Thermochromic material, molded article comprising said material and use thereof

Patent metadata

Field	Value
Publication number	US-9193863-B2
Application number	US-201314430419-A
Country	US
Kind code	B2
Filing date	Aug 8, 2013
Priority date	Sep 24, 2012
Publication date	Nov 24, 2015
Grant date	Nov 24, 2015

Abstract

The invention relates to a thermochromic material comprising at least one biopolymer, at least one natural dye and at least one reaction medium, selected from the group of fatty acids and derivatives thereof, gallic acid and derivatives thereof and mixtures thereof. The thermochromic material according to the invention is completely based on non-toxic, natural products. Processing into materials or molded articles can occur, according to the invention, by means of conventional extrusion technology in the form of flat film, blown film or sheets or multi-wall sheets. The thermochromic material can be used in particular in the food industry and medical technology.

First claim

The invention claimed is:

1. A thermochromic material comprising at least one biopolymer, at least one natural dye and at least one reaction medium selected from the group of fatty acids and derivatives thereof, gallic acid and derivatives thereof and mixtures thereof,
wherein all the components of the thermochromic material optionally contain components or additives which are permitted for foodstuff.

2. The thermochromic material according to claim 1 ,
wherein the at least one natural dye has an anthocyanidin structure.

3. The thermochromic material according to claim 1 ,
wherein the at least one reaction medium is selected from the group consisting of petroselinic acid, palmitoleic acid, myristoleic acid, oleic acid, elaidic acid, gadoleic acid, undecylenic acid, icosenic acid, vaccenic acid, cetoleic acid, erucic acid, nervonic acid, cervonic acid, clupanodonic acid, timnodonic acid, linoleic acid, calendic acid, punicic acid, eleostearic acid, arachidonic acid, formic acid, acetic acid, caprylic acid, pelargonic acid, caproic acid, laroic acid, myristic acid, palmitic acid, margaric acid, stearic acid, arachic acid, propionic acid, butyric acid, valeric acid, onanthic acid, behenic acid, lignoceric acid, cerotic acid, montanic acid, melissic acid, dodecylgallate, octylgallate, propylgallate, phytanic acid, isovaleric acid or etheric oils or mixtures thereof.

4. The thermochromic material according to claim 1 ,
wherein the at least one biopolymer is suitable for flat film- or blown film extrusion or for manufacture of sheets.

5. The thermochromic material according to claim 1 ,
wherein the at least one biopolymer is selected from the group consisting of polyhydroxybutanoic acid, cellulose acetate, polylactic acid and copolymers and polymer blends thereof.

6. The thermochromic material according to claim 1 ,
wherein all the components of the thermochromic material are permitted for foodstuff according to the EU regulation No. 1333/2008 and corresponding current appendices for foodstuff and have an E-number.

7. The thermochromic material according to claim 1 ,
wherein the thermochromic effect of the material is reversible or irreversible.

8. The thermochromic material according to claim 1 ,
wherein thermochromic effect is produced by physicochemical interactions of the components.

9. The thermochromic material according to claim 1 ,
wherein the thermochromic material is extrudable.

10. An extruded moulded article comprising a thermochromic material according to claim 1 .

11. The moulded article according to claim 10 ,
wherein the moulded article is a flat film or a blown film.

12. The moulded article according to claim 10 ,
wherein the moulded article is a sheet or a multiskin sheet.

13. A method comprising utilizing the thermochromic material and molded articles made therefrom in the foodstuff industry and medical technology according to claim 1 .

14. The thermochromic material according to claim 2 , wherein the at least one natural dye is selected from the group consisting of cyanidin, delphinidin, aurantinidin, petunidin, peonidin, malvidin, pelargondin, rosinidin, europinidin, luteolinidin and mixtures thereof.

Assignees

• Fraunhofer Ges Forschung

Inventors

• Lötzsch Detlef
• Ruhmann Ralf
• Seeboth Arno

Classifications

• C09K9/02 Primary

  Organic tenebrescent materials · CPC title

• C08L2666/34

  Oxygen-containing compounds, including ammonium and metal salts · CPC title

• C08L1/12

  Cellulose acetate · CPC title

• C08K5/1545

  Six-membered rings · CPC title

• C08L2666/28

  Non-macromolecular organic substances · CPC title