal nanowires and the metal nanotubes having an average diameter size of 1 to 500 nm, an average aspect ratio of more than 5, and an average major axis length of 1 to 100 μm.

2. The transparent conductive ink according to claim 1 , wherein the organic compound contained in the shape-holding material is bornylcyclohexanol, bornylphenol, isobornylcyclohexanol, or isobornylphenol.

3. The transparent conductive ink according to claim 1 , wherein the viscosity adjustment solvent is terpineol.

4. The transparent conductive ink according to claim 1 , wherein the content of the metal nanowires or the metal nanotubes is 0.25 to 3% by mass.

5. The transparent conductive ink according to claim 1 , wherein the pattern printing is screen printing or gravure printing.

6. The transparent conductive ink according to claim 1 , wherein the content of the shape-holding material relative to the total mass of the dispersion medium is 30% by mass or more.

7. The transparent conductive ink according to claim 1 , having the viscosity at 25° C. of 100 to 2×10 5 mPa·s.

8. The transparent conductive ink according to claim 7 , having the viscosity at 25° C. of 10 3 to 5×10 4 mPa·s.

9. The transparent conductive ink according to claim 1 , wherein the metal nanowires and the metal nanotubes have an average aspect ratio of 100 or more.

10. A transparent conductive pattern forming method comprising,
a step for printing a pattern having an arbitrary shape on a substrate using a transparent conductive ink according to claim 1 ,
a step for subjecting the pattern to a heating treatment to dry the pattern, and
a step for subjecting the pattern which has been dried to pulsed light irradiation or pressing.

Assignees

• Univ Osaka
• Showa Denko Kk
• Showa Denko Kk

Inventors

• Suganuma Katsuaki
• Ohtsuka Kuniaki
• Murahashi Koichiro
• Takemura Yasutaka
• Uchida Hiroshi

Classifications

• H01B13/003

  using irradiation · CPC title

• H05K3/1283

  After-treatment of the printed patterns, e.g. sintering or curing methods · CPC title

• C09D11/52

  Electrically conductive inks · CPC title

• H05K3/12

  using {thick film techniques, e.g.} printing techniques to apply the conductive material {or similar techniques for applying conductive paste or ink patterns} · CPC title

• H05K2203/107

  Using laser light · CPC title