Macrocyclic compounds and methods of use
US-2024294551-A1 · Sep 5, 2024 · US
US9196846B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9196846-B2 |
| Application number | US-201514687059-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 15, 2015 |
| Priority date | Apr 17, 2014 |
| Publication date | Nov 24, 2015 |
| Grant date | Nov 24, 2015 |
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A novel electron acceptor based on bay-annulated indigo (BAI) was synthesized and used for the preparation of a series of high performance donor-acceptor small molecules and polymers. The resulting materials possess low-lying LUMO energy level and small HOMO-LUMO gaps, while their films exhibited high crystallinity upon thermal treatment, commensurate with high field effect mobilities and ambipolar transfer characteristics.
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What is claimed is: 1. A composition comprising of the formula: 7,14-di(thiophen-2-yl)diindolo[3,2,1-de:3′,2′,1′-ij][1,5]naphthyridene-6,13-dione. 2. A method of making the composition of claim 1 comprising: adding a solution of 2-thiopheneacetyl chloride in xylene dropwise to a refluxing xylene suspension of indigo. 3. The met…
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