Polyelectrochromism of electronically weakly coupled 4,4′-divinylazoarylene-bridged two Ru(CO)Cl(PiPr3)2 entities
US-11987596-B1 · May 21, 2024 · US
US9217005B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9217005-B2 |
| Application number | US-201113819188-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 17, 2011 |
| Priority date | Aug 26, 2010 |
| Publication date | Dec 22, 2015 |
| Grant date | Dec 22, 2015 |
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Provided is a catalyst for asymmetric reduction, which can be produced by a convenient and safe production method, has a strong catalytic activity, and has excellent stereoselectivity. The present invention relates to a ruthenium complex represented by the following formula (1): wherein R 1 represents an alkyl group or the like; Y represents a hydrogen atom; X represents a halogen atom or the like; j and k each represent 0 or 1; R 2 and R 3 each represent an alkyl group or the like; R 11 to R 19 each represent a hydrogen atom, an alkyl group or the like; Z represents oxygen or sulfur; n 1 represents 1 or 2; and n 2 represents an integer from 1 to 3, a method for producing the ruthenium complex, a catalyst for asymmetric reduction formed from the ruthenium complex, and methods for selectively producing an optically active alcohol and an optically active amine using the catalyst for asymmetric reduction.
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The invention claimed is: 1. A ruthenium complex represented by the following formula (1): wherein symbol * represents an asymmetric carbon atom; R 1 represents an alkyl group having 1 to 10 carbon atoms; a halogenated alkyl group having 1 to 10 carbon atoms; 10-camphoryl group; an amino group which is optionally substituted with one or two alkyl group having 1 to 10…
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