Three dimensional nand device with silicide containing floating gates and method of making thereof
US-2015072488-A1 · Mar 12, 2015 · US
US9230976B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9230976-B2 |
| Application number | US-201414587368-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 31, 2014 |
| Priority date | Jun 30, 2010 |
| Publication date | Jan 5, 2016 |
| Grant date | Jan 5, 2016 |
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Monolithic, three dimensional NAND strings include a semiconductor channel, at least one end portion of the semiconductor channel extending substantially perpendicular to a major surface of a substrate, a plurality of control gate electrodes having a strip shape extending substantially parallel to the major surface of the substrate, the blocking dielectric comprising a plurality of blocking dielectric segments, a plurality of discrete charge storage segments, and a tunnel dielectric located between each one of the plurality of the discrete charge storage segments and the semiconductor channel.
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What is claimed is: 1. A method of making a monolithic three dimensional NAND string, comprising: providing a stack of alternating first material layers and second material layers different from the first material layer over a substrate, the stack comprising at least one opening containing a charge storage material over a sidewall of the at least one opening, a tunnel dielectric on the charge storage material in the at least one opening, and a semiconductor channel on the tunnel dielectric in the at least one opening; selectively removing the second material layers without removing the first material layers from the stack; and forming control gates between the first material layers. 2. The method of claim 1 , further comprising forming a blocking dielectric between the first material layers and a side wall of the charge storage material exposed between the first material layers. 3. The method of claim 2 , further comprising forming a cut area on a back side of stack. 4. The method of claim 3 , wherein: the second material layers are selectively removed through the cut area; the blocking dielectric is formed through the cut area such that the blocking dielectric contacts the sidewall of the charge storage material exposed between the first material layers; and the control gates are formed through the cut area. 5. The method of claim 4 , wherein portions of the blocking dielectric between the first material layers have a clam shape, and wherein each of the control gates is located at least partially in an opening in a respective clam-shaped portion of the blocking dielectric. 6. The method of claim 1 , wherein the tunnel dielectric has a straight sidewall and a uniform thickness. 7. The method of claim 1 , wherein the charge storage material comprises a charge storage dielectric material. 8. The method of claim 1 , wherein the charge storage material comprises a floating gate material. 9. The method of claim 8 , wherein the floating gate material comprises polysilicon, metal, metal alloy or metal silicide. 10. The method of claim 1 , wherein the charge storage material comprises conductive nanoparticles. 11. The method of claim 1 , wherein one of the first material layers and the second material layers comprise an oxide and the other of the first material layers and the second material layers comprise a nitride. 12. The method of claim 1 , wherein the semiconductor channel in the at least one opening completely fills the at least one opening with a semiconductor channel material. 13. The method of claim 1 , wherein the semiconductor channel in the at least one opening forms a semiconductor channel material on the side wall of the at least one opening but not in a central part of the at least one opening such that the semiconductor channel material does not completely fill the at least one opening. 14. The method of claim 13 , further comprising forming an insulating fill material in the central part of the at least one opening to completely fill the at least one opening. 15. The method of claim 1 , furthering comprising forming an upper electrode over the semiconductor channel and forming a lower electrode below the semiconductor channel. 16. The method of claim 1 , wherein the control gates comprise conductive or semiconductor control gate material. 17. The method of claim 16 , wherein the control gates comprise tungsten, copper, aluminum, tantalum, titanium, cobalt, titanium nitride or alloys thereof. 18. The method of claim 17 , wherein the control gates comprise tungsten. 19. The method of claim 1 , wherein the step of providing the stack comprises: etching the stack to form the at least one opening in the stack; forming the charge storage material over a sidewall of the at least one opening; forming the tunnel dielectric on the charge storage material in the at least one opening; and forming the semiconductor channel on the tunnel dielectric in the at least one opening. 20. The method of claim 1 , wherein: the semiconductor channel extends substantially perpendicular to a major surface of the substrate; the NAND string comprises a plurality of device levels over the substrate; the NAND string is vertically oriented, such that at least one memory cell is located over another memory cell in the NAND string; and each of the plurality of device levels comprises a respective control gate, a respective blocking dielectric portion adjacent to the respective control gate, a respective charge storage material portion adjacent to respective blocking dielectric portion, a respective tunnel dielectric portion adjacent to the respective charge storage material portion, and a respective portion of the semiconductor channel.
the conductor comprising a layer of elemental metal contacting the insulator, e.g. tungsten or molybdenum (having lateral variation H10D64/671) · CPC title
the conductor comprising a layer of silicon contacting the insulator, e.g. polysilicon having vertical doping variation (having lateral variation in the gate structure H10D64/671) · CPC title
comprising charge-trapping insulators · CPC title
comprising conductor-insulator-conductor-insulator-semiconductor structures · CPC title
characterised by the shapes, relative sizes or dispositions of the floating gate electrode · CPC title
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