Composition based on electroactive terpolymer
US-2017355870-A1 · Dec 14, 2017 · US
US9234062B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9234062-B2 |
| Application number | US-201213713630-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 13, 2012 |
| Priority date | Dec 14, 2011 |
| Publication date | Jan 12, 2016 |
| Grant date | Jan 12, 2016 |
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Fluorinated macromonomers, a PCTFE-g-poly(M) graft copolymer, and moisture barrier films and articles formed therefrom are provided. The PCTFE-g-poly(M) graft copolymers have a PCTFE backbone component and a plurality of pendant groups attached to the PCTFE backbone component.
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What is claimed is: 1. A poly-chlorotrifluoroethylene (PCTFE) graft copolymer having a PCTFE backbone component and a plurality of polymeric pendant groups poly(M) attached to said PCTFE backbone component (PCTFE-g-poly(M)), wherein M is a monomeric unit of the polymeric pendant groups, and wherein the monomeric unit M comprises chlorotrifluoroethylene and the polymeric pendant groups poly(M) comprise PCTFE. 2. The PCTFE-g-poly(M) graft copolymer of claim 1 comprising from about 2 to about 20 pendant groups attached to the PCTFE backbone component. 3. A film formed from the PCTFE-g-poly(M) graft copolymer of claim 1 . 4. An article comprising the film of claim 3 . 5. The PCTFE-g-poly(M) graft copolymer of claim 1 wherein the PCTFE backbone component comprises one or more four-carbon chain units. 6. The PCTFE-g-poly(M) graft copolymer of claim 1 wherein the PCTFE backbone component comprises at least two four-carbon chain units. 7. The PCTFE-g-poly(M) graft copolymer of claim 1 wherein the PCTFE backbone component comprises at least three four-carbon chain units. 8. A poly-chlorotrifluoroethylene (PCTFE) graft copolymer having a PCTFE backbone component and a plurality of polymeric pendant groups poly(M) attached to said PCTFE backbone component (PCTFE-g-poly(M)), wherein M is a monomeric unit of the polymeric pendant groups, and wherein the monomeric unit M comprises vinylidenefluoride (VDF) and the polymeric pendant groups poly(M) comprise poly-vinylidenefluoride (PVDF). 9. The PCTFE-g-poly(M) graft copolymer of claim 8 comprising from about 2 to about 20 pendant groups attached to the PCTFE backbone component. 10. A film formed from the PCTFE-g-poly(M) graft copolymer of claim 8 . 11. An article comprising the film of claim 10 . 12. The PCTFE-g-poly(M) graft copolymer of claim 8 wherein the PCTFE backbone component comprises one or more four-carbon chain units. 13. The PCTFE-g-poly(M) graft copolymer of claim 8 wherein the PCTFE backbone component comprises at least two four-carbon chain units. 14. The PCTFE-g-poly(M) graft copolymer of claim 8 wherein the PCTFE backbone component comprises at least three four-carbon chain units. 15. A poly-chlorotrifluoroethylene (PCTFE) graft copolymer having a PCTFE backbone component and a plurality of polymeric pendant groups poly(M) attached to said PCTFE backbone component (PCTFE-g-poly(M)), wherein M is a monomeric unit of the polymeric pendant groups, and wherein the monomeric unit M comprises 4-bromo-3-chloro-3,4,4-trifluoro-1-butene (BCTFB) and the polymeric pendant groups poly(M) comprise poly-(4-bromo-3-chloro-3,4,4-trifluoro-1-butene) (poly-BCTFB). 16. The PCTFE-g-poly(M) graft copolymer of claim 15 comprising from about 2 to about 20 pendant groups attached to the PCTFE backbone component. 17. A film formed from the PCTFE-g-poly(M) graft copolymer of claim 15 . 18. An article comprising the film of claim 17 . 19. The PCTFE-g-poly(M) graft copolymer of claim 15 wherein the PCTFE backbone component comprises one or more four-carbon chain units. 20. The PCTFE-g-poly(M) graft copolymer of claim 15 wherein the PCTFE backbone component comprises at least two four-carbon chain units.
containing fluorine atoms · CPC title
Polymers provided for in subclasses C08C or C08F · CPC title
Trifluorochloroethene · CPC title
Mixtures of peroxy-compounds · CPC title
Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 · CPC title
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