Resin-coated aluminum alloy sheet and formed body using resin-coated aluminum alloy sheet
US-9410251-B2 · Aug 9, 2016 · US
US9234284B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9234284-B2 |
| Application number | US-200813057715-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 6, 2008 |
| Priority date | Aug 6, 2008 |
| Publication date | Jan 12, 2016 |
| Grant date | Jan 12, 2016 |
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An electrical discharge surface treatment method for forming a coating film by generating a pulsed electrical discharge between an electrode and a workpiece in working fluid or gas using a green compact obtained by molding metal powder or metal alloy powder or a molded body obtained by heating the green compact as the electrode, and by melting an electrode material by an energy of the pulsed electrical discharge, forming a coating of the electrode material or a coating of a material obtained by a reaction of the electrode material by the energy of the pulsed electrical discharge on a surface of the workpiece, the electrical discharge surface treatment method includes generating the pulsed electrical discharge by mixing together two or more types of pulsed electrical discharges having different energies.
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The invention claimed is: 1. An electrical discharge surface treatment method for forming a coating film by generating a pulsed electrical discharge between an electrode and a workpiece in working fluid or gas using a green compact obtained by molding metal powder or metal alloy powder or a molded body obtained by heating the green compact as the electrode, and by melting an electrode material by an energy of the pulsed electrical discharge, forming a coating of the electrode material or a coating of a material obtained by a reaction of the electrode material by the energy of the pulsed electrical discharge on a surface of the workpiece, the electrical discharge surface treatment method comprising generating the pulsed electrical discharge by mixing together two or more types of pulsed electrical discharges, wherein each of the two or more types of pulsed electrical discharges has different energies from each other, and wherein the two or more types of pulsed electrical discharges comprise: a first pulsed electrical discharge comprising a plurality of first pulses each pulse having a first pulse width and a plurality of first pause times, each first pause time having a predetermined length, between the plurality of first pulses; and a second pulsed electrical discharge comprising a plurality of second pulses each pulse having a second pulse width shorter than the first pulse width and a plurality of second pause times, shorter than the first pause times, between the plurality of second pulses, wherein the first pulsed electrical discharge and the second pulsed electrical discharge are repeatedly periodically alternated for processing said workpiece, each pulsed electrical discharge having a predetermined length of time, between the electrode and the workpiece. 2. The electrical discharge surface treatment method according to claim 1 , wherein the metal alloy contains equal to or more than 40 volume % of a metal material whose Gibbs free energy, for forming carbide, is equal to that of Cr or higher in an Ellingham diagram at a specific temperature. 3. The electrical discharge surface treatment method according to claim 2 , wherein the metal material whose Gibbs free energy, for forming carbide, is equal to that of Cr or higher in the Ellingham diagram at a specific temperature includes Co (cobalt), Ni (nickel), Fe (iron), W (tungsten), and Mo (molybdenum). 4. The electrical discharge surface treatment method according to claim 1 , wherein the pulsed electrical discharge is generated by mixing together the first pulsed electrical discharge with a pulse width equal to or longer than 50 microseconds and the second pulsed electrical discharge with a pulse width equal to or shorter than 20 microseconds. 5. The electrical discharge surface treatment method according to claim 1 , wherein the first pulsed electrical discharge and the second pulsed electrical discharge are generated in said alternate manner with a predetermined cycle. 6. The electrical discharge surface treatment method according to claim 5 , wherein the cycle is 10 milliseconds to 20 seconds. 7. The electrical discharge surface treatment method according to claim 5 , wherein the cycle is changed according to an area of forming the coating film. 8. The electrical discharge surface treatment method according to claim 1 , wherein the second pulsed electrical discharge is generated in a successive manner until a convex-shaped portion formed by melting the electrode material in a coating film formed by the first pulsed electrical discharge is covered by a coating film formed by the second pulsed electrical discharge. 9. The electrical discharge surface treatment method according to claim 1 , wherein a particle diameter of particles distributed around a convex-shaped portion formed by melting the electrode material in a coating film formed by the first pulsed electrical discharge is equal to or smaller than a particle diameter of particles in a coating film formed by the second pulsed electrical discharge. 10. The electrical discharge surface treatment method according to claim 1 , wherein the pulsed electrical discharge having different energies is generated by mixing together two or more types of pulses having different peak current values from each other.
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