Process for producing water-absorbing resin

Patent metadata

Field	Value
Publication number	US-9233186-B2
Application number	US-201113634151-A
Country	US
Kind code	B2
Filing date	Mar 14, 2011
Priority date	Mar 12, 2010
Publication date	Jan 12, 2016
Grant date	Jan 12, 2016

Abstract

The disclosed process for producing a water-absorbing resin comprising: a polymerization step of polymerizing an aqueous unsaturated monomer; a drying step of drying a particulated water-containing gel-liked crosslinked polymer, obtained in a finely crushing step during the polymerization or after the polymerization; a pulverizing step after the drying, a classification step after the drying, and a surface treatment step after the classification. In the process is, the surface-treatment step is interrupted with a heating treatment apparatus kept in a heated state and thereafter the surface treatment step is restarted.

First claim

The invention claimed is:

1. A process for producing a water-absorbing resin comprising a polymerization step of polymerizing an aqueous unsaturated monomer solution, a drying step of drying a particulated water-containing gel-like crosslinked polymer obtained in a finely crushing step during the polymerization or after the polymerization, a pulverizing step after the drying, a classification step after the drying, and a surface treatment step for the water-absorbing resin powder after the classification step, wherein
the surface treatment step is a heating treatment step by using a heating treatment apparatus, and where the surface treatment step is continuous treatment where the water-absorbing resin is continuously charged to and continuously discharged out of the heating treatment apparatus and an operation time of the continuous treatment step is not shorter than 24 hours,
the surface treatment step is interrupted while the heating treatment apparatus is kept in a heated state and thereafter the surface treatment step is restarted, and
the interruption time of the surface treatment step is not shorter than 0.5 hours and within 100 days,
the interruption of the surface treatment step means a state where the water-absorbing resin powder is absent in the heating treatment apparatus, or not charged to or not discharged out of the heating treatment apparatus in the surface treatment, and
a state not charged to or not discharged out of an apparatus means a state where a water-absorbing resin powder is stopped in an apparatus and a state where the apparatus is stopped.

2. The production process according to claim 1 , wherein the surface treatment step is surface-crosslinking by a heating reaction.

3. The production process according to claim 1 , wherein the heating treatment apparatus is a transverse type continuous stifling apparatus having a charging inlet and a discharge outlet for a water absorbent resin powder, as well as a stirring means including one or more of rotary shafts equipped with a plurality of stirring disks and a heating means, and the apparatus is stopped in a heated state.

4. The production process according to claim 1 , wherein the temperature of the heating treatment apparatus during the interruption time of the surface treatment step is lower than a heating treatment temperature by 10° C. or more.

5. The production process according to claim 1 , wherein the temperature of the heating treatment apparatus during the interruption time of the heating treatment step is 80 to 140° C.

6. The production process according to claim 1 , wherein water-absorbing resin fine particles obtained in the classification step are recycled to the particulated water-containing gel-like crosslinked polymer before the drying.

7. The production process according to claim 1 , wherein the water-absorbing resin powder is subjected to the surface treatment at not less than 1 [t/hr] in the surface treatment step.

8. The production process according to claim 1 , wherein the heating treatment apparatus during the interruption time of the surface treatment step is heated by heated steam or hot air.

9. The production process according to claim 8 , wherein the heated steam is recycled.

10. The production process according to claim 1 , further comprising, after the surface treatment step, a second classification step after surface-crosslinking, and/or a fine powder recovery step after the second classification step.

11. The production process according to claim 1 , wherein a gas having a dew point of −100 to −5° C. is injected into the heating treatment apparatus during the interruption time of the surface treatment step.

12. The production process according to claim 1 , wherein a surface-crosslinking agent to be used in the surface treatment step is a dehydration reactive surface-crosslinking agent.

Assignees

• Kanzaki Syuji
• Okuda Sumio
• Ishizaki Kunihiko
• Matsumoto Satoshi
• Nippon Catalytic Chem Ind

Inventors

• Kanzaki Syuji
• Okuda Sumio
• Ishizaki Kunihiko
• Matsumoto Satoshi

Classifications

• C08J2300/14

  Water soluble or water swellable polymers, e.g. aqueous gels · CPC title

• B01J2220/68

  Superabsorbents · CPC title

• A61L15/60

  Liquid-swellable gel-forming materials, e.g. super-absorbents · CPC title

• C08J2333/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• A61L15/56 Primary

  Wetness-indicators or colourants · CPC title