Oxidation catalyst for production of butadiene and method of preparing the same
US-2015375212-A1 · Dec 31, 2015 · US
US9199895B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9199895-B2 |
| Application number | US-201113825439-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 3, 2011 |
| Priority date | Jun 30, 2011 |
| Publication date | Dec 1, 2015 |
| Grant date | Dec 1, 2015 |
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Disclosed is a method for producing 1,3-butadiene through oxidative dehydrogenation of normal-butene using a parallel reactor in which catalysts are charged into fixed bed reactors and are not physically mixed. More specifically, disclosed is a method for efficiently producing 1,3-butadiene through oxidative dehydrogenation of normal-butene using the parallel reactor containing multi-component bismuth molybdate-based catalysts exhibiting different activities to oxidative dehydrogenation for normal-butene isomers (1-butene, trans-2-butene and cis-2-butene), and butene separated from a C4 mixture containing normal-butene and normal-butane, as a reactant.
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The invention claimed is: 1. A method for preparing 1,3-butadiene as a high yield comprising the steps of: a) charging a bismuth molybdate-based multimetal elements oxide catalyst wherein the multimetal elements consist of Mo, Bi, Fe, Co, and Cs as a first catalyst in a first reactor as a first catalyst fixed bed; b) charging a potassium bismuth molybdate-based multimetal elements oxide catalyst wherein the multimetal elements consist of Mo, Bi, Fe, Co, Cs, and K as a second c…
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