Method for the siliceous bonding of coated and uncoated optical bodies

Patent metadata

Field	Value
Publication number	US-9233873-B2
Application number	US-201113697253-A
Country	US
Kind code	B2
Filing date	May 9, 2011
Priority date	May 11, 2010
Publication date	Jan 12, 2016
Grant date	Jan 12, 2016

Abstract

The present invention pertains to a process for the silicate bonding of joined surfaces, facing one another, of two components by means of an aqueous, alkaline, silicon-cation-containing joining solution for the purpose of producing an optical element, characterized in that one or both of said joined surfaces ( 1; 2 b; 10 ) are covered with a layer of an oxide ( 3 ), which has a higher refractive index than SiO 2 and is selected from among oxides of the third and fourth main group elements, of the second and third group of the transition elements as well as zirconium and from among mixed oxides of the said elements, whereupon the joining solution is applied to at least one of the surfaces to be joined and the surfaces are bonded to one another. The present invention also teaches the use of oxide layer ( 3 ) as a topmost layer of a component to be joined by means of an alkaline, silicate-containing solution for preventing or reducing opacifications and/or defects as a result of a chemical attack on the layer lying under it by the said alkaline solution.

First claim

What is claimed is:

1. Process for siliceous bonding of surfaces to be joined, facing one another, of two components by means of an aqueous, alkaline, silicon-cation-containing joining solution for the purpose of producing an optical element, characterized in that said surfaces to be joined are covered with a layer of an oxide, which has a higher refractive index than SiO 2 and is selected from the group consisting of oxides of the third and fourth main group elements, of the second (IIB) and third (IIIB) group of the transition elements and zirconium and from the group consisting of mixed oxides of said elements, whereupon the joining solution is applied to at least one of the surfaces to be joined and the surfaces are bonded to one another, and wherein the oxide is applied by a technique selected from the group consisting of vapor deposition methods, thin-layer deposition methods and atomic layer deposition methods.

2. Process according to claim 1 , wherein the oxide is selected from the group consisting of oxides of the third main group elements, of the second (IIB) and third (IIIB) group of the transition elements, of germanium, of zirconium, of mixed oxides of said elements with one another as well as of mixed oxides of said elements with tin oxide.

3. Process according to claim 2 , wherein the oxide is selected from the group consisting of aluminum oxide, zirconium oxide, an oxide doped with aluminum and an oxide containing tin in a portion of up to 50 at. % of the cations.

4. Process according to claim 3 , wherein the oxide is aluminum oxide.

5. Process according to claim 1 , wherein the oxide layer has a thickness between 5 nm and 1,500 nm.

6. Process according to claim 5 , wherein the oxide layer has a thickness in the range of 50-120 nm.

7. Process according to claim 1 , wherein the surfaces to be joined consist of a material, which is selected from the group consisting of silicon dioxide, a boron-containing glass, titanium dioxide, hafnium dioxide, niobium trioxide, tantalum pentoxide and a metal.

8. Process according to claim 7 , wherein the surfaces to be joined consist of chromium, aluminum and titanium.

9. Process according to claim 1 , wherein the joining takes place with a joining solution, which has a pH value of greater than 11.

10. Process according to claim 1 , wherein the joining takes place at temperatures between 2° C. and 70° C., and then a drying process takes place at temperatures of 50° C. to 120° C.

11. Process according to claim 10 , wherein the layer lying under the topmost layer consists of a material selected from the group consisting of a boron-containing glass, silicon dioxide, titanium dioxide, hafnium dioxide, niobium trioxide, tantalum pentoxide and a metal selected from the group consisting of chromium, aluminum and titanium.

12. Process according to claim 10 , wherein the joining takes place at temperatures between 5° C. and 40° C., and then a drying process takes place at 100° C.

13. Process according to claim 1 , characterized by a heat treatment at temperatures between 50° C. and 350° C. following the joining.

14. Process according to claim 1 , wherein the vapor deposition methods are selected from the group consisting of chemical vapor deposition and physical vapor deposition (PVD) methods.

15. Process according to claim 1 , wherein the oxide is applied by a technique selected from the group consisting of sputtering techniques, electron beam vapor deposition under vacuum and ion-supported vapor deposition.

16. Process for the siliceous bonding of surfaces to be joined, facing one another, of two components by means of an aqueous, alkaline, silicon-cation-containing joining solution for the purpose of producing an optical element, wherein one of the two surfaces to be joined consists of an oxide, which has a higher refractive index than SiO 2 and is selected from the group consisting of oxides of the third and fourth main group elements, of the second (IIB) and third (IIIB) group of the transition elements and zirconium and from the group consisting of mixed oxides of said elements, characterized in that the other of the two surfaces to be joined is covered with a layer of an oxide, which has a higher refractive index than SiO 2 and is selected from the group consisting of oxides of the third and fourth main group elements, of the second (IIB) and third (IIIB) group of the transition elements as well as zirconium and from the group consisting of mixed oxides of said elements, whereupon the joining solution is applied to at least one of the surfaces to be joined and the surfaces are bonded to one another, and wherein the oxide is applied by a technique selected from the group consisting of vapor deposition methods, thin-layer deposition methods and atomic layer deposition methods.

17. Process according to claim 16 , wherein the vapor deposition methods are selected from the group consisting of chemical vapor deposition and physical vapor deposition (PVD) methods.

18. Process according to claim 16 , wherein the oxide is applied by a technique selected from the group consisting of sputtering techniques, electron beam vapor deposition under vacuum and ion-supported vapor deposition.

Assignees

• Kalkowski Gerhard
• Fabian Simone
• Jahnke Charlotte
• Eberhardt Ramona
• Schuermann Mark
• Fraunhofer Ges Forschung

Inventors

• Kalkowski Gerhard
• Fabian Simone
• Jahnke Charlotte
• Eberhardt Ramona
• Schuermann Mark

Classifications

• C09J2400/166

  in the pretreated surface to be joined · CPC title

• C04B2237/341

  Silica or silicates · CPC title

• C03C17/23

  Oxides (C03C17/02 takes precedence) · CPC title

• C04B2237/346

  Titania or titanates · CPC title

• C04B37/005

  consisting of glass or ceramic material · CPC title