Liquid crystalline composition having a pearly luster

Patent metadata

Field	Value
Publication number	US-9234091-B2
Application number	US-201414527806-A
Country	US
Kind code	B2
Filing date	Oct 30, 2014
Priority date	Dec 19, 2013
Publication date	Jan 12, 2016
Grant date	Jan 12, 2016

Abstract

A polymer composition that contains a liquid crystalline polymer and a pearlescent filler is provided. By selectively controlling the type and relative concentration of these components, the polymer composition and shaped parts formed therefrom can be achieved that have a pearly luster appearance similar to parts plated with metals, such as copper, brass, or bronze.

First claim

What is claimed is:

1. A liquid crystalline polymer composition that has a pearly luster, wherein the polymer composition comprises a liquid crystalline polymer in an amount of from about 50 wt. % to about 95 wt. % and a pearlescent filler, wherein the pearlescent filler includes flake-shaped silicate mineral particles coated with a metal oxide layer.

2. The liquid crystalline polymer composition of claim 1 , wherein the liquid crystalline polymer contains repeating units derived from an aromatic dicarboxylic acid, an aromatic hydroxycarboxylic acid, or a combination thereof.

3. The liquid crystalline polymer composition of claim 1 , wherein the polymer further comprises one or more repeating units derived from an aromatic diol, an aromatic amide, an aromatic amine, or a combination thereof.

4. The liquid crystalline polymer composition of claim 1 , wherein the liquid crystalline polymer is wholly aromatic.

5. The liquid crystalline polymer composition of claim 1 , wherein the particles have an aspect ratio of about 4:1 or more.

6. The liquid crystalline polymer composition of claim 1 , wherein the particles have an average length of from about 1 to about 100 micrometers.

7. The liquid crystalline polymer composition of claim 1 , wherein the particles include mica.

8. The liquid crystalline polymer composition of claim 1 , wherein the metal oxide layer includes titanium dioxide, tin dioxide, iron oxide, zirconium dioxide, silicon dioxide, aluminum oxide, magnesium oxide, manganese dioxide, or a combination thereof.

9. The liquid crystalline polymer composition of claim 1 , wherein the particles are coated with a titanium dioxide layer.

10. The liquid crystalline polymer composition of claim 1 , wherein the particles are coated with a first metal oxide layer and a second metal oxide layer that overlies the first metal oxide layer.

11. The liquid crystalline polymer composition of claim 10 , wherein the first metal oxide layer includes titanium dioxide and the second metal oxide layer contains iron oxide.

12. The liquid crystalline polymer composition of claim 11 , further comprising a tin oxide layer.

13. The liquid crystalline polymer composition of claim 1 , wherein the pearlescent filler is present in an amount of from about 5 wt. % to about 50 wt. % based on the weight of liquid crystalline polymers in the composition.

14. The liquid crystalline polymer composition of claim 1 , wherein liquid crystalline polymers constitute from about 60 wt. % to about 90 wt. % of the polymer composition.

15. A molded part that defines a surface with a pearly luster, wherein the part comprises the liquid crystalline polymer composition of claim 1 .

16. The molded part of claim 15 , wherein the surface has a first color and a metal has a second color, wherein the difference between the first color and the second color is about 12 or less as determined by the CIELAB test and represented by ΔE in the following equation:
Δ E =[(Δ L *) 2 +(Δ a *) 2 +(Δ b *) 2 ] 1/2

wherein,
ΔL* is the luminosity value L* of the first color subtracted from the luminosity value L* of the second color, wherein L* ranges from 0 to 100, where 0=dark and 100=light;
Δa* is the red/green axis value at of the first color subtracted from the red/green axis value a* of the second color, wherein at ranges from −100 to 100, and where positive values are reddish and negative values are greenish; and
Δb* is the yellow/blue axis value b* of the first color subtracted from the yellow/blue axis value b* of the second color, wherein b* ranges from −100 to 100, and where positive values are yellowish and negative values are bluish.

17. The molded part of claim 16 , wherein the metal is copper.

18. The molded part of claim 15 , wherein the part is injection molded.

19. A cookware article comprising the molded part of claim 15 .

20. The cookware article of claim 19 , wherein the article is a cooking utensil, beverage container, food tray, food container, cake pan, pie pan, cooking tray, bun pan, cooking pan, muffin pan, or bread pan.

Assignees

• Ticona Llc

Inventors

• Tyler Mark Allen
• Mulholland Bruce Michael

Classifications

• C08K9/02 Primary

  Ingredients treated with inorganic substances · CPC title

• C09K2019/521

  Inorganic solid particles · CPC title

• C09K19/3809

  Polyesters; Polyester derivatives, e.g. polyamides · CPC title

• A47J36/02

  Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay · CPC title