Removal of metals from water

Patent metadata

Field	Value
Publication number	US-9199867-B2
Application number	US-201013264441-A
Country	US
Kind code	B2
Filing date	Apr 14, 2010
Priority date	Apr 14, 2009
Publication date	Dec 1, 2015
Grant date	Dec 1, 2015

Abstract

A method of purifying water is provided that includes applying a voltage to an electrolytic cell 10 that includes an anode 14 , a cathode 16 and an alkaline electrolyte composition having a pH value of about 11 or less. The alkaline electrolyte composition 13 includes at least one waste metal ion to be reduced, and a sacrificial reductant, such as urea, ammonia or a combination thereof, to be oxidized. According to the disclosed method, the voltage is applied across the cathode 16 and the anode 14 and is sufficient to reduce the at least one waste metal ion to form at least one elemental metal species at the cathode 16 , and to oxidize the sacrificial reductant at the anode 14 . Additionally, the applied voltage does not affect the generation of hydrogen at the cathode 16 and/or oxygen at the anode 14.

First claim

What is claimed is:

1. A method of purifying water comprising:
applying a voltage to an electrolytic cell comprising
a cathode with a first conducting component,

an anode with a second conducting component selected from the group consisting of cobalt, copper, iron, nickel, platinum, iridium, ruthenium, rhodium, and mixtures thereof and alloys thereof, and
an alkaline electrolyte composition in electrical communication with the anode and the cathode, wherein the alkaline electrolyte composition has a pH value of about 11 or less and wherein the alkaline electrolyte composition comprises at least one waste metal ion to be reduced, and a sacrificial reductant selected from the group consisting of urea, ammonia, ethanol, methanol, and a combination thereof,
wherein the voltage is applied across the cathode and the anode and is sufficient to reduce the at least one waste metal ion to form at least one elemental metal species at the cathode, and to oxidize the sacrificial reductant at the anode, and less than about 20% of the voltage is spent generating hydrogen at the cathode and/or oxygen at the anode, and
wherein the voltage difference is a single cell voltage with a value of about 1.1 volts or less.

2. The method of claim 1 , wherein the first conducting component is selected from the group consisting of cobalt, copper, iron, nickel, platinum, iridium, ruthenium, rhodium, and mixtures thereof and alloys thereof.

3. The method of claim 1 , wherein the first conducting component is nickel and the second conducting component is platinum.

4. The method of claim 1 , wherein the anode further comprises a support material at least partially layered with the second conducting component.

5. The method of claim 1 , wherein the alkaline electrolyte composition further comprises a hydroxide salt.

6. The method of claim 5 , wherein the hydroxide salt is selected from the group consisting of lithium hydroxide, rubidium hydroxide, cesium hydroxide, barium hydroxide, strontium hydroxide, potassium hydroxide, sodium hydroxide, magnesium hydroxide, calcium hydroxide, and mixtures thereof.

7. The method of claim 5 , wherein the hydroxide salt is potassium hydroxide.

8. The method of claim 1 , wherein the alkaline electrolyte composition is a polymeric gel.

9. The method of claim 8 , wherein the polymeric gel comprises polyacrylic acid, polyacrylates, polymethacrylates, polyacrylamides, sulfonated-polymers or combinations thereof.

10. The method of claim 1 , wherein the waste metal ion is a cation of a metal selected from the group consisting of zinc, chromium, tantalum, gallium, iron, cadmium, indium, thallium, cobalt, nickel, tin, lead, copper, bismuth, silver, mercury, gold, niobium, vanadium, manganese, aluminum, and combinations thereof.

11. The method of claim 1 , wherein the alkaline electrolyte composition has a pH range of about 8 to about 11.

12. The method of claim 1 , wherein the alkaline electrolyte composition has a pH range of about 9 to about 10.

13. The method of claim 1 , wherein the electrolytic cell operates at a temperature in a range from about 0° C. to about 80° C.

14. The method of claim 1 , wherein the electrolytic cell operates at a temperature from about 20° C. to about 65° C.

15. The method of claim 1 , wherein the electrolytic cell operates at a temperature from about 20° C. to about 30° C.

16. The method of claim 1 , wherein the voltage difference is a single cell voltage with a value within a range from about 0.01 volts to about 1.1 volts.

17. The method of claim 1 , wherein the voltage difference across the cathode and the anode is maintained at a value that is less than the voltage necessary to affect any generation of hydrogen at the cathode and/or any generation of oxygen at the anode.

18. The method of claim 1 , wherein
the first conducting component is nickel and the second conducting component is platinum;
the waste metal ion is a cation of a metal selected from the group consisting of zinc, chromium, tantalum, gallium, iron, cadmium, indium, thallium, cobalt, nickel, tin, lead, copper, bismuth, silver, mercury, gold, chromium, niobium, vanadium, manganese, aluminum, and combinations thereof;
the alkaline electrolyte composition has a pH range of about 8 to about 11.

19. A method of recovering metal ions from water comprising:
applying a voltage to an electrolytic cell, comprising
a cathode with a first conducting component,
an anode with a second conducting component selected from the group consisting of cobalt, copper, iron, nickel, platinum, iridium, ruthenium, rhodium, and mixtures thereof and alloys thereof, and
an alkaline electrolyte composition in electrical communication with the anode and the cathode, wherein the alkaline electrolyte composition has a pH value of about 11 or less and wherein the alkaline electrolyte composition comprises at least one metal ion to be reduced, and a sacrificial reductant comprising urea,

wherein the voltage is applied to the electrolytic cell across the cathode and the anode and is sufficient to reduce the at least one metal ion to form at least one elemental metal species at the cathode, and to oxidize the sacrificial reductant at the anode, and less than about 20% of the voltage is spent generating hydrogen at the cathode and/or oxygen at the anode; and
recovering the at least one elemental metal species.

Assignees

• Botte Gerardine G
• Univ Ohio

Inventors

• Botte Gerardine G

Classifications

• C02F2101/20

  Heavy metals or heavy metal compounds · CPC title

• C02F2209/06

  pH · CPC title

• C02F2201/4618

  Supplying or removing reactants or electrolyte · CPC title

• C02F1/4678 Primary

  of metals · CPC title

• C02F2101/16

  Nitrogen compounds, e.g. ammonia · CPC title