Anode containing metal oxide and organic light emitting device having the same

Patent metadata

Field	Value
Publication number	US-9231228-B2
Application number	US-201113299543-A
Country	US
Kind code	B2
Filing date	Nov 18, 2011
Priority date	Jun 23, 2011
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

An anode for an organic light emitting device which introduces a metal oxide to improve flows of charges, and an organic light emitting device using the anode. The anode for the organic light emitting device has excellent charge injection characteristics, thereby improving power consumption of the organic light emitting device.

First claim

What is claimed is:

1. An anode for an organic light emitting device, comprising:
a metal layer; and
a transparent conductive layer formed on the metal layer,
the transparent conductive layer consisting essentially of a transparent conductive oxide (TCO) and a metal oxide, a metal of the metal oxide being other than the metal for the transparent conductive oxide,
the metal oxide having a content of essentially 3 wt % to essentially 15 wt % of the total weight of the transparent conductive layer, and
the metal oxide having a work function higher than a work function of the transparent conductive oxide.

2. The anode as claimed in claim 1 , the metal layer containing silver (Ag).

3. The anode as claimed in claim 1 , the metal layer having a thickness of approximately 500 Å to approximately 3000 Å.

4. The anode as claimed in claim 1 , the transparent conductive layer having a thickness of approximately 50 Å to approximately 150 Å.

5. The anode as claimed in claim 1 , the transparent conductive oxide comprising at least one selected from the group consisting of ITO, AZO, IGO, GIZO, IZO, and ZnOx.

6. The anode as claimed in claim 1 , the metal oxide being an oxide of at least one metal selected from the group consisting of Ni, Co, V, W, and Yb.

7. The anode as claimed in claim 1 , the metal oxide having a work function of approximately 5.0 eV to approximately 6.5 eV.

8. The anode as claimed in claim 1 , the transparent conductive layer having a work function of approximately 4.8 eV to approximately 6.5 eV.

9. The anode as claimed in claim 1 , the transparent conductive oxide forming a matrix within the transparent conductive layer, the metal oxide being doped into the matrix formed of the transparent conductive oxide.

10. The anode as claimed in claim 9 , the transparent conductive layer being formed through one of sputtering and deposition, where the transparent conductive oxide and the metal oxide are used as raw materials.

11. The anode as claimed in claim 1 , the transparent conductive layer comprising a thin film formed of the metal oxide disposed on a thin film formed of the transparent conductive oxide.

12. The anode as claimed in claim 11 , the thin film formed of the metal oxide having a thickness of from approximately 5 Å to approximately 50 Å.

13. The anode as claimed in claim 11 , the thin film formed of the transparent conductive oxide having a thickness of from approximately 45 Å to approximately 100 Å.

14. The anode as claimed in claim 1 , the anode comprising a reflective electrode.

15. A method of manufacturing an anode for an organic light emitting device, comprising steps of:
forming a metal layer on a substrate; and
forming a transparent conductive layer on the metal layer,
the step of forming a transparent conductive layer comprising a sputtering or deposition step where a transparent conductive oxide and a metal oxide a metal of the metal oxide being other than the metal for the transparent conductive oxide are used as raw materials,
the metal oxide having a content of essentially 3 wt % to essentially 15 wt % of the total weight of the transparent conductive layer, and
the metal oxide having a work function higher than a work function of the transparent conductive oxide.

16. The method as claimed in claim 15 , the step of forming a transparent conductive layer comprising steps of:
forming a thin film formed of the transparent conductive oxide on the metal layer using the transparent conductive oxide; and
forming a thin film formed of the metal oxide on the thin film formed of the transparent conductive oxide.

17. The method as claimed in claim 15 , the step of forming a transparent conductive layer further comprising simultaneously sputtering or depositing the transparent conductive oxide and the metal oxide so that the transparent conductive oxide forms a matrix and the metal oxide is doped into the matrix formed by the transparent conductive oxide.

18. An organic light emitting device, comprising:
a substrate;
a first electrode formed on the substrate;
an organic layer formed on the first electrode, and
a second electrode formed on the organic layer,
the organic layer including at least one layer including a light emitting layer,
one of the first electrode and the second electrode comprising an anode including a metal layer and a transparent conductive layer formed on the metal layer,
the transparent conductive layer consisting essentially of a transparent conductive oxide and a metal oxide, a metal of the metal oxide being other than the metal for the transparent conductive oxide, and
the metal oxide having a content of essentially 3 wt % to essentially 15 wt % of the total weight of the transparent conductive layer, and
the metal oxide having a work function higher than a work function of the transparent conductive oxide.

19. The light emitting device as claimed in claim 18 , the metal layer containing silver (Ag).

20. The light emitting device as claimed in claim 18 , the metal layer having a thickness of approximately 500 Å to approximately 3000 Å.

21. The light emitting device as claimed in claim 18 , the transparent conductive layer having a thickness of approximately 50 Å to approximately 150 Å.

22. The light emitting device as claimed in claim 18 , the transparent conductive oxide comprising at least one selected from the group consisting of ITO, AZO, IGO, GIZO, IZO, and ZnOx.

23. The light emitting device as claimed in claim 18 , the metal oxide being an oxide of at least one metal selected from the group consisting of Ni, Co, V, W, and Yb.

24. The light emitting device as claimed in claim 18 , the metal oxide having a work function of from approximately 5.0 eV to approximately 6.5 eV.

25. The light emitting device as claimed in claim 18 , the transparent conductive layer having a work function of from approximately 4.8 eV to approximately 6.5 eV.

26. The light emitting device as claimed in claim 18 , the transparent conductive oxide in the transparent conductive layer forming a matrix, the metal oxide being doped into the matrix formed of the transparent conductive oxide.

27. The light emitting device as claimed in claim 26 , the transparent conductive layer being formed through sputtering or deposition where the transparent conductive oxide and the metal oxide are used as raw materials.

28. The light emitting device as claimed in claim 18 , the transparent conductive layer comprising a thin film formed of the metal oxide disposed on a thin film formed of the transparent conductive oxide.

29. The light emitting device as claimed in claim 28 , the thin film formed of the metal oxide having a thickness of from approximately 5 Å to approximately 50 Å.

30. The light emitting device as claimed in claim 28 , the thin film formed of the transparent conductive oxide having a thickness of from approximately 45 Å to approximately 100 Å.

31. The light emitting device as claimed in claim 18 , the electrode including the metal layer and the transparent conductive layer formed on the metal layer being a reflective electrode.

32. The light emitting device as claimed in claim 18 , the anode including the metal layer and the transparent conductive layer formed on the metal layer being the first electrode.

Assignees

• Kim Won-Jong
• Lee Joon-Gu
• Choung Ji-Young
• Choi Jin-Baek
• Lee Yeon-Hwa
• Lee Chang-Ho
• Oh Il-Soo
• Song Hyung-Jun
• Yun Jin-Young
• Song Young-Woo
• Lee Jong-Hyuk
• Samsung Display Co Ltd

Inventors

• Kim Won-Jong
• Lee Joon-Gu
• Choung Ji-Young
• Choi Jin-Baek
• Lee Yeon-Hwa
• Lee Chang-Ho
• Oh Il-Soo
• Song Hyung-Jun
• Yun Jin-Young
• Song Young-Woo
• Lee Jong-Hyuk

Classifications

• H10H20/032

  of electrodes · CPC title

• H01L51/5218 Primary

  Electricity · mapped topic

• H05B33/26

  characterised by the composition or arrangement of the conductive material used as an electrode · CPC title

• H10K2102/301

  Details of OLEDs · CPC title

• H10K50/818 Primary

  Reflective anodes, e.g. ITO combined with thick metallic layers · CPC title