Epoxy curative composition and compositions therefrom
US-2018371154-A1 · Dec 27, 2018 · US
US9232636B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9232636-B2 |
| Application number | US-201113992189-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 18, 2011 |
| Priority date | Dec 21, 2010 |
| Publication date | Jan 5, 2016 |
| Grant date | Jan 5, 2016 |
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The flexible printed wiring board according to the present invention includes a first flexible insulating layer, a first conductor wiring laminated on the first insulating layer, a second single-layered insulating layer laminated on the first insulating layer, as it covers the first conductor wiring, and a second conductor wiring laminated on the second insulating layer. The first conductor wiring has a thickness in the range of 10 to 30 μm, a line width in the range of 50 μm to 1 mm, and a line gap in the range of 50 μm to 1 mm. The thickness from the surface of the first conductor wiring to the surface of the second insulating layer is in the range of 5 to 30 μm. The surface waviness of the part of the second insulating layer covering the first conductor wiring is 10 μm or less.
Opening claim text (preview).
The invention claimed is: 1. A flexible printed wiring board, comprising a first insulating layer that is flexible, a first conductor wiring laminated on the first insulating layer, a second insulating layer that is a single layer and laminated on the first insulating layer, as it covers the first conductor wiring, and a second conductor wiring laminated on the second insulating layer, wherein: the first conductor wiring has a thickness in the range of 10 to 30 μm, a line width in the range of 50 μm to 1 mm, and a line gap in the range of 50 μm to 1 mm; a thickness from a surface of the first conductor wiring to a surface of the second insulating layer is in the range of 5 to 30 μm; a surface waviness of part of the second insulating layer covering the first conductor wiring is 10 μm or less; the second insulating layer is made of a hardened product of an epoxy resin composition containing an epoxy resin, a curing agent, and a carbodiimide-modified soluble polyamide; and the epoxy resin contains a naphthalene skeleton-containing epoxy resin. 2. A flexible printed wiring board, comprising a first insulating layer that is flexible, a first conductor wiring laminated on the first insulating layer, a second insulating layer that is laminated on the first insulating layer, as it covers the first conductor wiring, and a second conductor wiring laminated on the second insulating layer, wherein: the second insulating layer includes a third insulating layer directly laminated on the first insulating layer and a fourth insulating layer laminated on the third insulating layer; the first conductor wiring has a thickness in the range of 10 to 30 μm, a line width in the range of 50 μm to 1 mm, and a line gap in the range of 50 μm to 1 mm; a thickness from a surface of the first conductor wiring to a surface of the third insulating layer, among the multiple layers constituting the second insulating layer, is in the range of 5 to 30 μm; a surface waviness of part of the second insulating layer covering the first conductor wiring is 10 μm or less; the third insulating layer is made of a hardened product of an epoxy resin composition containing an epoxy resin, a curing agent, and a carbodiimide-modified soluble polyamide; and the epoxy resin contains a naphthalene skeleton-containing epoxy resin. 3. The flexible printed wiring board as set forth in claim 1 , wherein a content of the carbodiimide-modified soluble polyamide in the epoxy resin composition is in the range of 40 to 70 mass %. 4. The flexible printed wiring board as set forth in claim 1 , wherein the naphthalene skeleton-containing epoxy resin contains at least one compound selected from compounds represented by the following formulae (1) to (3): 5. The flexible printed wiring board as set forth in claim 1 , wherein the curing agent contains at least one of dicyandiamide and aminotriazine novolac resins represented by the following formula (4): 6. The flexible printed wiring board as set forth in claim 1 , wherein the carbodiimide-modified soluble polyamide contains a reaction product of 100 parts by mass of a soluble polyamide and 0.5 to 20 parts by mass of a carbodiimide compound. 7. The flexible printed wiring board as set forth in claim 1 , wherein the epoxy resin composition contains a phenoxy resin. 8. The flexible printed wiring board as set forth in claim 1 , wherein the epoxy resin composition contains at least one compound selected from phosphorus-modified epoxy resins, phosphorus-modified phenoxy resins, and phosphorus-based flame retardants. 9. The flexible printed wiring board as set forth in claim 1 , wherein a through hole is formed in the first insulating layer and part of the second insulating layer fills the through hole. 10. A laminate for production of a flexible printed wiring board comprising: a first insulating layer that is flexible, a first conductor wiring laminated on the first insulating layer, a second insulating layer that is a single layer and laminated on the first insulating layer, as it covers the first conductor wiring, and a metal foil laminated on the second insulating layer, wherein the first conductor wiring has a thickness in the range of 10 to 30 μm, a line width in the range of 50 μm to 1 mm, and a line gap in the range of 50 μm to 1 mm; a thickness from a surface of the first conductor wiring to a surface of the second insulating layer is in the range of 5 to 30 μm; a surface waviness of part of the second insulating layer covering the first conductor wiring is 10 μm or less; the second insulating layer is made of a hardened product of an epoxy resin composition containing an epoxy resin, a curing agent, and a carbodiimide-modified soluble polyamide; and the epoxy resin contains a naphthalene skeleton-containing epoxy resin. 11. A laminate for production of a flexible printed wiring board comprising a first insulating layer that is flexible, a first conductor wiring laminated on the first insulating layer, a second insulating layer that is laminated on the first insulating layer, as it covers the first conductor wiring, and a metal foil laminated on the second insulating layer, wherein the second insulating layer includes a third insulating layer directly laminated on the first insulating layer and a fourth insulating layer laminated on the third insulating layer; the first conductor wiring has a thickness in the range of 10 to 30 μm, a line width in the range of 50 μm to 1 mm, and a line gap in the range of 50 μm to 1 mm; a thickness from a surface of the first conductor wiring to a surface of the third insulating layer, among the multiple layers constituting the second insulating layer, is in the range of 5 to 30 μM; a surface waviness of part of the second insulating layer covering the first conductor wiring is 10 μm or less; the third insulating layer is made of a hardened product of an epoxy resin composition containing an epoxy resin, a curing agent, and a carbodiimide-modified soluble polyamide; and the epoxy resin contains a naphthalene skeleton-containing epoxy resin. 12. The flexible printed wiring board as set forth in claim 2 , wherein a content of the carbodiimide-modified soluble polyamide in the epoxy resin composition is in the range of 40 to 70 mass %. 13. The flexible printed wiring board as set forth in claim 2 , wherein the naphthalene skeleton-containing epoxy resin contains at least one compound selected from compounds represented by the following formulae (1) to (3): 14. The flexible printed wiring board as set forth in claim 2 , wherein the curing agent contains at least one of dicyandiamide and aminotriazine novolac resins represented by the following formula (4): 15. The flexible printed wiring board as set forth in claim 2 , wherein the carbodiimide-modified soluble polyamide contains a reaction product of 100 parts by mass of a soluble polyamide and 0.5 to 20 parts by mass of a carbodiimide compound. 16. The flexible printed wiring board as set forth in claim 2 , wherein the epoxy resin composition contains a phenoxy resin. 17. The flexible printed wiring board as set forth in claim 2 , wherein the epoxy res
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