Assembly for reversible fuel cell

Patent metadata

Field	Value
Publication number	US-9214694-B2
Application number	US-201113818769-A
Country	US
Kind code	B2
Filing date	Aug 23, 2011
Priority date	Aug 30, 2010
Publication date	Dec 15, 2015
Grant date	Dec 15, 2015

Abstract

A membrane-electrode assembly for use in a reversible fuel cell comprises an ion conductive membrane having first and second surfaces; a first electrocatalyst layer in contact with the first surface of the membrane, such first electrocatalyst layer comprising at least one discrete electrolysis-active area (ELE 1 i ) and at least one discrete energy generation-active area (EG 1 i ). A second electrocatalyst layer is placed in contact with the second surface of the membrane, such second electrocatalyst layer comprising at least one discrete electrolysis-active area (ELE 2 i ) and at least one discrete energy generation-active area (EG 2 i ). Each of the discrete electrolysis-active area(s) (ELE 1 i ) on the first electrocatalyst layer correspond and are aligned with each of the discrete electrolysis-active area(s) (ELE 2 i ) on the second electrocatalyst layer, and each of the discrete energy generation-active area(s) (EG 1 i ) on the first electrocatalyst layer correspond and are aligned with each of the discrete energy generation-active area(s) (EG 2 i ) on the second electrocatalyst layer.

First claim

The invention claimed is:

1. An assembly for an electrochemical cell, comprising:
an ion conductive membrane disposed between a first electrocatalyst layer E 1 and a second electrocatalyst layer E 2 ; wherein
the first electrocatalyst layer E 1 , in contact with a surface of the membrane, comprises at least one discrete electrolysis-active area (ELE 1 i ) and at least one discrete energy generation-active area (EG 1 1 );
the second electrocatalyst layer E 2 , in contact with the surface of the membrane opposite of the surface in contact with the first electrocatalyst layer E 1 , comprises at least one discrete electrolysis-active area (ELE 2 i ) and at least one discrete energy generation-active area (EG 2 i );
wherein the at least one discrete electrolysis-active area (ELE 1 i ) of said first electrocatalyst layer E 1 corresponds and is aligned with the at least one discrete electrolysis-active area (ELE 2 i ) of said second electrocatalyst layer E 2 ;
wherein the at least one discrete energy generation-active area (EG 1 i ,) of said first electrocatalyst layer E 1 corresponds and is aligned with the at least one discrete energy generation-active area (EG 2 i ) of said second electrocatalyst layer E 2 ; and
wherein the assembly further comprises at least one boundary region between the at least one discrete electrolysis-active area (ELE 1 i ) and the at least one discrete energy generation-active area (EG 1 i ) of the first electrocatalyst layer E 1 and at least one boundary region between the at least one discrete electrolysis-active area (ELE 2 ,) and the at least one discrete energy generation-active area (EG 2 i ) of the second electrocatalyst layer E 2 ;
wherein each said boundary region has negligible or no electrical conductivity.

2. The assembly according to claim 1 , wherein the ion conductive membrane comprises at least one discrete area corresponding and aligned with the electrolysis-active areas (ELE 1 i and ELE 2 i ) of said first and second electrocatalyst layers and comprises at least one discrete area corresponding and aligned with the energy generation-active areas (EG 1 i and EG 2 i ) of said first and second electrocatalyst layers.

3. The assembly according to claim 1 , further comprising a first gas diffusion layer (GDL 1 ) in contact with the surface of said first electrocatalyst layer not in contact with the ion conductive membrane and further comprising a second gas diffusion layer (GDL 2 ) in contact with the surface of said second electrocatalyst layer not in contact with the ion conductive membrane.

4. The assembly according to claim 3 , wherein said first gas diffusion layer (GDL 1 ) comprises at least one discrete electrolysis-active area (GDL 1 ELEi ) corresponding and aligned with each of the at least one electrolysis-active areas on the first electrocatalyst layer and comprises at least one discrete energy generation-active area (GDL 1 EGi ) corresponding and aligned with each of the at least one energy generation-active areas on the first electrocatalyst layer.

5. The assembly according to claim 4 , wherein said second gas diffusion layer (GDL 2 ) comprises at least one discrete electrolysis-active area (GDL 2 ELEi ) corresponding and aligned with each of the at least one electrolysis-active areas on the second electrocatalyst layer and comprises at least one discrete energy generation-active area (GDL 2 EGi ) corresponding and aligned with each of the at least one energy generation-active areas on the second electrocatalyst layer.

6. The assembly according to claim 5 , wherein the at least one discrete electrolysis-active area on the first and/or second gas diffusion layer is hydrophilic; and wherein the at least one discrete energy generation-active area on the first and/or second gas diffusion layer is hydrophobic.

7. The assembly according to claim 3 , further comprising a first bipolar plate in contact with the first gas diffusion layer and a second bipolar plate in contact with the second gas diffusion layer, said first and second bipolar plates each optionally comprising at least one discrete energy generation-active area and at least one discrete electrolysis-active area corresponding and aligned with the electrolysis-active and energy generation-active areas of the first and second gas diffusion layers.

8. The assembly according to claim 7 , further comprising at least one boundary region between the discrete energy generation-active areas and discrete electrolysis-active areas of said first and second electrocatalyst layers; or between the discrete energy generation-active areas and discrete electrolysis-active areas of said ion conductive membrane; or between the discrete energy generation-active areas and discrete electrolysis-active areas of said first and second gas diffusion layers; and/or between the discrete energy generation-active areas and discrete electrolysis-active areas of said first and second bipolar plates.

9. The assembly according to claim 8 , wherein said at least one boundary region has a composition different from the composition of any of the adjacent energy generation-active areas and electrolysis-active areas.

10. The assembly according to claim 1 , wherein said electrolysis-active areas (ELE 1 i and ELE 2 i ) on said first and second electrocatalyst layers comprise catalysts suitable for the electrolysis of water.

11. The assembly according to claim 1 , wherein said energy generation-active areas (EG 1 i and EG 2 i ) on said first and second electrocatalyst layers comprise catalysts suitable for the production of water from hydrogen and oxygen.

12. The assembly according to claim 9 , wherein the ratio between the sum of all of the discrete energy generation-active areas (EG 1 i or EG 2 i ) on said first or second electrocatalyst layer and the sum of all of the discrete electrolysis-active areas (ELE 1 i or ELE 2 i ) on said first or second electrocatalyst layer is in the range from 1.5:1 to 5:1.

13. The assembly according to claim 12 , wherein said ratio is in the range from 2.8:1 to 3.5:1.

14. A fuel cell comprising the assembly of claim 1 .

15. The assembly according to claim 1 , wherein the boundary regions have electrical conductivity different from each of the adjacent discrete energy generation-active and discrete electrolysis-active areas.

16. The assembly according to claim 15 , wherein the boundary regions have no electrical conductivity.

17. The assembly according to claim 1 , wherein the boundary regions have lower electrical conductivity and lower water adsorption properties than each of the adjacent discrete energy generation-active and discrete electrolysis-active areas.

18. The assembly according to claim 1 , wherein the boundary regions are discrete regions characterized by compositions different from the compositions of any of the adjacent discrete energy generation-active and discrete electrolysis-active areas.

Assignees

• Dubois Eric
• Vandenborre Hugo
• Solvay

Inventors

• Dubois Eric
• Vandenborre Hugo

Classifications

• H01M8/02

  Details (electrodes H01M4/86 - H01M4/98) · CPC title

• H01M4/8605

  Porous electrodes · CPC title

• H01M8/186 Primary

  by electrolytic decomposition of the electrolytic solution or the formed water product · CPC title

• H01M8/0202

  Collectors; Separators, e.g. bipolar separators; Interconnectors · CPC title

• H01M4/8657

  layered · CPC title