Flat and high-density cathodes for use in electrochemical cells

Patent metadata

Field	Value
Publication number	US-9231256-B2
Application number	US-201213556242-A
Country	US
Kind code	B2
Filing date	Jul 24, 2012
Priority date	Dec 13, 2004
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

The traditional method of pressing CF x , screen and SVO sheet assembly results in an electrode that is cupped and not flat. This results in the reduction of the effective volumetric energy density of the electrode or the addition of a process step of flattening of the cathode if at all possible. The new method of assembly effectively eliminates the cupping behavior and produces a flat electrode. In addition, the physical density of the cathode is also increased.

First claim

What is claimed is:

1. An electrochemical cell, which comprises:
a) an anode;
b) a cathode, comprising:
i) a first cathode current collector comprising first and second major current collector sides;
ii) a first cathode active material selected from the group consisting of CF x (wherein x is from about 0.1 to about 1.9), Ag 2 O, Ag 2 O 2 , CuF, Ag 2 CrO 4 , MnO 2 , SVO, and mixtures thereof, wherein the first cathode active material has a relatively high energy density but a relatively low rate capability, and
iii) a second cathode active material selected from the group consisting of SVO, CSVO, V 2 O 5 , MnO 2 , LiCoO 2 , LiNiO 2 , LiMnO 2 , CuO 2 , TiS 2 , Cu 2 S, FeS, FeS 2 , copper vanadium oxide and mixtures thereof, wherein the second cathode active material has a relatively low energy density but a relatively high rate capability, and
iv) wherein when SVO is the first cathode active material, it is not the second cathode active material;
v) wherein the first cathode active material is characterized as having been formed into a first free-standing cathode blank at a first pressure and then positioned in a contact relationship with the first major side of the first cathode current collector; and
vi) wherein a second free-standing blank of the second cathode active material is characterized as having been positioned in a contact relationship with the second major side of the first cathode current collector to thereby provide a cathode assembly; and
vii) wherein the cathode is further characterized as having been formed by pressing the cathode assembly at a second pressure that is less than the first pressure previously used to form the first cathode blank, so that the first cathode blank of the first cathode active material cups in a range from 2% to about 5% toward the second cathode blank of the second cathode active material after the second pressure is removed from the thusly formed cathode;

c) a separator intermediate the anode and cathode in electrical association with each other; and
d) an electrolyte activating the anode and cathode.

2. The electrochemical cell of claim 1 wherein the anode is lithium, the first cathode active material is CF x (wherein x is from about 0.1 to about 1.9), and the second cathode active material is SVO.

3. The electrochemical cell of claim 1 wherein a second cathode current collector comprises third and fourth major current collector sides and wherein a third cathode active material being the same as the first cathode active material is contacted to the fourth major current collector side with the third major side of the second current collector contacted to the second cathode blank of the second cathode active material opposite the second side of the first cathode current collector thus forming a cathode assembly, the cathode characterized as having been formed by pressing the cathode assembly comprising the first, second and third cathode blanks to the respective first and second cathode current collectors at a third pressure that is less than the first pressure.

4. The electrochemical cell of claim 1 wherein the first cathode current collector is of titanium having a layer of graphite/carbon contacted thereto.

5. An electrochemical cell, which comprises:
a) an anode;
b) a cathode, comprising:
i) a cathode current collector comprising titanium having first and second major current collector sides with a graphite/carbon layer supported on at least the first major side thereof;
ii) CF x (wherein x is from about 0.1 to about 1.9) characterized as having been formed into a first free-standing CF x blank at a first pressure and then positioned in a contact relationship with the first side of the titanium cathode current collector supporting the graphite/carbon layer; and
iii) a second free-standing blank of silver vanadium oxide (SVO) characterized as having been positioned in a contact relationship with the second side of the cathode current collector to thereby provide a cathode assembly,
iv) wherein the cathode is further characterized as having been formed by pressing the cathode assembly at a second pressure that is less than the first pressure previously used to form the CF x blank, so that the CF x cups in a range from 2% to about 5% toward the SVO after the second pressure is removed from the thusly formed cathode;

c) a separator intermediate the anode and cathode in electrical association with each other; and
d) an electrolyte activating the anode and cathode.

6. The electrochemical cell of claim 5 wherein the anode is lithium.

7. The electrochemical cell of claim 5 wherein the cathode current collector has a thickness from about 0.001 inches to about 0.01 inches.

8. The electrochemical cell of claim 5 wherein the anode is of lithium in the form of at least one plate comprising an anode current collector electrically connected to a casing as its terminal and the cathode current collector is electrically connected to a cathode terminal insulated from the casing.

9. A cathode, comprising:
a) a cathode current collector, comprising:
i) first and second major current collector sides, the cathode current collector being selected from the group consisting of stainless steel, titanium, tantalum, platinum, aluminum, gold, nickel, and alloys thereof,
ii) wherein, when the cathode current collector is of titanium, a graphite/carbon outer layer is supported on at least the first major side thereof;

b) CF x (wherein x is from about 0.1 to about 1.9) characterized as having been formed into a first free-standing CF x blank at a first pressure and then positioned in a contact relationship with the first major side of the cathode current collector;
c) a second free-standing blank of silver vanadium oxide (SVO) characterized as having been positioned in a contact relationship with the second major side of the cathode current collector to thereby provide a cathode assembly,
d) wherein the cathode is further characterized as having been formed by pressing the cathode assembly at a second pressure that is less than the first pressure previously used to form the CF x blank, so that the CF x cups in a range from 2% to about 5% toward the SVO after the second pressure is removed from the thusly formed cathode.

10. The cathode of claim 9 wherein the first pressure is greater than about 4 tons/cm 2 .

11. The electrochemical cell of claim 1 wherein the second cathode blank of the second cathode active material is characterized as having been contacted to the second major side of the first cathode current collector either before or after the first cathode blank is contacted to the first major side of the first cathode current collector.

12. The electrochemical cell of claim 5 wherein the SVO blank is characterized as having been contacted to the second major side of the cathode current collector either before or after the CF x blank is contacted to the first major side of the cathode current collector.

13. The cathode of claim 9 wherein the SVO blank is characterized as having been contacted to the second major side of the cathode current collector either before or after the CF x blank is contacted to the first major side of the cathode current collector.

14. The electrochemical cell of claim 1 wherein the first cathode current collector is selected from the group consisting of stainless steel, titanium, tantalum, platinum, aluminum, gold, nickel, and alloys thereof.

15. The electrochemical cell of claim 1 wherein the first cathode current collector is perforated.

16. The electrochemical cell of claim 5 wherein the cathode curr

Assignees

• Shah Ashish
• Rubino Robert
• Gan Hong
• Greatbatch Ltd

Inventors

• Shah Ashish
• Rubino Robert
• Gan Hong

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/08

  Processes of manufacture · CPC title

• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title