Method of producing substitute natural gas

Patent metadata

Field	Value
Publication number	US-9227884-B2
Application number	US-201213723448-A
Country	US
Kind code	B2
Filing date	Dec 21, 2012
Priority date	Apr 13, 2012
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

Provided is a method of producing a substitute natural gas. The method includes: generating carbon monoxide and hydrogen using coal and a metal fuel; and generating methane from the generated carbon monoxide and hydrogen. Since the method supplies a metal fuel along with coal, generates hydrogen from the metal fuel, and supplies the hydrogen, the amount of coal needed to generate methane through methanation may be reduced and the amount of carbon dioxide (CO 2 ) generated when the coal is combusted may be reduced.

First claim

What is claimed is:

1. A method of producing a substitute natural gas (SNG), the method comprising:
generating carbon monoxide and hydrogen using coal and a metal fuel, the generating the carbon monoxide and the hydrogen comprising:
generating the carbon monoxide and primary hydrogen by gasifying the coal in a first gasification unit; and
generating secondary hydrogen by reacting the metal fuel in a second gasification unit;

generating methane from the generated carbon monoxide and primary hydrogen;
generating secondary hydrogen by reacting the metal fuel in the second gasification unit; and
supplying heat generated from the generating of the secondary hydrogen in the second gasification unit to the first gasification unit.

2. The method of claim 1 , wherein the generating of the carbon monoxide and the hydrogen further comprises
supplying the secondary hydrogen generated in the second gasification unit to the first gasification unit.

3. The method of claim 2 , further comprising:
generating a metal oxide by reacting the metal fuel in the second gasification unit; and
reducing and reusing the metal oxide as the metal fuel.

4. The method of claim 2 , wherein the metal fuel comprises aluminum powder or magnesium powder.

5. The method of claim 3 further comprising removing impurities from the generated carbon monoxide and hydrogen in a gas cleaning unit.

6. The method of claim 1 , wherein the generating of the carbon monoxide and the hydrogen comprises generating carbon monoxide and hydrogen by gasifying both the coal and the metal fuel in the first gasification unit.

7. The method of claim 6 further comprising adding an alkaline material along with the metal fuel to the first gasification unit.

8. The method of claim 7 , wherein the metal fuel comprises aluminum powder or magnesium powder, and the alkaline material is selected from the group consisting of sodium hydroxide, potassium hydroxide, and gallium.

9. The method of claim 6 , wherein the gasifying both the carbon monoxide and the hydrogen comprises:
generating the carbon monoxide and primary hydrogen by reacting the coal with water and oxygen; and
generating secondary hydrogen by reacting the metal fuel with water and a catalyst.

10. The method of claim 9 , further comprising generating heat from the generating the secondary hydrogen by reacting the metal fuel with the water and the catalyst.

11. The method of claim 6 further comprising removing impurities from the generated carbon monoxide and hydrogen in a gas cleaning unit.

12. The method of claim 1 , wherein the supplying the heat generated from the generating of the secondary hydrogen comprises supplying steam generated from the generating of the secondary hydrogen to the first gasification unit for the generating the carbon monoxide and the primary hydrogen.

13. The method of claim 12 , wherein the supplying the steam comprises supplying the steam generated from the generating of the secondary hydrogen to the first gasification unit for the generating the carbon monoxide and the primary hydrogen to reduce an amount of coal used for the generating the carbon monoxide and the primary hydrogen.

Assignees

• Hanwha Techwin Co Ltd
• Hanwha Techwin Co Ltd

Inventors

• Park Hee-Ho
• Yun Deok-Jin

Classifications

• C07C1/0495 Primary

  Non-catalytic processes; Catalytic processes in which there is also another way of activation, e.g. radiation · CPC title

• C07C1/041

  Reactors · CPC title

• Y02P20/10

  Process efficiency · CPC title

• Y02P20/584

  Recycling of catalysts · CPC title

• C10L3/08 Primary

  Production of synthetic natural gas · CPC title