Two stage oxygenate conversion reactor with improved selectivity

Patent metadata

Field	Value
Publication number	US-9233885-B2
Application number	US-79329010-A
Country	US
Kind code	B2
Filing date	Jun 3, 2010
Priority date	Jun 3, 2010
Publication date	Jan 12, 2016
Grant date	Jan 12, 2016

Abstract

A process and apparatus is presented for the improved selectivity of oxygenate conversion to olefins. The process includes passing a process stream through a two stage reactor, wherein the process stream is separated from the catalyst in the first stage before passing the process stream to the second stage. The catalyst is continuously passed through the two stages, and cycles through a regeneration unit to control the carbon content on the catalyst.

First claim

The invention claimed is:

1. A process for the conversion of oxygenates to olefins comprising:
passing an oxygenate feedstream to a first stage reactor;
contacting the oxygenate feedstream with a catalyst in a fluidized bed in the first stage reactor, thereby creating an intermediate stream;
separating catalyst from the intermediate stream comprising olefins, wherein at least 96% of the catalyst is removed from the intermediate stream, thereby creating an intermediate product stream and a first returned catalyst stream, comprising a first portion and a second portion;
returning the first portion of the first returned catalyst stream to the first stage reactor, wherein the first portion of the first returned catalyst stream comprises catalyst in the same form as recovered from the intermediate stream;
passing the intermediate product stream to a second stage reactor;
contacting the intermediate product stream with a catalyst in a fluidized bed in the second stage reactor, thereby creating an effluent stream;
separating catalyst from the effluent stream thereby creating a product stream and a second returned catalyst stream;
returning the second returned catalyst stream to the second stage reactor, wherein the second returned catalyst stream comprises catalyst in the same form as recovered from the effluent stream;
passing the second portion of the first returned catalyst stream to a regenerator to create a regenerated catalyst stream; and
passing the regenerated catalyst stream to the second reactor.

2. The process of claim 1 wherein the first stage reactor is operated at a temperature in the range of 200° C. to 700° C.

3. The process of claim 2 wherein the first stage reactor is operated at a temperature in the range of 400° C. to 550° C.

4. The process of claim 1 wherein the first stage reactor is operated at a pressure in the range of 0.1 kPa to 10 MPa.

5. The process of claim 4 wherein the first stage reactor is operated at a pressure in the range of 100 kPa to 800 kPa.

6. The process of claim 5 wherein the first stage reactor is operated at a pressure in the range of 170 kPa to 800 kPa.

7. The process of claim 1 wherein the oxygenate feed stream comprises methanol.

8. The process of claim 1 further comprising cooling the first returned catalyst stream.

9. The process of claim 1 further comprising cooling the second returned catalyst stream.

10. The process of claim 1 wherein the second stage reactor is operated at a temperature in the range of 200° C. to 700° C.

11. The process of claim 1 wherein the second stage reactor is operated at a pressure in the range of 0.1 kPa to 10 MPa.

12. The process of claim 1 wherein the second portion of the first returned catalyst stream is less than 50% of the first returned catalyst stream.

13. The process of claim 1 further comprising passing air to the regeneration unit.

14. The process of claim 1 further comprising passing the regenerated catalyst stream to the second stage reactor.

15. A process for the conversion of oxygenates to olefins comprising:
passing an oxygenate feedstream to a first stage reactor;
contacting the oxygenate feedstream with a catalyst in a fluidized bed in the first stage reactor, thereby creating an intermediate stream;
separating catalyst from the intermediate stream comprising olefins, wherein at least 96% of the catalyst is removed from the intermediate stream, thereby creating an intermediate product stream and a first returned catalyst stream;
returning the first returned catalyst stream to the first stage reactor and passing the intermediate product stream to a second stage reactor;
passing a portion of the first returned catalyst stream to a regeneration unit;
passing the regenerated catalyst from the regeneration unit to the second stage reactor;
contacting the intermediate product stream with the regenerated catalyst in a fluidized bed in the second stage reactor, thereby creating an effluent stream;
separating catalyst from the effluent stream thereby creating a product stream and a second returned catalyst stream;
returning a portion of the second returned catalyst stream to the second stage reactor;
returning a portion of the second returned catalyst stream to the first stage reactor; and
passing a regenerated catalyst stream to the second stage reactor.

Assignees

• Stevens Carl J
• Sechrist Paul A
• Johnson Ii Richard A
• Uop Llc

Inventors

• Stevens Carl J
• Sechrist Paul A
• Johnson Ii Richard A

Classifications

• B01J2208/00212

  Plates; Jackets; Cylinders · CPC title

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• B01J8/26

  with two or more fluidised beds, e.g. reactor and regeneration installations · CPC title

• B01J2219/0004

  Processes in series · CPC title

• C07C2529/85

  Silicoaluminophosphates (SAPO compounds) · CPC title