Process for preparing polyethylene blend comprising metallocene produced resins and Ziegler-Natta produced resins

Patent metadata

Field	Value
Publication number	US-9228078-B2
Application number	US-201214003192-A
Country	US
Kind code	B2
Filing date	Mar 2, 2012
Priority date	Mar 4, 2011
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

A process for preparing a homogeneous polyethylene product can include producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor. The first polyethylene resin can have a density of from 0.940 to 0.970 g/cm 3 . The first polyethylene resin can have a Low Molecular Weight (LMW) with an MI 2 of between 2 and 250 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The second polyethylene resin can have a High Molecular Weight (HMW) with an MI 2 of between 0.01 and 15 g/10 min. The process can include physically blending together the first polyethylene resin and the second polyethylene resin to produce the homogeneous polyethylene product.

First claim

The invention claimed is:

1. A process for preparing a polyethylene product, said process comprising:
(a) producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor, said first polyethylene resin having a density of from 0.940 to 0.970 g/cm 3 , with the density being determined with the ASTM D-1505 standardized test at a temperature of 23° C. and wherein the first polyethylene resin has a melt index (MI 2 ) of between 2 and 250 g/10 min, with the MI 2 being measured by the procedure of ASTM D-1238 using a temperature of 190° C. and a load of 2.16 kg, wherein the first polyethylene resin has a bimodal molecular weight distribution;
(b) separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in the reactor or a separate reactor, wherein the second polyethylene resin has an MI 2 of between 0.01 and 15 g/10 min; and
(c) physically blending together said first polyethylene resin and said second polyethylene resin to produce the polyethylene product.

2. The process according to claim 1 , wherein the metallocene catalyst used for the production of the first polyethylene resin comprises a bis tetrahydroindenyl compound of the general formula (IndH4)2R 4 MQ 2 wherein each Ind is the same or different and is indenyl or substituted indenyl, R 4 is a bridge which comprises a C 1-20 alkylene group, a dialkyl germanium or silicon or siloxane, or an alkyl phosphine or amine group, which bridge is substituted or unsubstituted, M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen.

3. The process according to claim 1 , wherein the Ziegler-Natta catalyst used for the production of said second polyethylene resin has an average particle size (D50) of at most 15 μm, with the D50 being measured by laser diffraction analysis on a Malvern type analyzer.

4. The process according to claim 1 , wherein the second polyethylene resin has monomodal molecular weight distribution.

5. The process according to claim 1 , wherein the second polyethylene resin has a density of from 0.920 to 0.960 g/cm 3 , with the density being determined with the ASTM D-1505 standardized test at a temperature of 23° C.

6. The process according to claim 1 , wherein a weight ratio of said first polyethylene resin to said second polyethylene resin in said polyethylene product is between 0.20 and 5.

7. The process according to claim 1 , wherein said first polyethylene resin and said second polyethylene resin are each produced under slurry conditions.

8. The process according to claim 1 , wherein said first polyethylene resin and said second polyethylene resin are each produced in a loop reactor.

9. The process according to claim 1 , wherein step (c) is performed in a device for continuously melting and blending said first polyethylene resin and second polyethylene resin.

10. The process according to claim 9 , wherein said device is an extruder, a mixer, or combinations thereof.

11. The process according to claim 1 , wherein the second polyethylene resin has a density that is equal to or lower than the density of the first polyethylene resin, with the densities being determined with the ASTM D-1505 standardized test at a temperature of 23° C.

12. The process according to claim 1 , wherein the second polyethylene resin has a molecular weight distribution of at least 5.

13. The process according to claim 1 , wherein the polyethylene product has a density of from 0.920 to 0.960 g/cm 3 , with the density being determined with the ASTM D-1505 standardized test at a temperature of 23° C.

14. The process according to claim 1 , wherein the polyethylene product has an MI 2 of from 0.01 to 100 g/10 min, with the MI 2 being measured by the procedure of ASTM D-1238 using a temperature of 190° C. and a load of 2.16 kg.

15. The process according to claim 1 , wherein the polyethylene product has a multimodal molecular weight distribution.

16. The process according to claim 1 , wherein the polyethylene product is a homogenous blend of the first polyethylene resin and the second polyethylene resin.

Assignees

• Dewachter Daan
• Damme Eric
• Total Res & Technology Feluy

Inventors

• Dewachter Daan
• Damme Eric

Classifications

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/04

  Homopolymers or copolymers of ethene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title

• C08F110/02

  Ethene · CPC title