Low-bandgap, monolithic, multi-bandgap, optoelectronic devices

Patent metadata

Field	Value
Publication number	US-9231135-B2
Application number	US-201414285468-A
Country	US
Kind code	B2
Filing date	May 22, 2014
Priority date	May 21, 2002
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

Low bandgap, monolithic, multi-bandgap, optoelectronic devices ( 10 ), including PV converters, photodetectors, and LED's, have lattice-matched (LM), double-heterostructure (DH), low-bandgap GaInAs(P) subcells ( 22, 24 ) including those that are lattice-mismatched (LMM) to InP, grown on an InP substrate ( 26 ) by use of at least one graded lattice constant transition layer ( 20 ) of InAsP positioned somewhere between the InP substrate ( 26 ) and the LMM subcell(s) ( 22, 24 ). These devices are monofacial ( 10 ) or bifacial ( 80 ) and include monolithic, integrated, modules (MIMs) ( 190 ) with a plurality of voltage-matched subcell circuits ( 262, 264, 266, 270, 272 ) as well as other variations and embodiments.

First claim

We claim:

1. A monolithic, integrated, module (MIM), comprising:
a plurality of monolithic, multi-bandgap, photovoltaic converters, each of which comprises: (i) a first subcell with a first bandgap and a first lattice constant; (ii) a second subcell with a second bandgap and a second lattice constant, wherein the second bandgap is less than the first bandgap and the second lattice constant is greater than the first lattice constant; and (iii) a lattice constant transition material positioned between the first subcell and the second subcell, said lattice constant transition material having a bandgap at least as large as the first bandgap and a lattice constant that changes from the first lattice constant to the second lattice constant; and
a common substrate with a substrate bandgap and a substrate lattice constant, said common substrate being positioned between the first subcell and the lattice constant transition material of each of the monolithic, multi-bandgap, photovoltaic converters, wherein the substrate bandgap is at least as large as the first bandgap and the substrate lattice constant is equal to the first lattice constant.

2. The monolithic, integrated, module (MIM) of claim 1 , wherein the first subcells are grown epitaxially on a front side of the substrate, and wherein the lattice constant transition materials and the second subcells are grown epitaxially on a back side of the substrate.

3. The monolithic, integrated, module (MIM) of claim 1 , wherein each of the first subcells comprises GaInAs(P), each of the second subcells comprises GaInAs(P), each of the lattice constant transition materials comprises InAs y P 1−y , and the substrate comprises InP.

4. The monolithic, integrated, module (MIM) of claim 1 , further comprising a tunnel junction positioned between the first subcell and the second subcell of each of the monolithic, multi-bandgap, photovoltaic converters.

5. The monolithic, integrated, module (MIM) of claim 4 , wherein the tunnel junction is positioned between the first subcell and the substrate.

6. The monolithic, integrated, module (MIM) of claim 1 , further comprising an isolation layer positioned between the first subcell and the second subcell of each of the monolithic, multi-bandgap, photovoltaic converters.

7. A monolithic, multi-bandgap, photovoltaic converter comprising:
a first subcell with a first bandgap and a first lattice constant;
a second subcell with a second bandgap and a second lattice constant, wherein the second bandgap is less than the first bandgap and the second lattice constant is greater than the first lattice constant;
a lattice constant transition material positioned between the first subcell and the second subcell, said lattice constant transition material having a bandgap at least as large as the first bandgap and a lattice constant that changes from the first lattice constant to the second lattice constant; and
a substrate with a substrate bandgap and a substrate lattice constant, said substrate being positioned between the first subcell and the lattice constant transition material, wherein the substrate bandgap is at least as large as the first bandgap and the substrate lattice constant is equal to the first lattice constant.

8. The monolithic, multi-bandgap, photovoltaic converter of claim 7 , wherein the first subcell is grown epitaxially on a front side of the substrate, and wherein the lattice constant transition material and the second subcell are grown epitaxially on a back side of the substrate.

9. The monolithic, multi-bandgap, photovoltaic converter of claim 7 , wherein the first subcell comprises GaInAs(P), the second subcell comprises GaInAs(P), the lattice constant transition material comprises InAs y P 1−y , and the substrate comprises InP.

10. The monolithic, multi-bandgap, photovoltaic converter of claim 7 , further comprising a tunnel junction positioned between the first subcell and the second subcell.

11. The monolithic, multi-bandgap, photovoltaic converter of claim 10 , wherein the tunnel junction is positioned between the first subcell and the substrate.

12. The monolithic, multi-bandgap, photovoltaic converter of claim 7 , further comprising an isolation layer positioned between the first subcell and the second subcell.

Assignees

• Alliance Sustainable Energy

Inventors

• Wanlass Mark W
• Carapella Jeffrey J

Classifications

• H10F19/40

  comprising photovoltaic cells in a mechanically stacked configuration · CPC title

• H10F19/20

  comprising photovoltaic cells in arrays in or on a single semiconductor substrate, the photovoltaic cells having planar junctions (having multiple thin-film photovoltaic cells deposited on the same substrate H10F19/31) · CPC title

• H10F10/1425 Primary

  Inverted metamorphic multi-junction [IMM] photovoltaic cells · CPC title

• H10F10/142

  comprising multiple PN homojunctions, e.g. tandem cells · CPC title

• H10F19/31 Primary

  having multiple laterally adjacent thin-film photovoltaic cells deposited on the same substrate · CPC title