Functionalized olefin polymers, compositions and articles prepared therefrom, and methods for making the same

Patent metadata

Field	Value
Publication number	US-9200103-B2
Application number	US-201313901805-A
Country	US
Kind code	B2
Filing date	May 24, 2013
Priority date	Dec 21, 2006
Publication date	Dec 1, 2015
Grant date	Dec 1, 2015

Abstract

In one aspect the invention provides a melt process for preparing a functionalized olefin multiblock interpolymer, said process comprising grafting onto the backbone of the olefin multiblock interpolymer at least one compound comprising at least one “amine-reactive” group to form a grafted olefin multiblock interpolymer, and reacting a primary-secondary diamine or an alkanolamine with the grafted olefin multiblock interpolymer, without the isolation of the grated olefin multiblock interpolymer.

First claim

We claim:

1. A process for preparing a functionalized olefin multiblock interpolymer, said process comprising:
A) grafting onto the backbone of an olefin multiblock interpolymer at least one compound comprising at least one “amine-reactive” group to form a grafted olefin multiblock interpolymer;
B) reacting a primary-secondary diamine with the grafted olefin multiblock interpolymer; and
wherein step B) takes place subsequent to step A), without the isolation of the grafted olefin multiblock interpolymer, and wherein both steps A) and B) take place in a melt reaction; and
wherein said olefin multiblock interpolymer comprises an ethylene/α-olefin multiblock interpolymer characterized by one or more of the following characteristics prior to functionalization:
(a) has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship:
T m >−2002.9+4538.5( d )−2422.2( d ) 2 , or

(b) has a Mw/Mn from about 1.7 to about 3.5, and is characterized by a heat of fusion, ΔH in J/g, and a delta quantity, ΔT, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of ΔT and ΔH have the following relationships:
ΔT>−0.1299 (ΔH)+62.81 for ΔH greater than zero and up to 130 J/g,
ΔT≧48° C. for ΔH greater than 130 J/g,

wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30° C.; or

(c) is characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when the ethylene/α-olefin interpolymer is substantially free of a cross-linked phase: Re>1481-1629(d); or
(d) has a molecular fraction which elutes between 40° C. and 130° C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer has the same comonomer(s) and a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/a-olefin interpolymer; or
(e) is characterized by a storage modulus at 25° C., G′ (25° C.), and a storage modulus at 100° C., G′(100° C.), wherein the ratio of G′(25° C.) to G′(100° C.) is from about 1:1 to about 10:1; or
(f) at least one molecular fraction which elutes between 40° C. and 130° C. when fractionated using TREF, characterized in that the fraction has a block index of at least 0.5 and up to about 1 and a molecular weight distribution, Mw/Mn, greater than about 1.3 or
(g) an average block index greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3.

2. The process of claim 1 , wherein the primary-secondary diamine is selected from the group consisting N-ethylethylenediamine, N-phenylethylenediamine, N-phenyl-1,2-phenylene-diamine, N-phenyl-1,4-phenylenediamine, and N-(2-hydroxyethyl)-ethylenediamine.

3. The product of the process of claim 1 .

4. An article comprising at least one component formed from the product of claim 3 .

Assignees

• Dow Global Technologies Llc

Inventors

• Silvis H Craig
• Hahn Stephen F
• Pawlowski David F
• Ansems Patricia
• Mergenhagen Laura K
• Lakrout Hamed

Classifications

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F8/46

  Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation · CPC title

• C08F8/32

  by reaction with amines · CPC title

• C08F222/06

  Maleic anhydride · CPC title

• C08F297/08

  polymerising mono-olefins · CPC title