Methods for operating polyethylene reactor systems
US-2024392119-A1 · Nov 28, 2024 · US
US9202014B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9202014-B2 |
| Application number | US-201314078576-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 13, 2013 |
| Priority date | Dec 5, 2012 |
| Publication date | Dec 1, 2015 |
| Grant date | Dec 1, 2015 |
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The Application of equations of state to experimental and literature data permits the formation of a model and phase diagram(s) that show under what conditions polyethylene is likely to precipitate out of a high pressure solution of polyethylene in supercritical ethylene. This then permits a better definition to run a high pressure reactor to reduce the likelihood of phase separation, loss of cooling and potentially decomposition of the reactor contents.
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What is claimed is: 1. A method to determine the curve of the liquid liquid equilibrium boundary as a function of molecular weight distribution (MWD) for a multitude of different products comprising from about 80 to about 100 wt. % of ethylene and about 0 up to about 20 weight % of one or more C 3-8 alpha olefins having a molecular weight from about 8,000 to about 500,000 produced in super critical ethylene in a high pressure reactor at temperatures from about 80° C. to about 350°…
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